1-9 A-D E-G H-M N-P Q-S T-Z

GLYCIDYL METHACRYLATE

Glycidyl Methacrylate; 106-91-2; Small additives GMA (glycidyl methacrylate) and its derivatives to different polymeric materials improve their mechanical, optical, adhesive characteristics, chemical and atmospheric durability. GMA (glycidyl methacrylate) is used for an improvement in the quality and reaching of the optimum performance properties of varnishes and paints, natural rubbers, latexes, sealing compounds, industrial protective coatings, synthetic fibers, paper, thermoplastics, electros-laminate, structural and ion-exchange materials, used in polygraphy, automobile construction, to radio engineering and to microelectronics, biotechnology and to medicine. Characteristic property GMA is its dual functionality - due to the methacrylic and epoxy groups. This gives to it the possibility to combine the chemical properties of acrylates, reacting with styrene, by acrylates or by ethylene, and epoxies. Epoxy group GMA is capable of different chemical transformations both in the monomer and in the polymers. Its ability easily to react with different substances (amines, phenols, ketones, carbonaceous acids, which contain halogen and other.) it makes it possible to synthesize many new chemical connections.

Synonym: 2,3-Epoxypropylmethacrylate; oxiran-2-ylmethyl 2-methylprop-2-enoate. Other names:glycidyl methacrylate, 2,3-epoxypropyl methacrylate, 2-((Methacryloxy)methyl)oxirane. Glycidyl methacrylate (GMA) is an ester of methacrylic acid and glycidol, it is a common monomer used in the creation of epoxy resins. 

While typical home epoxies contain diglycidyl ether of bisphenol A (DGEBA), glycidyl methacrylate is instead used to provide epoxy functionalization to polyolefins and other acrylate resins

Glycidyl methacrylate is a colorless liquid with a fruity odor. Floats on water

Glycidyl methacrylate is an enoate ester obtained by formal condensation of the carboxy group of methacrylic acid with the hydroxy group of glycidol. 

It is an enoate ester and an epoxide. It derives from a methacrylic acid and a glycidol.

 

Glycidyl methacrylate (GMA) is an  is an epoxy-functional monomer/ acrylic monomer ester with the molecular formula C7H10O3, CAS 106-91-2.  It has a sharp odour that may be troublesome. 

 

It is a common monomer used in the creation of epoxy resins. Glycidyl methacrylate is used to provide epoxy functionalization to polyolefins and other acrylate resins.

Production

Glycidyl methacrylate is produced from methacrylic acid and glycidol. Glycidol contain both epoxide and alcohol functional groups.

 

Uses

Glycidyl methacrylate is used in the production of polymer coatings and finishes, adhesives, plastics and elastomers.

 

GMA can also undergo polymerization to form poly (glycidyl methacrylate).

 

 

Glycidyl methacrylate is a polyfunctional monomer. It acts as an adhesion promoting crosslinking co-monomer for acrylic and vinyl resins. It is also a reactive colorless diluent. GMA is soluble in ethanol, acetone, diethyl ether, benzene.

 

Uses

Glycidyl methacrylate (GMA) is a common monomer used in the creation of epoxy resins. It is used to provide epoxy functionalization to polyolefins and other acrylate resins.

Glycidyl methacrylate is used in the production of polymer coatings and finishes, adhesives, plastics and elastomers.

Glycidyl methacrylate dextran has been reported to be used as a biocompatible hydrogel. In situ polymerization of GMA with trimethylolpropane trimethacrylate to form macroporous sorbents has also been reported. GMA may also be grafted onto polypropylene.

 

Preparation

Glycidyl methacrylate is produced from methacrylic acid and glycidol. Glycidol contain both epoxide and alcohol functional groups.It is an enoate ester and an epoxide. It derives from a methacrylic acid and a glycidol.

 

Reactions

Glycidyl methacrylate (GMA) is a kind of functional monomer. Its active vinyl and epoxy groups could be grafted with polyolefin and reacted with the polar groups such as amine, hydroxyl and carboxyl group, respectively. It can also undergo polymerization to form poly (glycidyl methacrylate).

 

Synthesis Reference(s)

Synthesis, p. 1019, 1986

Tetrahedron, 48, p. 5099, 1992 DOI: 10.1016/S0040-4020(01)90120-6

 

General Description

Colorless liquid with a fruity odor. Floats on water.

 

Air & Water Reactions

Flammable. Slightly water soluble.

 

Reactivity Profile

Epoxides, such as Glycidyl methacrylate, are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

 

Health Hazard

The liquid irritates eyes about as much as soap. Prolonged contact with skin produces irritation and dermatitis.

 

Fire Hazard

Special Hazards of Combustion Products: Irritating vapors are generated when heated

 

106-91-2 

Name: Glycidyl methacrylate

CAS: 106-91-2

Molecular Formula: C7H10O3

Molecular Weight: 142.152

CAS: 106-91-2

106-91-2 - Names and Identifiers

Name: Glycidyl methacrylate

Synonyms: 2,3-Epoxypropyl methacrylate

Methacrylic acid glycidyl ester

oxiran-2-ylmethyl 2-methylprop-2-enoate

(2S)-oxiran-2-ylmethyl 2-methylprop-2-enoate

(2R)-oxiran-2-ylmethyl 2-methylprop-2-enoate

2-Propenoic acid,2-methyl-,2-oxiranylmethyl ester

Epoxypropyl methacrylate

GMA

CAS 106-91-2

EINECS 203-441-9

106-91-2 - Physico-chemical Properties

Molecular Formula: C7H10O3

Molar Mass: 142.152 g/mol

Density 1.095g/cm3

Boling Point: 189°C at 760 mmHg

Flash Point:76.1°C

Solubility:0.5-1.0 g/100 mL at 20℃

Vapor Presure:0.582mmHg at 25°C

Refractive Index:1.457

 

 

EC / List no.: 203-441-9

CAS no.: 106-91-2

Mol. formula: C7H10O3

 

 

1-Propanol, 2,3-epoxy-, methacrylate

2,3-epoxypropyl methacrylate

2,3-Epoxypropyl methacrylate

2,3-epoxypropyl methacrylate

2,3-epoxypropyl methacrylate; glycidyl methacrylate

2,3-Epoxypropyl methacrylic acid ester

2-((Methacryloxy)methyl)oxirane

2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester

2-Propenoic acid, 2-methyl-, oxiranylmethyl ester

Acriester G

Blemmer G

Other

Blemmer GMA

Glycidol methacrylate

Glycidyl alpha-methyl acrylate

Glycidyl methacrylate

glycidyl methacrylate

Light Ester G

Methacrylic acid, 2,3-epoxypropyl ester

methacrylic acid, 2,3-epoxypropyl ester

SR 379

 

Translated names

(oxiranylmetyl)-metakrylát (sk)

2,3-epoksipropil metakrilat (sl)

2,3-epoksipropil-metakrilat (hr)

2,3-epoksipropilmetakrilatas (lt)

2,3-epoksipropilmetakrilāts (lv)

2,3-epoksypropylmetakrylat (no)

2,3-epoksüpropüülmetakrülaat (et)

2,3-epossipropile metacrilato (it)

2,3-epoxipropil metacrilat (ro)

2,3-epoxipropil-metakrilát (hu)

2,3-epoxipropylmetakrylat (sv)

2,3-epoxypropyl-methakrylát (cs)

2,3-epoxypropylmethacrylaat (nl)

2,3-epoxypropylmethacrylat (da)

2,3-Epoxypropylmethacrylat (de)

2,3-епоксипропил метакрилат (bg)

ester 2,3-epoksypropylowy kwasu metakrylowego (pl)

glicidil metacrilat (ro)

glicidil metacrilato (it)

glicidil metakrilat (sl)

glicidil-metakrilat (hr)

glicidil-metakrilát (hu)

glicidilmetakrilatas (lt)

glicidilmetakrilāts (lv)

glycidyl-metakrylát (sk)

glycidyl-methakrylát (cs)

glycidylmetakrylat (no)

glycidylmetakrylat (sv)

glycidylmethacrylaat (nl)

glycidylmethacrylat (da)

Glycidylmethacrylat (de)

Glysidyylimetakrylaatti (fi)

Glütsidüülmetakrülaat (et)

metacrilato de 2,3-epoxipropilo (es)

metacrilato de 2,3-epoxipropilo (pt)

metacrilato de glicidilo (es)

metacrilato de glicidilo (pt)

metakrylan 2,3-epoksypropylu (pl)

metakrylan glicydowy (pl)

méthacrylate de 2,3-époxypropyle (fr)

méthacrylate de glycidyle (fr)

μεθακρυλικός 2,3-εποξυπροπυλεστέρας μεθακρυλικός γλυκυδυλεστέρας (el)

глицидил метакрилат (bg)

 

CAS names

2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester

 

IUPAC names

(2,3-Epoxy-propyl)-methacrylat

(2S)-oxiran-2-yl]methyl 2-methylprop-2-enoate

(oxiran-2-yl)methyl 2-methylprop-2-enoate

2,3-Epoxypropyl methacrylate

2,3-epoxypropyl methacrylate

2,3-epoxypropyl methacrylate

2,3-epoxypropyl methacrylate/glycidyl methacrylate

2,3-epoxypropyl methacrylate/glycidyl methacrylate

2,3-epoxypropyl methacrylate; glycidyl methacrylate

2,3-Epoxypropylmethacrylat

2-Oxiranylmethyl 2-methylacrylate, Glycidyl methacrylate

2-propenoic acid, 2-methyl-,2-oxiranylmethyl ester

GLYCIDYL METHACRYLATE

Glycidyl Methacrylate

Glycidyl methacrylate

glycidyl methacrylate

Glycidyl Methacrylate

Glycidyl methacrylate

Glycidyl Methacrylate (stabilized with MEHQ)

glycidylmethacrylate

GMA

Methacrylsäure-2,3-epoxypropylester

oxiran-2-yl methyl 2-methylprop-2-enoate

oxiran-2-ylmethyl 2-methylprop-2-enoate

oxiran-2-ylmethyl methacrylate

 

Trade names

2,3-epoxypropyl methacrylate

 

ACRYESTER G

Glycidyl methacrylate

glycidyl methacrylate

 

GMA

 

 

(±)-Glycidyl methacrylate

106-91-2 [RN]

2,3-EPOXYPROPYL METHACRYLATE

2,3-Epoxypropyl methacrylic acid ester

2-[(Methacryloyloxy)methyl]oxirane

203-441-9 [EINECS]

2-Methyl-2-propenoic acid oxiranylmethyl ester

2-Oxiranylmethyl methacrylate [ACD/IUPAC Name]

2-Oxiranylmethylmethacrylat [German] [ACD/IUPAC Name]

2-Propenoic acid, 2-methyl-, oxiranylmethyl ester [ACD/Index Name]

Allyl glycidyl ether [UN2219] [Flammable liquid]

Glycidol methacrylate

Glycidyl methacrylate [Wiki]

Glycidyl α-methylacrylate

GMA

Méthacrylate de 2-oxiranylméthyle [French] [ACD/IUPAC Name]

Methacrylic acid 2,3-epoxypropyl ester

Methacrylic acid, 2,3-epoxypropyl ester

MFCD00005137 [MDL number]

oxiran-2-ylmethyl methacrylate

R8WN29J8VF

Sartomer 379

sy-monomer g

UNII:R8WN29J8VF

(oxiran-2-yl)methyl 2-methylprop-2-enoate

[106-91-2]

1-Allilossi-2,3 epossipropano [Italian]

1-Propanol, 2,3-epoxy-, methacrylate

2-((Methacryloxy)methyl)oxirane

2,3-Epoxypropanol methacrylate

2,3-Epoxypropylmethacrylate

203-442-4 [EINECS]

2-methyl-2-propenoic acid [(2R)-2-oxiranyl]methyl ester

2-Methyl-acrylic acid oxiranylmethyl ester

2-Oxiranylmethyl 2-methylacrylate

2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester

5-17-03-00012 [Beilstein]

95%, stab. with100 ppm MEHQ

Acriester G

AGE

Allil-glicidil-etere

Allyl 2, 3-epoxypropyl ether

Allylglycidaether [German]

Denacol EX 111

Epiol A

glycidyl methacrylate 95%

glycidyl methacrylate, 97%, stabilized

Glycidyl α-methylacrylate

glycidylmethacrylate

https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:132844

Jsp000614

methacrylic acid glycidyl ester

oxiran-2-ylmethyl 2-methylacrylate

oxiran-2-ylmethyl 2-methylprop-2-enoate

OXIRANYLMETHYL-2-METHYL-2-PROPENOATE

Oxyde d'allyle et de glycidyle

Propane, 1-(allyloxy)-2,3-epoxy- (8CI)

Santolin XI

SR-379

VS-02747

WLN: T3OTJ B1OVY1 & U1

 

 

GLYCIDYL METHACRYLATE

 

106-91-2

 

2,3-Epoxypropyl methacrylate

 

SY-Monomer G

 

Glycidol methacrylate

 

Acriester G

 

Blemmer G

 

Blemmer GMA

 

Light Ester G

 

glycidylmethacrylate

 

oxiran-2-ylmethyl 2-methylprop-2-enoate

 

Methacrylic Acid Glycidyl Ester

 

2-((Methacryloxy)methyl)oxirane

 

Methacrylic acid, 2,3-epoxypropyl ester

 

Glycidyl alpha-methylacrylate

 

2-Propenoic acid, 2-methyl-, oxiranylmethyl ester

 

CP 105

 

Polyglycidyl methacrylate

 

NSC 24156

 

Glycidyl alpha-methyl acrylate

 

oxiran-2-ylmethyl methacrylate

 

1-Propanol, 2,3-epoxy-, methacrylate

 

CCRIS 2626

 

HSDB 494

 

EINECS 203-441-9

 

SR 379

 

Glycidyl methacrylate(GMA)

 

2,3-Epoxypropyl methacrylic acid ester

 

BRN 0002506

 

2,3-Epoxypropanol methacrylate

 

Glycidyl .alpha.-methylacrylate

 

DTXSID0025361

 

2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester

 

MFCD00005137

 

(oxiran-2-yl)methyl 2-methylprop-2-enoate

 

DSSTox_CID_5361

 

DSSTox_RID_77762

 

DSSTox_GSID_25361

 

GMA

 

oxiran-2-ylmethyl 2-methylacrylate

 

Methacrylic acid,3-epoxypropyl ester

 

WLN: T3OTJ B1OVY1 & U1

 

Glycidyl methacrylate, 97%, stabilized

 

CAS-106-91-2

 

25067-05-4

 

Acryester G

 

glycidyl-methacrylate

 

PubChem23289

 

ACMC-20dh4k

 

2-Propenoic acid, 2-methyl-, oxiranylmethyl ester, homopolymer

 

methacrylic acid glycidyl

 

2-Propenoic acid, 2-methyl-, (2R)-oxiranylmethyl ester

 

EC 203-441-9

 

NCIOpen2_000036

 

SCHEMBL15617

 

5-17-03-00035 (Beilstein Handbook Reference)

 

KSC175C8B

 

methacrylic acid-glycidyl ester

 

CHEMBL1333073

 

CTK0H5180

 

KS-00000BXD

 

CHEBI:132844

 

130463-96-6

 

NSC24156

 

NSC67195

 

Tox21_201494

 

Tox21_303145

 

2-Oxiranylmethyl 2-methylacrylate #

 

ANW-15457

 

BBL010914

 

LS-411

 

NSC-24156

 

NSC-67195

 

SBB081273

 

SR-379

 

STK801798

 

AKOS000276065

 

AKOS016041668

 

MCULE-2297059991

 

Glycidyl methacrylate, >=97.0% (GC)

 

NCGC00091055-01

 

NCGC00091055-02

 

NCGC00256974-01

 

NCGC00259045-01

 

VS-02747

 

2-methyl-acrylic acid oxiranylmethyl ester

 

Oxiran-2-ylmethyl methacrylate 106-91-2

 

Epoxypropyl methacrylate,5 cp(25 degrees c)

 

FT-0609742

 

Glycidyl Methacrylate (stabilized with MEHQ)

 

M0590

 

ST50330616

 

Glycidyl Methacrylate, (stabilized with MEHQ)

 

2-methyl-acrylic acid oxiran-2-yl-methyl ester

 

Glycidyl methacrylate, purum, >=97.0% (GC)

 

Q2013175

 

W-108764

 

Glycidyl methacrylate, stab. with 100ppm 4-methoxyphenol

 

2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester, homopolymer

 

Glycidyl methacrylate, 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor

 

 

 

 

CAS No: 106-91-2
EC No: 203-441-9


Metatags:
Glisidil metakrilat
Glisidilmetakrilat
Glycidyl metakrilat
Glisidil methakrilat
GMA
2,3-epoxypropyl methacrylate
glycidyl methacrylate
monomethacrylate propylene oxide
Sta-Lock
GLYCIDYL METHACRYLATE
106-91-2
2,3-Epoxypropyl methacrylate
SY-Monomer G
Glycidol methacrylate
Acriester G
Light Ester G
oxiran-2-ylmethyl 2-methylprop-2-enoate
2-Propenoic acid, 2-methyl-, oxiranylmethyl ester
glycidylmethacrylate
CP 105
Methacrylic Acid Glycidyl Ester
Methacrylic acid, 2,3-epoxypropyl ester
2-((Methacryloxy)methyl)oxirane
NSC 24156
1-Propanol, 2,3-epoxy-, methacrylate
Glycidyl alpha-methylacrylate
Glycidyl alpha-methyl acrylate
oxiran-2-ylmethyl methacrylate
Glycidyl .alpha.-methylacrylate
2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester
2,3-Epoxypropyl methacrylic acid ester
oxiran-2-ylmethyl 2-methylacrylate
2-Propenoic acid, 2-methyl-, oxiranylmethyl ester, homopolymer
Methacrylic acid,3-epoxypropyl ester
Methacrylic acid 2,3-epoxypropyl ester
glycidyl-methacrylate
glisidil-metakrilat
Polyglycidyl methacrylate
methacrylic acid glycidyl
methacrylic acid-glycidyl ester
2,3-Epoxypropanol methacrylate
Glycidyl methacrylate, stab. with 100ppm 4-methoxyphenol
2-Propenoic acid, 2-methyl-, 2-oxiranylmethyl ester, homopolymer

 

 

Glisidil Metakrilat (GMA) metakrilik asit esteridir ve epoksi reçinelerin üretilmesinde kullanılan yaygın bir monomerdir. Bilinen epoksiler Bisphenol A diglisidil eter (DGEBA) içerirken, glisidil metakrilat poliolefinlere ve diğer akrilat reçinelerine epolsi fonksiyonu kazandırmak için kullanılır. Glisidil metakrilat dünya çapında pek çok firma tarafından üretilmektedir.

 

 

Glycidyl methacrylate (GMA) is an ester of methacrylic acid and a common monomer used in the creation of epoxy resins. While typical home epoxies contain diglycidyl ether of bisphenol A (DGEBA), glycidyl methacrylate is instead used to provide epoxy functionalization to polyolefins and other acrylate resins. Glycidyl methacrylate is produced by several companies worldwide.

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