TERT DODECYL MERCAPTAN
CAS NUMBER: 25103-58-6
EC NUMBER: 246-619-1
SYNONYMS:tert-Dodecanethiol; 2,3,3,4,4,5-Hexamethyl-2-hexanethiol; tert-Dodecylmercaptan; sulfole120; t-ddm; tert.Dodecanthiol;tert-Dodecyl Mercaptan ;tert-Dodecanethiol; Tert-dodecyl mercaptan;Lauryl mercaptan; Dodecyl mercaptan; TDM;t-ddm;sulfole120;Sulfol 120;Dodecanethiol;tert-Dodecanet;T-DODECANETHIOL;Ncgc00091163-01;tert-dodecylthiol;tert.Dodecanthiol; tert-Dodecanethiol, tert-Lauryl Mercaptan;tert-Dodecyl mercaptan; tert-Dodecylthiol; TERT-DODECANETHIOL; t-Dodecanethiol; t-Dodecylmercaptan; Sulfole 120; CCRIS 6030; t-DDM; 2,3,3,4,4,5; hexamethylhexane-2-thiol; terc.Dodecylmerkaptan [Czech]; EINECS 246-619-1; BRN 1738382; NCGC00091163-03; 2,3,3,4,4,5-Hexamethyl-2-hexanethiol; terc.Dodecylmerkaptan; AC1L1OFU; DSSTox_CID_5221; UNII-G00MDQ58TB; DSSTox_RID_77707; G00MDQ58TB; DSSTox_GSID_25221; SCHEMBL3332338; CHEMBL1325985; DTXSID1025221; YAJYJWXEWKRTPO-UHFFFAOYSA-NTox21_400018; AKOS015900250; LS-1066; NCGC00091163-01; NCGC00091163-02; NCGC00091163-04; CAS-25103-58-6; 3-01-00-01794 (Beilstein Handbook Reference); I14-10461; 119147-91-0; 90501-34-1; InChI=1S/C12H26S/c1-9(2)10(3,4)11(5,6)12(7,8)13/h9,13H,1-8H3; YAJYJWXEWKRTPO-UHFFFAOYSA-N; tert-Dodecanethiol; tert-Dodecanethiol; Mercaptan (tert-Dodecyl Mercaptan); tert-Dodecanethiol (mixture of isomers); tert-Lauryl Mercaptan (mixture of isomers); tert-Dodecanethiol; Alkyl Thiols, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols; InChI=1S/C12H26S/c1-12(2,3)10-8-6-4-5-7-9-11-13/h13H,4-11H2,1-3H3; UVXGZLRXSOTRRS-UHFFFAOYSA-N; Decanethiol, 9,9-dimethyl-; Lauryl mercaptan, Dodecyl mercaptan; tert-Dodecanethiol (mixture of isomers) for synthesis; TDM, Tert-Dodecanethiol; 2,3,3,4,4,5-HEXAMETHYL-2-HEXANETHIOL; SULFOLE 120; T-DDM; T-DODECANETHIOL; T-DODECYLMERCAPTAN, TERT-DODECANETHIOL; TERT-DODECYL MERCAPTAN; TERT-DODECYL THIOL, TERT-DODECYLMERCAPTAN; TERT-DODECYLTHIOL; TERT-LAURYL MERCAPTAN; C12H26S; tert-Dodecyl Mercaptan; tert-Dodecyl mercaptan, ethoxylated;tert-Dodecylthio poly(ethyleneoxy) ethanol; tert-Dodecyl mercaptan, ethoxylated; tert-Dodecyl mercaptan, ethoxylated;tert-Dodecylthio poly(ethyleneoxy) ethanol; Sphalerite flotationTert dodecyl mercaptanDensity functional theory; tert-Dodecyl Mercaptan; tert dodecyl mercaptan wiki; tert-dodecylmercaptaN; tert-Dodecylthiol 0.97; tert-Dodecylthiol 98%; dodecanthiol 98.00% ; tert-Dodecanethiol 98+% ; tert-Dodecylthiol; tert-Dodecyl mercaptan; Tert Dodecyl Mercaptan,99.00 Grade A, 99.00 Grade A *; tert-Dodecanethiol_(mixture of isomers); ; Lauryl mercaptan; Dodecyl mercaptan; tert-Dodecanethiol; tert-Dodecyl mercaptane; tert-Dodecanethiol (mixture ofisomers); tert dodecylmercaptan ; tert-Dodecylthio 92%; tert-Dodecyl mercaptan; tert-dodecylthiol 98.0%; tert-dodecylthiol2,3,3,4,4,5-hexamethyl-2-hexanethiol; tert-Dodecylthiol 99%; tert-Dodecyl mercaptan; Sulfide Palladium Acetophenone Hydrochloric Acid Solution Mercaptan ; PEG TERT-DODECYL THIOETHER; ALPHA-(2-(TERT-DODECYLTHIO)ETHYL)-OMEGA-HYDROXYPOLY(OXY-1,2-ETHANEDIYL); DODECYLTHIOL, TERT-, ETHOXYLATED; DODECYL MERCAPTAN, TERT-, ETHOXYLATED; PEG TERT-DODECANETHIOL; POLY(OXY-1,2-ETHANEDIYL), ALPHA-(2 (TERT DODECYLTHIO)ETHYL)-OMEGA-HYDROXY- TERT-DODECYL MERCAPTAN, ETHOXYLATED; t-dodecanethiol; 2,2,4,6,6-Pentamethyl-4-heptanethiol [ACD/IUPAC Name]; 2,2,4,6,6-Pentaméthyl-4-heptanethiol [French] [ACD/IUPAC Name]; 2,2,4,6,6-Pentamethyl-4-heptanthiol [German] [ACD/IUPAC Name]; 2,2,4,6,6-Pentamethylheptane-4-thiol; 25103-58-6 [RN]; 296-714-7 [EINECS]; 4-Heptanethiol, 2,2,4,6,6-pentamethyl- [ACD/Index Name]; MFCD00043233 [MDL number]; tert-Dodecylmercaptan; tert-Dodecanethiol; tert-Dodecanethiol (mixture of isomers); tert-dodecylthiol; tert-Dodecyl mercaptan; tert-Dodecylthiol; TERT-DODECANETHIOL; t-Dodecanethiol; t-Dodecylmercaptan; Sulfole 120; CCRIS 6030; t-DDM; 2,3,3,4,4,5; hexamethylhexane-2-thiol; terc.Dodecylmerkaptan [Czech]; EINECS 246-619-1; BRN 1738382; NCGC00091163-03; 2,3,3,4,4,5-Hexamethyl-2-hexanethiol; terc.Dodecylmerkaptan; AC1L1OFU; DSSTox_CID_5221; UNII-G00MDQ58TB; DSSTox_RID_77707; G00MDQ58TB; DSSTox_GSID_25221; SCHEMBL3332338; CHEMBL1325985; DTXSID1025221; YAJYJWXEWKRTPO-UHFFFAOYSA-N; Tox21_400018; AKOS015900250; LS-1066; NCGC00091163-01; NCGC00091163-02; NCGC00091163-04; CAS-25103-58-6; 3-01-00-01794 (Beilstein Handbook Reference); I14-10461; 119147-91-0; 90501-34-1; InChI=1S/C12H26S/c1-9(2)10(3,4)11(5,6)12(7,8)13/h9,13H,1-8H3; YAJYJWXEWKRTPO-UHFFFAOYSA-N; tert-Dodecanethiol; tert-Dodecanethiol; Mercaptan (tert-Dodecyl Mercaptan); tert-Dodecanethiol (mixture of isomers); tert-Lauryl Mercaptan (mixture of isomers); tert-Dodecanethiol; Alkyl Thiols, Materials Science, Micro/NanoElectronics, Self Assembly & Contact Printing, Self-Assembly Materials, Thiols; InChI=1S/C12H26S/c1-12(2,3)10-8-6-4-5-7-9-11-13/h13H,4-11H2,1-3H3; UVXGZLRXSOTRRS-UHFFFAOYSA-N; Decanethiol, 9,9-dimethyl-; Lauryl mercaptan, Dodecyl mercaptan; tert-Dodecanethiol (mixture of isomers) for synthesis; TDM, Tert-Dodecanethiol; 2,3,3,4,4,5-HEXAMETHYL-2-HEXANETHIOL; SULFOLE 120; T-DDM; T-DODECANETHIOL; T-DODECYLMERCAPTAN, TERT-DODECANETHIOL; TERT-DODECYL MERCAPTAN; TERT-DODECYL THIOL, TERT-DODECYLMERCAPTAN; TERT-DODECYLTHIOL; TERT-LAURYL MERCAPTAN; C12H26S; tert-Dodecyl Mercaptan; tert-Dodecyl mercaptan, ethoxylated;tert-Dodecylthio poly(ethyleneoxy) ethanol; tert-Dodecyl mercaptan, ethoxylated; tert-Dodecyl mercaptan, ethoxylated;tert-Dodecylthio poly(ethyleneoxy) ethanol; Sphalerite flotationTert dodecyl mercaptanDensity functional theory; tert-Dodecyl Mercaptan; tert dodecyl mercaptan wiki; tert-dodecylmercaptaN; tert-Dodecylthiol 0.97; tert-Dodecylthiol 98%; dodecanthiol 98.00% ; tert-Dodecanethiol 98+% ; tert-Dodecylthiol; tert-Dodecyl mercaptan; Tert Dodecyl Mercaptan,99.00 Grade A, 99.00 Grade A *; tert-Dodecanethiol_(mixture of isomers); ; Lauryl mercaptan; Dodecyl mercaptan; tert-Dodecanethiol; tert-Dodecyl mercaptane; tert-Dodecanethiol (mixture ofisomers); tert dodecylmercaptan ; tert-Dodecylthio 92%; tert-Dodecyl mercaptan; tert-dodecylthiol 98.0%; tert-dodecylthiol2,3,3,4,4,5-hexamethyl-2-hexanethiol; tert-Dodecylthiol 99%; tert-Dodecyl mercaptan; Sulfide Palladium Acetophenone Hydrochloric Acid Solution Mercaptan ; PEG TERT-DODECYL THIOETHER; ALPHA-(2-(TERT-DODECYLTHIO)ETHYL)-OMEGA-HYDROXYPOLY(OXY-1,2-ETHANEDIYL); DODECYLTHIOL, TERT-, ETHOXYLATED; DODECYL MERCAPTAN, TERT-, ETHOXYLATED; PEG TERT-DODECANETHIOL; POLY(OXY-1,2-ETHANEDIYL), ALPHA-(2 (TERT DODECYLTHIO)ETHYL)-OMEGA-HYDROXY- TERT-DODECYL MERCAPTAN, ETHOXYLATED; t-dodecanethiol; 2,2,4,6,6-Pentamethyl-4-heptanethiol [ACD/IUPAC Name]; 2,2,4,6,6-Pentaméthyl-4-heptanethiol [French] [ACD/IUPAC Name]; 2,2,4,6,6-Pentamethyl-4-heptanthiol [German] [ACD/IUPAC Name]; 2,2,4,6,6-Pentamethylheptane-4-thiol; 25103-58-6 [RN]; 296-714-7 [EINECS]; 4-Heptanethiol, 2,2,4,6,6-pentamethyl- [ACD/Index Name]; MFCD00043233 [MDL number]; tert-Dodecylmercaptan; tert-Dodecanethiol; tert-Dodecanethiol (mixture of isomers); tert-dodecylthiol; tert-Dodecyl mercaptan, ethoxylated;tert-Dodecylthio pol (ethyleneoxy) ethanol; Sphalerite flotationTert dodecyl mercaptanDensity functional theory; 2,2,4,6,6-pentamethyl-4-heptanethiol (major, representative component), tert-dodecylmercaptan, tert-laurylmercaptan, TDM, tert-DDM, Sulfole®120; Sulfide Palladium Acetophenone Hydrochloric Acid Solution Mercaptan; tert dodecil merkaptan; tersiyer dodesil merkaptan; tersıyer dodesıl merkaptan; tersıyer dodesil merkaptan; tersiyer dodesıl merkaptan; tert dodecyl mercaptan; tert dodsil merkaptan; tert dodecyl mercaptan; TERT DODECYL MERCAPTAN; TERSİYER DODECYŞ MERCAPTAN; TERSIYER DODESIL MERKAPTAN; TERSİYER DODESİL MERKAPTAN; TERSIYER DODESİL MERKAPTAN; TERSİYER DODESIL MERKAPTAN; TERT DODECYL MERCAPTAN; PEG-9-10 TERT-DODECYL THIOETHER; DODECYLTHIOL, TERT-, ETHOXYLATED (9-10 MOLES); DODECYL MERCAPTAN, TERT-, ETHOXYLATED (9-10 MOLES); PEG-9-10 TERT-DODECANETHIOL; TERT-DODECANETHIOL, ETHOXYLATED (9-10 MOLES); TERT-DODECYL MERCAPTAN, ETHOXYLATED (9-10 MOLES); tert Dodecylmercaptan;Sulfole 120;t-DDM;tert-Dodecyl Thiol;tert-Lauryl Mercaptan;2,3,3,4,4,5-Hexamethyl-2-hexanethiol;2,3,3,4,4,5-Hexamethylhexane-2-thiol;tert-Dodecylthiol;Tertiary Dodecyl Mercaptan;tert-Dodecyl Mercaptan;tert-Dodecanethiol;Tertiary Dodecyl Mercaptan;Tert Dodecyl Mercaptan; Tert-dodecyl mercaptan; tert-Dodecanethiol (mixture of isomers); dodecanethiol, mixed isomers; 2,3,3,4,4,5-hexamethylhexane-2-thiol; tert-Dodecanethiol; n-Dodecyl mercaptan; Dodecyl mercaptan; Lauryl mercaptan; Mercaptan C12; NDM; 1-Dodecanethiol; CH3(CH2)11SH; 202.40; 969337; MFCD00004885; tert-Dodecyl mercaptan; TERT-DODECANETHIOL; tert-Dodecylthiol; t-Dodecanethiol; t-Dodecylmercaptan; Sulfole 120; CCRIS 6030; t-DDM; 2,3,3,4,4,5-hexamethylhexane-2-thiol; terc.Dodecylmerkaptan [Czech]; 1,3,3,4,4,5-Hexamethyl-2-hexanethiol; EINECS 246-619-1; BRN 1738382; NCGC00091163-03; terc.Dodecylmerkaptan; AC1L1OFU; DSSTox_CID_5221; UNII-G00MDQ58TB; DSSTox_RID_77707; G00MDQ58TB; DSSTox_GSID_25221; SCHEMBL3332338; CHEMBL1325985; DTXSID1025221; YAJYJWXEWKRTPO-UHFFFAOYSA-N; Tox21_400018; AKOS015900250; LS-1066; NCGC00091163-01; NCGC00091163-02; NCGC00091163-04; LP082215; OR050371; CAS-25103-58-6; 3-01-00-01794; (Beilstein Handbook Reference); I14-10461; 119147-91-0; 90501-34-1; C12H26S; 1-Dodécanethiol; 1-Dodecanthiol; Pennfloat M; Pennfloat S; UNII:S8ZJB6X253; WNAHIZMDSQCWRP-UHFFFAOYSA-N; dodesil; dodesil merkaptan; merkaptan; dodecil; dodecil mercaptan; dodecyl mercaptane; dodesil mercaptane; dodecyl merkaptan; dodecyl merkaptane; dodesil merkaptane
Önemli
Tertiary dodecyl mercaptan (TDM) is commonly used as a chain transfer agent in the manufacturing process of styrene/butadiene latex for use in carpet and paper industries. A gas chromatographic technique has been successfully developed for the measurement of TDM based on its sulfur content for material identification, trend analysis, or for the monitoring of un-reacted residual material in final products. The method employs low thermal mass gas chromatography (LTM-GC) and a dual-plasma sulfur chemiluminescence detector (DP-SCD) to attain a high degree of sensitivity and selectivity. Using the technique described, a detection limit in the range of 0.5 ppm (v/v) TDM and less than 1 min analysis time can be achieved. Response is linear over four orders of magnitude with high degree of repeatability of less than 5% RSD. In the process of manufacturing latex such as styrene-butadiene, a chain transfer agent is required. The chain transfer agent assists in the polymerization to make products of the desired molecular distribution. Previously, chlorinated compounds such as carbon tetrachloride and chloroform have been used for this application, but because of their toxicity and negative environmental effects, it is no longer a practice to employ said compounds for the manufacturing of latex used for the carpet and paper industries. Instead, use of tertiary dodecyl mercaptan (TDM) is preferred for the applications described. As a result of the world demand for latex and the magnitude of the associated industries, TDM has become a chemical of industrial significance.
Highlights