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TETRAMETHYLTHIURAM MONOSULFIDE

Tetramethylthiuram Monosulfide's Synonyms: Tetramethylthiuram sulfide, TMTM, Tetramethyl thiuram monosulphide, Bis(dimethylthiocarbamoyl) sulfide

Tetramethylthiuram sulfide, also called TMTM or Tetramethylthiuram monosulfide, is an organosulfur compound with the formula ((CH3)2NCS)2S. 

Tetramethylthiuram monosulfide is a yellow solid that is soluble in organic solvents. 

Tetramethylthiuram monosulfide is the parent member of a large class of tetraalkylthiuram sulfides.
 

CAS Number: 97-74-5 

EC Number: 202-605-7


Properties
Chemical formula: C6H12N2S3

Linear Formula: ((H3C)2NCS)2S

Molar mass: 208.36 g·mol−1

Density: 1.39

Melting point: 107 °C (225 °F; 380 K)


Synonyms: Tetramethylthiuram sulfide, TMTM,  TETRAMETHYLTHIURAM MONOSULPHIDE, Bis(dimethylthiocarbamoyl) sulfide, [(CH3)2- NCS]2S, Tetramethylthiuram monosulfide, 1,1'-thiobis(N,N-dimethylthio-Formamide, Tetramethyl-thiodicarbonic diamide, Aceto TMTM, TMTM, Bis(dimethylthiocarbamyl) monosulfide, Tetramethylthiuramonosulfide, Bis(dimethylthiocarbamyl) sulphide, Tetramethyltrithio-Carbamic anhydride, Dimethyl-Carbamodithioic acid, anhydrosulfide, Tetramethyldithiocarbamic acid anhydrosulfide, Mono-Thiurad; Monothiuram, Tetramethylthiuram sulfide, Monosulfure de tetramethylthiurame, Thionex, N,N,N',N'-Tetramethylthiuram monosulfide, Thiuram MM, Sulfide, bis(dimethylthiocarbamoyl), UNADS

Other Names: Aceto TMTM, Bis(dimethylthiocarbamoyl) sulfide, Bis(dimethylthiocarbamoyl)sulfide, Carbamodithioic acid, dimethyl-, anhydrosulfide, Cyuram MS, Ekagom TM, Mono-thiurad, Monothiuram, Sulfide, bis((dimethylamino)thioxomethyl), Sulfide, bis(dimethylthiocarbamoyl), TMTM, TMTMS, Tetramethyldithiocarbamic acid anhydrosulfide, Tetramethylthiuram sulfide, Tetramethylthiuramide sulfide, Tetramethylthiurammonium sulfide, Thiuram MM, Thiuram monosulfide, tetramethyl-, Unads, Vulkacit MS, Vulkacit Thiuram MS



Tetramethylthiuram monosulfide is used as an activator in the sulfur vulcanization of natural and butyl rubbers.

Tetramethylthiuram monosulfide is used as an accelerator and activator in the processing of natural rubbers and butyl rubbers.

Tetramethyl thiuram monosulfide is used in manufacturing cables, tires, rubber hoses, belts, brilliant and transparent products, rubber shoes, and products resistant to heat, among other things.

Tetramethylthiuram monosulfide is widely used in the agricultural industry to protect crops from fungal diseases and in the rubber industry to accelerate the vulcanization process.

Tetramethylthiuram monosulfide is a non-staining, non-discoloring, fast-curing secondary accelerator with excellent storage stability. 
Tetramethylthiuram monosulfide can be used alone or in combination with other NR, SBR, NBR, Butyls, Neoprene, and Reclaim Rubber accelerators. 

Tetramethylthiuram monosulfide provides excellent processing safety while still allowing for high cure activity.

Unlike the thiuram disulfides, Tetramethylthiuram monosulfide will not produce cures without added elemental sulfur.


Uses

Adhesives
Diaphragms
Disinfectants, repellents, fungicides, and insecticides in agriculture
DIsulfiram (Antabuse)
Gloves (household, work, or hospital)
Leather shoes (insoles, adhesives, linings)
Medical devices
Natural rubber nitrile-butadiene and butyl rubber
Renal dialysis equipment
Rubber in undergarments and clothing
Rubber pillows and sheets
Rubber shoes (sneakers, tennis shoes, etc.)
Soaps and shampoos
Sponge makeup applicators and rubber eyelash curiers
Swimwear and toys
Tires and tubes


Tetramethylthiuram monosulfide
97-74-5
BIS(DIMETHYLTHIOCARBAMOYL) SULFIDE
TMTM
Unads
Monothiuram
Mono-thiurad
Thiuram MM
Bis(dimethylthiocarbamyl) sulfide
Aceto TMTM
TMTMS
Cyuram MS
Ekagom TM
Tetramethylthiuram sulfide
Vulkacit Thiuram MS
Vulkacit ms
Tetramethylthiuramide sulfide
Pennac MS
Tetramethylthiuram monosulphide
Usaf ek-p-6255
Usaf B-32
Tetramethylthiurammonium sulfide
Tetramethylthiuramonosulfide
Monex
Vulkacit thiuram ms/C
Thiuram monosulfide, tetramethyl-
Bis(dimethylthiocarbamyl) monosulfide
Tetramethyldithiocarbamic acid anhydrosulfide
Carbamic anhydride, tetramethyltrithio-
dimethylcarbamothioyl N,N-dimethylcarbamodithioate
Monosulfure de tetramethylthiurame
N,N,N',N'-Tetramethylthiuram monosulfide
Sulfide, bis(dimethylthiocarbamoyl)
NSC 3400
NSC 4767
Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-
Sulfide, bis((dimethylamino)thioxomethyl)
Formamide, 1,1'-thiobis(N,N-dimethylthio-
Carbamic acid, dimethyldithio-, anhydrosulfide
Carbamodithioic acid, dimethyl-, anhydrosulfide
01W430XXSQ
CHEMBL571700
DTXSID0021333
NSC4767
NSC-3400
NSC-4767
N,N-dimethyl[(dimethylcarbamothioyl)sulfanyl]carbothioamide
NCGC00159424-02
NCGC00159424-04
Sulfide, bis(dimethylthiocarbamoyl) (8CI)
Thionex rubber accelerator
N,N,N',N'-Tetramethyldicarbonotrithioic diamide
Carbamic acid, anhydrosulfide
DTXCID801333
Thiodicarbonic diamide (((H2N)C(S))2S), tetramethyl-
Carbamodithioic acid, anhydrosulfide
N,N',N'-Tetramethylthiuram monosulfide
CAS-97-74-5
Formamide,1'-thiobis[N,N-dimethylthio-
Sulfide, bis[(dimethylamino)thioxomethyl]
Bis(dimethylthiocarbamoyl)sulfide
HSDB 2902
WLN: 1N1 & YUS & SYUS & N1 & 1
EINECS 202-605-7
CP 2113
BRN 1775650
UNII-01W430XXSQ
AI3-00984
Monosulfure de tetramethylthiurame [French]
Perkacit TMTM
MFCD00014870
TMTMTMTM
EC 202-605-7
SCHEMBL23048
tetramethylthiuram-monosulfide
4-04-00-00238 (Beilstein Handbook Reference)
REQPQFUJGGOFQL-UHFFFAOYSA-
NSC3400
bis-(Dimethylthiocarbamoyl) sulfide
Tetramethylthiuram monosulfide, 97%
Thiodicarbonic diamide, tetramethyl-
Tox21_111656
Tox21_201554
Tox21_302880
BDBM50414949
BISDIMETHYLTHIOCARBAMYL SULFIDE
s2432
AKOS015850780
BISDIMETHYLTHIOCARBAMYL SULPHIDE
Tox21_111656_1
DB14178
HY-W020246
Bis(dimethylaminethiocarbonyl)monosulfide
NCGC00159424-03
NCGC00159424-05
NCGC00256325-01
NCGC00259103-01
LS-13171
CS-0039286
NS00007980
T0157
E80911
BIS(DIMETHYLTHIOCARBAMOYL) SULFIDE [HSDB]
EN300-7719162
N,N,N',N'-Tetramethyldicarbonotrithioic diamide #
SR-01000944762
SR-01000944762-1
W-100101
Q27231461
Thiodicarbonic diamide ([(H2-N)C(S)]2-S), tetramethyl-
Ethyl 2-(7-methoxy-2-oxo-2H-benzo[b][1,4]oxazin-3-yl)acetate
Thiodicarbonic diamide (((H2N)C(S))2S), N,N,N',N'-tetramethyl-
InChI=1/C6H12N2S3/c1-7(2)5(9)11-6(10)8(3)4/h1-4H3




4-04-00-00238 (Beilstein Handbook Reference)
• AI3-00984
• Aceto TMTM
• BRN 1775650
• Bis(dimethylthiocarbamoyl) sulfide
• Bis(dimethylthiocarbamoyl)sulfide
• CP 2113
• Carbamic acid, dimethyldithio-, anhydrosulfide
• Carbamic anhydride, tetramethyltrithio-
• Carbamodithioic acid, dimethyl-, anhydrosulfide
• Cyuram MS
• EINECS 202-605-7
• Ekagom TM
• Formamide, 1,1'-thiobis(N,NdimethylthioHSDB 2902
• Mono-thiurad
• Monosulfure de tetramethylthiurame
• Monosulfure de tetramethylthiurame [French]
• Monothiuram
• N,N,N',N' Tetramethylthiuram monosulfide
• NSC 3400
• NSC 4767
• Pennac MS Sulfide, bis((dimethylamino)thioxomethyl)
• TMTM
• TMTMS
• Tetramethyldithiocarbamic acid anhydrosulfide
• Tetramethylthiuram monosulfide
• Tetramethylthiuram sulfide
• Tetramethylthiuramide sulfide
• Tetramethylthiurammonium sulfide
• Tetramethylthiuramonosulfide
• Thiuram MM
• Thiuram monosulfide, tetramethyl-
• USAF B-32
• USAF EK-P-6255Unads
• Vulkacit MS
• Vulkacit Thiuram MS
• Vulkacit thiuram MS/C





Translated names
monosolfuro di tetrametiltiurame (it)

monossulfureto de tetrametiltiurama (pt)

monosulfid tetrametylotiuramu (pl)

monosulfure de tétraméthylthiurame (fr)

monosulfuro de tetrametiltiurama (es)

Tetraetüültiuraammonosulfiid (et)

tetramethylthiurammonosulfid (da)

Tetramethylthiurammonosulfid (de)

tetramethylthiurammonosulfide (nl)

tetramethylthiuramsulfid (cs)

tetrametil-tiurammonosulfid (hr)

tetrametiltiuram monosulfid (sl)

tetrametiltiuram monosulfura (ro)

tetrametiltiuram-monoszulfid (hu)

tetrametiltiurama monosulfīds (lv)

tetrametiltiuramomonosulfidas (lt)

tetrametyltiurammonosulfid (no)

tetrametyltiurammonosulfid (sv)

tetrametyltiurámmonosulfid (sk)

tetrametyylitiuraamimonosulfidi (fi)

μονοσουλφίδιο της τετραμεθυλοθειουράμης (el)

тeтраметилтиурам моносулфид (bg)





IUPAC names
Bis(dimethylthiocarbamoyl)sulfide

dimethylcarbamothioyl N,N-dimethylcarbamodithioate

N,N,N',N'-tetramethyldicarbonotrithioic diamide

N,N-dimethyl[(dimethylcarbamothioyl)sulfanyl]carbothioamide

Tetramethyl thiuram monosulfide

TETRAMETHYLTHIURAM MONOSULFIDE

Tetramethylthiuram Monosulfide

TETRAMETHYLTHIURAM MONOSULPHIDE

Tetramethylthiuram monosulphide

tetramethylthiuram monosulphide

Tetramethylthiuram monosulphide

TETRAMETHYLTHIURAM SULFIDE

Tetramethylthiurammonosulfid

TMTM




Trade names
Aceto TMTM

bis (dimethylthiocarbamyl) monosulfide

Bis(dimethylthiocarbamoyl) sulfide

Bis(dimethylthiocarbamoyl)sulfide

Bis(dimethylthiocarbamyl)sulfide

carbamic acid , dimethyldithio-anhydrosulfide

Carbamodithioic acid

Cyuram MS

dimethyl-, anhydrosulfide

Ekagom TM

EKALAND TMTM

etramethylthiurammonosulfide

Formamide, 1,1'-thiobis(N,N-dimethylthio

Monex

Mono-Thiurad

Mono-thiurad

Monosulfure de tetramethylthiurame

Monothiuram

N,N,N',N'-tetramethyldicarbonotrithioic diamide

N,N,N',N'-Tetramethylthiuram monosulfide

SAFIC-CHEM TMTM OP

Sulfide, bis((dimethylamino)thioxomethyl)

Sulfide, bis(dimethylthiocarbamoyl)

Tetramethyldithiocarbamic acid anhydrosulfide

Tetramethylthiodicarbonicdiamide

Tetramethylthiuram monosulfide

tetramethylthiuram monosulphide

Tetramethylthiuram sulfide

Tetramethylthiuramide sulfide

Tetramethylthiurammonium sulfide

Tetramethylthiuramonosulfide

Thiodicarbonic diamide (((H2N)C(S))2S), tetramethyl-

Thiodicarbonic diamide ([(H2N)C(S)]2S), N,N,N',N'-tetramethyl-

Thiodicarbonic diamide ([(H2N)C(S)]2S), tetramethyl-

Thiodicarbonic diamide, tetramrthyl

Thionex

Thiuram

Thiuram MM

Thiuram monosulfide

TMTM

TMTMS

UHOO TMTM








OTHER PRODUCTS OF ATAMAN CHEMICALS THAT MIGHT BE OF INTEREST:

Thiurams 
Tetramethylthiuram monosulfide (TMTM)
Tetramethylthiuram disulfide (TMTD)
Tetraethylthiuram disulfide (TETD)
Dipentamethylenethiuram disulfide (DPTD)
Tetraethylthiuram monosulfide (TETM)
Dipentamethylenethiuram monosulfide (DPTM)
Tetrabutylthiuram monosulfide (TBTM)
Tetrabutylthiuram disulfide (TBTD)

Dithiocarbamates 
Zinc dimethyldithiocarbamate (ZDMC)
Zinc diethyldithiocarbamate (ZDEC)
Zinc dibutyldithiocarbamate (ZDBC)
Methyl N,N-dimethyldithiocarbamate (MeDMC)
Methyl N,N-diethyldithiocarbamate (MeDEC)
Zinc pentamethylene-dithiocarbamate (ZPD)

Benzothiazoles 2- mercaptobenzothiazole (MBT)
N-cyclohexyl-2-benzothiazylsulfenamide (CBS)
Morpholinylmercaptobenzothiazole (MOR)
Dibenzothiazyle disulphide (MBTS)
2- (methyl)mercaptobenzothiazole (MBT)

Products of thiurams and mercaptobenzothiazoles
Dialkylthiocarbamyl benzothiazole Sulfide (DMTBS)
Diethylthiocarbamylbenzothiazole sulfide (DETBS



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