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HYDROFLUORIC ACID (HİDROFLORİK ASİT)

HYDROFLUORIC ACID (HİDROFLORİK ASİT)

 


CAS NUMBER: 37249-79-9

 

EC NUMBER: 231-634-8

 

SYNONYMS: Hydrofluoric Acid; Acid; Fluohydric Acid; Fluorhydric Acid; Hydrofluoric; Fluohydric Acid; Fluorhydric Acid; Fluoride; Hydrogen Hydrofluoric Acid; Hydrogen Fluoride; HYDROFLUORIC ACID; Hydrogen fluoride; 7664-39-3; Fluorhydric acid fluorane; Hydrofluoride; Rubigine; Fluorwasserstoff; Antisal 2B; Fluorowodor [Polish]; Caswell No. 484; Fluorwaterstof; hydrogenfluoride; fluoric acid; Hydrogen fluoride (HF); Fluorwasserstoff; UNII-RGL5YE86CZ; UN 1790; UN 1052; RCRA waste number U134; Acido fluoridrico; Acide fluorhydrique; Acido fluorhidrico; HSDB 546; HYDROFLUORICACID; EINECS 231-634-8; UN1052; UN1790; RGL5YE86CZ; Fluorure d'hydrogene anhydre; RCRA waste no. U134; EPA Pesticide Chemical Code 045601; Fluoruro de hidrogeno anhidro; 60% HF/DMF; CHEBI:29228; 32057-09-3; Fluohydric Acid; Hydrofluoric acid 70% by weight or more HF; Hydrogen fluoride/Hydrofluoric acid (conc 50% or greater); Hydrogenfluorid; Fluorowodor; Fluorwaterstof; MFCD00011346; Acido fluoridrico; Hydrogen-fluoride; Hydrofluoric acid, ACS reagent, 48% Acido fluorhidrico; Acide fluorhydrique; Hydrofluoricum acidum; Fluorure d'hydrogene anhydre; fluorum; Fluoruro de hidrogeno anhidro; Hydridofluorine; fluoridohydrogen; Fluoro radical; hydrogen fluorid; hyrofluoric acid; Fluorohydric acid; fluorure d'hydrogene; FLUORO GROUP; AC1Q4HET; ACMC-1BAS6; Hydrogen fluoride,anhydrous; EC 231-634-8; AC1L24SO; Hydrogen fluoride, anhydrous; KSC207Q2H; HYDROFLUORIC ACID, ACS; Hydrofluoric acid, 55%, CP; [HF]; CHEMBL1232767; DTXSID1049641; CHEBI:24061; CTK1A7823; HYDROFLUORIC ACID SOLUTION; Hydrofluoric acid, AR, >=40%; KRHYYFGTRYWZRS-UHFFFAOYSA-N; MolPort-001-775-646; Hydrofluoric acid, LR, 39-43%; Hydrofluoric acid, SAJ first grade; Hydrofluoric acid, 48% ACS reagent; Hydrofluoric acid, JIS special grade; NSC750679; PC4826; HYDROFLUORIC ACID ANTIDOTE GEL; AKOS024438092; DB11072; GF10001; MCULE-2361956978 NSC-750679; RL04917; RTR-037740; TRA0025402; Hydrofluoric acid, technical, 40-45%; 37249-79-9; AN-21816; IN001918; IN005625; LS-77246; SC-75315; Hydrofluoric acid, technical grade, 68.0%; TR-037740; FT-0627129; C16487; Hydrofluoric acid, with more than 60% strength; Hydrofluoric acid, with not more than 60% strength; Hydrogen fluoride, anhydrous [UN1052] [Corrosive]; Hydrogen fluoride, anhydrous [UN1052] [Corrosive]; I04-10592; Hydrofluoric acid, for ultratrace analysis, 47-51% (T); Hydrofluoric acid, Environmental Grade, (47-51 wt% in water); Hydrofluoric acid, 48 wt. % in H2O, >=99.99% trace metals basis; Hydrofluoric acid, Environmental Grade Plus, (47-51wt % in water); Hydrofluoric acid, puriss. p.a., reag. ISO, reag. Ph. Eur., >=40%; Hydrofluoric acid, semiconductor grade VLSI PURANAL(TM) (Honeywell 17601); Hydrofluoric acid, with more than 60% strength [UN1790] [Corrosive]; Hydrofluoric acid, with more than 60% strength [UN1790] [Corrosive]; Hydrofluoric acid, with not more than 60% strength [UN1790] [Corrosive]; Hydrofluoric acid, with not more than 60% strength [UN1790] [Corrosive]; Hydrofluoric acid, p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 48.0-51.0%; Hydrofluoric acid, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., >=48%; Hydrofluoric acid, semiconductor grade MOS PURANAL(TM) (Honeywell 17928), 49.5-50.5%; Hydrofluoric acid, semiconductor grade PURANAL(TM) (Honeywell 17735), 40-41%; Hydrofluoric acid, semiconductor grade PURANAL(TM) (Honeywell 17736), 49.5-50.5%; 326604-75-5; Cytoreg (r) is pharmacologically active solution composed by 6 acids in an aqueous medium. The Active ingredient is Hydrofluoric Acid; FLO; H-F; KRHYYFGTRYWZRS-UHFFFAOYSA-N; fluorane; 750679; MW7875000; RGL5YE86CZ; MFCD00011346; Hydrofluoric acid; Hydrofluoric acid ACS reagent, 48%; 244279; Hydrofluoric acid; Hydrofluoric acid (hydrogen fluoride); 100335 | Hydrofluoric acid 40%; hydrofluoric acid burns; 1790; Hydrofluoric acid (conc. 50% or greater); Hydrogen fluoride (anhydrous); ALSURF 45; ANTISAL 2B; AQUEOUS HYDROGEN FLUORIDE (I.E., HYDROFLUORIC ACID);FLUORHYDRIC ACID; FLUORIC ACID; FLUORINE HYDRIDE (FH); FLUORINE MONOHYDRIDE; HF-A; HYDROFLUORIC ACID; HYDROFLUORIC ACID (CONC. 50% OR GREATER); HYDROFLUORIC ACID, SOLUTION; HYDROGEN FLUORIDE (HF); HYDROGEN FLUORIDE (HYDROFLUORIC ACID); HYDROGEN MONOFLUORIDE; hydro- +‎ fluoric; fluohydric; fluoric; fluoride; Hydrofluoric acid, 99.99% (metals basis) 40% min; Hydrofluoric Acid, 48.0-51.0 %, BAKER ANALYZED ACS Reagent; Hydrofluoric Acid, 48% (ACS); Hydrofluoric Acid 38-40% Extra Pure; Fluka Hydrofluoric acid ACS reagent, 48%; Hydrofluoric acid, 40.0% min., 99.99% trace metals basis; Hydrofluoric Acid, 2% (v/v); Fluka Hydrofluoric acid technical, 40-45%; Suprapur® Hydrofluoric Acid 40%; Hydrofluoric acid, ACS, 48-51%; Hydrofluoric Acid, 1% (w/v); Hydrofluoric Acid 48% For Analysis EMSURE® ACS, ISO, Reagent Ph Eur; GR ACS Hydrofluoric Acid, 48%; Hydrofluoric Acid Neutralizing Kit; Hydrofluoric Acid, 0.4% (v/v); SIAL Hydrofluoric acid; SIAL Hydrofluoric acid; Fluka Hydrofluoric acid 47-51%, TraceSELECTTM, for trace analysis; Hydrofluoric Acid, BAKER INSTRA-ANALYZED Reagent; Hydrofluoric Acid Omnitrace 500ml UN1790; Hydrofluoric Acid Omnitrace 500ml UN1790; GR ACS Hydrofluoric Acid, 48%; GR ACS Hydrofluoric Acid, 48%; Hydrofluoric acid, Environmental, 47-51%; Hydrofluoric acid, technical, 40-45%; Hydrofluoric acid, 48 wt. % in H2O, =99.99% trace metals basis; Hydrofluoric Acid, BAKER INSTRA-ANALYZED Plus; Hydrofluoric acid; Hydrofluoric Acid, 48.0-51.0 %, BAKER ANALYZED® A.C.S. Reagent; Hydrofluoric Acid, 40%, Certified AR for Analysis, Fisher Chemical; Hydrofluoric Acid 47-51%, Trace MetalTM, for Trace Metal Analysis, Fisher Chemical; Hydrofluoric Acid, 48%, Certified AR for Analysis, Fisher Chemical; Hydrofluoric Acid, 40%, Extra Pure, SLR, Fisher Chemical; Hydrofluoric Acid, 58-62%, Technical, Fisher Chemical; Hydrofluoric Acid, 48%, for Electronic Use, Fisher Chemical; Hydrofluoric Acid 47-51%, OptimaTM, for Ultra Trace Elemental Analysis, Fisher Chemical; Hydrofluoric Acid, Technical grade, Honeywell Fluka; Hydrofluoric acid, Puriss. p.a., ACS Reagent, Reag. ISO, Reag. Ph. Eur., ≥48%, Honeywell Fluka; Hydrofluoric acid, J.T.Baker; Hydrofluoric acid, Puriss. p.a., Reag. ISO, Reag. Ph. Eur., ≥40%, Honeywell Fluka; Alfa AesarTM Hydrofluoric acid, 99.99% (metals basis) 40% min ; Alfa AesarTM Hydrofluoric acid, Environmental Grade Plus, 47-51%; Hydrofluoric acid, Acros Organics; Hydrofluoric acid, Environmental Grade, 47-51%, Alfa Aesar; Hydrofluoric acid, ACS reagent, 48-51% solution in water, ACROS Organics; Hydrofluoric acid, ACS, 48-51%, Alfa Aesar; Hydrofluoric Acid, 48%, HoneywellTM Fluka; Hydrofluoric Acid, puriss., Honeywell Fluka; Hydrofluoric Acid, Baker Instra-Analyzed Reagent, USP/NF Grade, For ACS analysis, J.T.Baker; Hydrofluoric Acid, 46% J.T.Baker; Hydrofluoric Acid, 48%, AR, For ACS analysis, Macron Fine Chemicals; Hydrofluoric acid, TraceSELECTTM, Honeywell;hydrogen fluoride, pure, 37 wt.% solution in triethylamine, ACROS Organics; Hydrofluoric Acid, 10% (w/w); HİDROFLORİK ASİT; HIDROFLORIK ASIT; HYDROFLORIK ASİT; HİDROFLORIK ASIT; HİDRO FLORIK ASIT; HYDRO FLORIK ASIT; HİDRO FLORİK ASİT; HIDROFLORIKASIT; hidroflurik asit; hidroflorik asit; hidroflorikasit; hydrofluricacid; hidro florik asit; hıdro flurık asıt; hidro florik asit; hydro florık asıt; hidro florık asıt; hıdroflurıkasıt; hidroflorikasit; hydro florık asit; hidro florık acıd; flurık asıt; florık asıt; hydro; hidro; hidro flurık; hıdro florık; hidro fulurık; hıdro fulorık; hıydro florık asıt; hıdroflorık asıt;Fluohydric Acid,Fluorhydric Acid, Acid, Hydrofluoric,Fluohydric Acid,Fluorhydric Acid,Fluoride, Hydrogen,Hydrofluoric Acid,Hydrogen Fluoride; HYDROFLUORIC ACID,Hydrogen fluoride,7664-39-3,Fluorhydric; acid,Hydrofluoride,fluorane,Rubigine,Fluorwasserstoff,Antisal 2B,Fluorowodor [Polish],Caswell No. 484,Fluorwaterstof [Dutch],
hydrogenfluoride,fluoric acid,Hydrogen fluoride (HF),Fluorwasserstoff [German],UNII-RGL5YE86CZ,UN 1790 (solution),UN 1052 (anhydrous),HCRA waste number U134,Acido fluoridrico [Italian]; Acide fluorhydrique [French],Acido fluorhidrico [Spanish],HSDB 546,(3h)hydrogen fluoride,(18f)hydrogen fluoride,EINECS 2316348,UN1052,UN1790,RGL5YE86CZ,Fluorure d'hydrogene anhydre [French],RCRA waste no. U134,EPA Pesticide Chemical Code 045601,Fluoruro de hidrogeno anhidro [Spanish],CHEBI:29228,32057-09-3,Fluohydric Acid,Hydrofluoric acid 70% by weight or more HF; 14119-19-8,144923-90-0,Hydrogen fluoride/Hydrofluoric acid (conc 50% or greater),Hydrogenfluorid,Fluorowodor,FluorwaterstofMFCD00011346,Acido fluoridrico,Hydrogen-fluoride, Hydrofluoric acid, ACS reagent, 48%,Acido fluorhidrico,Acide fluorhydrique,Hydrofluoricum acidum,13981-56-1,Fluorure d'hydrogene anhydre,fluorum,Fluoruro de hidrogeno anhidro; Hydridofluorine,fluoridohydrogen,Fluoro radical,hydrogen fluorid,hyrofluoric acid,Fluorohydric acid,fluorure d'hydrogene,HYDROFLUORICACID,FLUORO GROUP,AC1Q4HET,ACMC-1BAS6; Hydrogen fluoride,anhydrous,EC 231-634-8,AC1L24SO,Hydrogen fluoride, anhydrous,KSC207Q2H,HYDROFLUORIC ACID, ACS,Hydrofluoric acid, 55%, CP,[HF];60% HF/DMF,CHEMBL1232767,DTXSID1049641,CHEBI:24061,CTK1A7823,HYDROFLUORIC ACID SOLUTION,Hydrofluoric acid, AR, >=40%,KRHYYFGTRYWZRS-UHFFFAOYSA-N,MolPort-001-775-646,YCKRFDGAMUMZLT-UHFFFAOYSA-N; KST-1A1344,KST-1A1444,Hydrofluoric acid, LR, 39-43%,Hydrofluoric acid, SAJ first grade,AR-1A0698,AR-1A4202,Hydrofluoric acid, 48% ACS reagent,Hydrofluoric acid, JIS special grade; NSC750679PC4826,HYDROFLUORIC ACID ANTIDOTE GEL,AKOS024438092,GF10001,MCULE-2361956978,NSC-750679,RL04917,RTR-037740,TRA0025402,Hydrofluoric acid, technical, 40-45%; 37249-79-9,AN-21816,IN001918,IN005625,LS-77246,SC-75315,Hydrofluoric acid, technical grade, 68.0%,TR-037740,FT-0627129,C16487,Hydrofluoric acid, with more than 60% strength; Hydrofluoric acid, with not more than 60% strength,Hydrogen fluoride, anhydrous [UN1052] [Corrosive],Hydrogen fluoride, anhydrous [UN1052] [Corrosive],I04-10592,Hydrofluoric acid, for ultratrace analysis, 47-51% (T), Hydrofluoric acid, Environmental Grade, (47-51 wt% in water),Hydrofluoric acid, 48 wt. % in H2O, >=99.99% trace metals basis,Hydrofluoric acid, Environmental Grade Plus, (47-51wt % in water); Hydrofluoric acid, puriss. p.a., reag. ISO, reag. Ph. Eur., >=40%,Hydrofluoric acid, semiconductor grade VLSI PURANAL(TM) (Honeywell 17601); Hydrofluoric acid, with more than 60% strength [UN1790] [Corrosive],Hydrofluoric acid, with more than 60% strength [UN1790] [Corrosive],Hydrofluoric acid, with not more than 60% strength [UN1790] [Corrosive]; Hydrofluoric acid, with not more than 60% strength [UN1790] [Corrosive],Hydrofluoric acid, p.a., ACS reagent, reag. ISO, reag. Ph. Eur., 48.0-51.0%
,Hydrofluoric acid, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., >=48%,Hydrofluoric acid, semiconductor grade MOS PURANAL(TM) (Honeywell 17928), 49.5-50.5%,Hydrofluoric acid, semiconductor grade PURANAL(TM) (Honeywell 17735), 40-41%; Hydrofluoric acid, semiconductor grade PURANAL(TM) (Honeywell 17736), 49.5-50.5%,326604-75-5,9F, DE Fluorwasserstoffsäure; ES Fluoruro de hidrógeno; FR Acide fluorhydrique; IT Acido fluoridrico; NL Fluorwaterstofzuur.

 

 


HİDROFLORİK ASİT

 

Kimyasal

Hidroflorik asit güçlü akrid veya keskin kokusu olan renksiz bir sıvıdır.

Belki de en iyisi, camı ve kesinlikle birçok metali, organik ve inorganik polimeri çözebilen bir asit olarak bilinir.

Hidroflorik asit, vücudun kalsiyum dengesini etkileyen eşsiz zehirlenme etkisinden dolayı en tehlikeli asitlerden biridir. Sadece palmiye büyüklüğünde bir alanın derisine doğrudan temas ölümcül olabilir.

Parçalanma ve madencilik endüstrisinde, hidroflorik asit arazideki kalıcı etkiler ve ekosistemlere giriş nedeniyle son derece tartışmalı.

 

Uygulamalar

Hidroflorik asitin baskın kullanımı, ptfe kaplamaları, soğutkanları ve farmasötik maddeleri gibi ürünlerde kullanılan flourine esaslı bileşiklerin öncüsüdür.
Petrokimyasal endüstride, hidroflorik asit, yakıt katkılarının üretiminde bir alkilasyon katalizörü olarak kullanılır ve kanal akışını iyileştirmek ve daha derin çökeltilere erişmek için kayaları eriterek çözelti enjekte ederek ekstraksiyon verimlerini artırmak için kullanılır.
Hidroflorik asit, yarıiletkenleri, silikonlu gofretleri, metalleri ve camı etch ve hazırlamak için kullanılır.
Pas ve leke çıkarma ürünlerinde bulunur.
Uranyum ve mineral arıtımında hem endüstriyel hem de laboratuar ortamlarında kullanılır.
Pompalama konuları

Hidroflorik asit için önemli pompalama hususları, toksisitesi ve kimyasal uyumluluğudur.

Hidroflorik asit son derece tehlikelidir ve deriyle veya gözlerle doğrudan temas felaket olabilir. Asit cildin derinliklerine hızla nüfuz eder ve sinir sistemini etkiler, bu nedenle ağrı başlamış veya belirli sıvının temas ettiğini bilmesinin geciktirilmesi.

Asit, kalsiyum metabolizmasını ve vücuda dolaşırken sistem toksisitesini etkilerken, hızla kalp durması, organ yetmezliği ve sonuçta saatlerce ölüm neden olabilir.

Atmosfere salınım olayı meydana geldiğinde, asit duman çıkarabilir ve insan dokusuna ve solunum sistemine saldırabilecek tehlikeli bir arka plan buharına neden olabilir.

Asit tutulmasının her şeyden önce herhangi bir bitki müdürü akıllarda olması gerektiğini açıkça belirtmektedir.

Mag sürücünün sınırlandırılması

Sızıntısız bir çözüm için uygun bir öneri, manyetik bir tahrik santrifüj pompası takmaktır. Mag tahrik pompası, sızdırma riskini ortadan kaldırır, çünkü pompa şaftı etrafında, başarısız olma riski taşıyan aşınmaya karşı mekanik keçeler yoktur. Mag tahrik pompası,% 100 sızıntısız hava geçirmez şekilde kapatılmış bir ünite için o-halkalı bir sızdırmazlık sistemi kullanır.

Bir ETFE astarlı olan Verdermag U serisi manyetik pompalar bu sızdırmazlık sistemini birleştirir ve kimyasal olarak dayanıklıdır. Hastelloy C-2000 / G-30 gibi metalik bir pompa kullanılabilir ancak birçok metal ciddi korozyona uğrar ve daha gelişmiş alaşımlar hafif korozyona uğrayacaktır. Pompanın kimyasala dirençli olması,% 100 oranında sıvı içerir.


Genel Bilgi

Kimyasal formülü HF olan zayıf bir asit türü olmasına karşın etkileri oldukça kuvvetlidir.Camı aşındırıcı etkisi olduğundan dolayı, cam şişelerde saklanamazlar. Sadece düşük yoğunluklu poli etilen plastik kaplarda saklanmalıdırlar. Susuz hidrojen florür;akışkan,renksiz,berrak ve yüksek sıcaklıkta kararlı bir sıvıdır.Son derece küçük bir molekul ve ozel bir asit oldugundan dolayi neredeyse herseyi eritip icinden geçebilir.Saf sıvı hidrojen florür elektriği iletmez fakat suda çözündüğü zaman iyonize olur ve elektriği iletebilir.İnsan vücuduna teması sonucunda acı hissi vermezken vücut içine emilerek kemiklerin erimesine yol açabilir.


Moleküler Yapısı

H F


Üretim ve Reaksiyonlar

Hidrojen florür endüstride, büyük miktarda kalsiyum florürün,sülfürik asitle muamelesi işlemiyle elde edilmektedir.

Cam aşındırma işlemlerinde gaz veya suda çözünür silikon flüorürler oluşturulması için silikon dioksit ile reaksiyona sokulması ile kullanılırlar.
SiO2 + 4 HF SiF4 (g ) + 2 H2OSiO2 + 6 HF → H2SİF6 + 2 H2O
Petrol rafinasyonunda alkilasyon olarak bilinen, izobütan hidroflorik asitten türetilen güçlü bir asit katalizör eşliğinde düşük molekül ağırlıklı alkenler ile alkile edilirek uygun kullanım sağlanmaktadır.


Kullanım Alanları

Petrol

Hidroflorik asit;yüksek oktanlı benzin üretiminde kullanılmaktadır.

Maden
Bu sektörde mineral ve kaya analiz prosesi için silikat bileşiklerini çözme yeteneği nedeniyle,kaya örneklerini eritmek amacıyla kullanılmaktadır.

Cam
Cam sektöründe camı eritebilme özelliğinden faydalanılarak şekillendirmelerinde kullanılmaktadır.

Kimya
İçeriğinde flor yapısı sayesinde bu sektörde floroorganik bileşiklerin üretiminde flor kaynağı olarak kullanılmaktadır.


Fiziksel özellikleri:

Molekül ağırlığı: 10
Kaynama noktası: 19 ° C'nin üzerindeki sıcaklıklarda gaz
Otomatik ateşleme: İlgili değil
Buhar basıncı: 150mm (26.7 ° C'de% 70 çözelti); 70mm (20.0 ° C'de% 70 çözelti)
Çözünürlük:% 70'e kadar sulu solüsyonlar,
Patlayıcı sınırlar: Uygulanamaz - yanıcı değil (Ateşe maruz kalan konteynerlerde BLEVE tehlikesi vardır)
Nakliye adı: Hidrojen florür, susuz (1052), hidroflorik asit,% 60'dan daha fazla dayanıklılık (1790)
Kimlik numarası: 1052 (hidrojen florür, susuz) (Kılavuz 125), 1790 (hidroflorik asit) (Kılavuz 157)
Tehlikeli sınıf veya bölüm: 8 (1052)
Yan tehlikeli sınıf veya bölüm: 6.1, Solunum tehlikesi (1790)
Etiket: Korozif, Zehir (toksik) (1052), Korozif, Zehir (Zehirli), Soluma Tehlikesi (1790)
Hidrojen florür, cam ve metal aşındırma, endüstriyel ve ev temizleyicileri ve pas sökücüler ve elektronik üretiminde çözelti formunda kullanılır. Tam güç, petrol rafinerilerinde yüksek oktanlı yakıtlar üretmek için kullanılır. Hidrojen floridinin diğer büyük endüstriyel kullanımları, florokarbonların sentezi (örneğin, freon ve teflon) ve alüminyum rafinde kullanılmak üzere alüminyum florür ve sentetik kryolit üretimini içerir. Aynı zamanda, nükleer yakıt olarak, çeşitli organik kimyasalların üretiminde, paslanmaz çelik üretiminde ve çeşitli diğer uygulamalar için uranyumun rafine edilmesinde de kullanılmaktadır:

Itici gazlar ve solventler
Böcek öldürücü ve gübre üretimi
Klorür imalatı ve indirimi
Fermantasyonu kontrol etmek için bira fabrikası
Leke çıkarma için kumaş endüstrisi
Tabaklama sanayi deri sanayi
İlaç ve boya üretimi
Yarı iletken imalatı.
Şu andaki ev kullanımı şunları içerir:

Pas sökücü
Alüminyum parlaklaştırıcılar
Ağır iş temizleyiciler.

 

 


HYDROFLUORIC ACID

 


Chemical

Hydrofluoric acid is a colourless fluid with a strong acrid or pungent odour.

It is perhaps best known as an acid which can dissolve glass and certainly many metals, organic and inorganic polymers.

Hydrofluoric acid sits as one of the most dangerous acids due its unique poisoning effect affecting the body calcium balance. Direct contact to the skin of just a palm-sized area can be fatal.

In the fracking and mining industry, hydrofluoric acid is highly controversial due to the residual effects on the land and introduction to ecosystems.

 


Applications

The predominant use of hydrofluoric acid is as a precursor to flourine-based compounds used in products such as ptfe coatings, refrigerants and pharmaceuticals.
In the petrochemical industry, hydrofluoric acid is used as an alkylation catalyst in the production of fuel additives and to increase extraction yields by injecting solutions by dissolving rock to improve conduit flow and access deeper deposits.
Hydrofluoric acid is used to etch and prepare semiconductors, silicon wafers, metals and glass.
Found in rust and stain removal products.
Used in uranium and mineral refining both industrial and in laboratory environments.
Pumping considerations

The key pumping considerations for hydrofluoric acid is its toxicity and chemical compatibility.

Hydrofluoric acid is extremely dangerous and any direct contact with skin or eyes can be catastrophic. The acid quickly penetrates the skin and affects the nervous system so onset of any pain or even knowing the specific fluid has made contact is delayed.

As the acid affects the calcium metabolism and system toxicity as it circulates throughout the body, it can quickly cause cardiac arrest, organ failure and eventually death in hours.

Should a release to atmosphere event occur, the acid can fume and cause a hazardous background vapour which can attack human tissue and the respiratory system.

It is quite clear that the containment of the acid should be first and foremost in the minds any plant manager.

Mag drive containment

A suitable recommendation for a leak-free solution is to install a mag drive centrifugal pump. A mag drive pump eliminates the risk of leakage as there are no wearable mechanical seals around the pump shaft which are at inherent risk of failing. The mag drive pump instead uses an o-ring sealing system for a hermetically sealed unit which is 100% leak-free.

Fitted with a lining of ETFE, a Verdermag U series mag drive pump combines this sealing system and is chemically resistant. A metallic pump may be used such as Hastelloy C-2000/G-30 however many metals are subject to severe corrosion and even more advanced alloys will suffer minor corrosion. Providing the pump is chemically resistant, it will 100% contain the fluid.

 

General Information

Although the chemical formula is a weak acid species with HF, the effects are quite strong. Because of the abrasive effect, they can not be stored in glass bottles. Only low density poly ethylene should be stored in plastic containers. Anhydrous hydrogen fluoride is a liquid stable, colorless, clear and stable at high temperature. Because it is a small molecule and a special acid, it can almost dissolve and pass almost everything. The liquid hydrogen fluoride does not transmit electricity but when it is dissolved in water it ionizes and it can transmit electricity. it can lead to the absorption of the bones by sucking into the body while not giving the feeling of pain as the result of contact with the body.


Molecular Structure

H F


Production and Reactions

Hydrogen fluoride is obtained by treatment of large amounts of calcium fluoride with sulfuric acid.

They are used by reacting with silicon dioxide to form gas or water-soluble silicone fluorides in glass etching processes.
SiO 2 + 4 HF SiF 4 (g) + 2 H 2 OSiO 2 + 6 HF → H 2 SiF 6 + 2 H 2 O
Alkylation with low molecular weight alkenes in the refinement of petroleum, in the presence of a strong acid catalyst derived from isobutane hydrofluoric acid, known as alkylation, provides convenient use.


Usage areas

Oil

Hydrofluoric acid is used in the production of high octane gasoline.

Mine
Because of its ability to solve silicate compounds for mineral and rock analysis process in this sector, it is used to dissolve rock samples.

Pine
It is used in shaping by making use of glass melting feature in glass industry.

Chemistry
It is used as a fluorine source in the production of fluoroorganic compounds in this sector thanks to the fluoride structure in its content.


Its physical properties are:

Molecular weight: 10
Boiling point: Gas at temperatures above 19°C
Auto-ignition: Not relevant
Vapor pressure: 150mm (70% solution at 26.7°C); 70mm (70% solution at 20.0°C)
Solubility: Aqueous solutions to 70%
Explosive limits: Not applicable--non-flammable (BLEVE hazard if container subjected to fire conditions)
Shipping name: Hydrogen fluoride, anhydrous (1052), hydrofluoric acid, with not more than 60% strength (1790)
Identification number: 1052 (hydrogen fluoride, anhydrous) (Guide 125), 1790 (hydrofluoric acid) (Guide 157)
Hazardous class or division: 8 (1052)
Subsidiary hazardous class or division: 6.1, Inhalation hazard (1790)
Label: Corrosive, Poison (toxic) (1052), Corrosive, Poison (Toxic), Inhalation Hazard (1790)
Hydrogen fluoride is used in solution form in glass and metal etching, industrial and home cleaners and rust removers, and in manufacturing electronics. Full strength, it is used to manufacture high-octane fuels in oil refineries. Other major industrial uses of hydrogen fluoride include synthesis of fluorocarbons (e.g., freon and Teflon) and production of aluminum fluoride and synthetic cryolite for use in aluminum refining. It is also employed in refining uranium for use as a nuclear fuel, in manufacturing various organic chemicals, in producing stainless steel, and for various other applications such as:

Propellants and solvents
Insecticide and fertilizer production
Manufacture and reduction of chlorides
Brewery to control fermentation
Fabric industry for stain removal
Leather industry for tanning
Drug and dye production
Manufacture of semiconductors.
Present household uses include:

Rust remover
Aluminum brighteners
Heavy-duty cleansers.

 

 

 

 

Ataman Kimya A.Ş. © 2015 Tüm Hakları Saklıdır.