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HPMA

CAS: 27813-02-1;2-Hydroxy-Propyl Methacrylate ; 2-HPMA; Propylene Glycol Monomethacrylate; HPMA has very good performance of scale inhibitor and dispersant, widely used in industrial cooling water, boiler water, oil field injection, sugar mill evaporator, reverse osmosis, desalination applications, etc. especially in those of critical water condition such as high-temperature, high alkalinity, high hardness. Propylene Glycol Monomethacrylate;2-Hydroxypropyl 2-methyl-2-propenoate;2-Propenoic acid, 2-methyl-, 2-hydroxypropyl ester; Acryester HP; beta-Hydroxypropyl methacrylate; Methacrylic acid, 2-hydroxypropyl ester.;Propylene glycol monomethacrylate

Use: Hydroxypropyl methacrylate (HPMA). It is a clear, colourless liquid with a characteristic odour. It is an ester of methacrylic acid. It is relatively non-volatile, non-toxic and non-yellowing. HPMA copolymerizes readily with a wide variety of monomers, and the added hydroxyl groups improve adhesion to surfaces, incorporate cross-linking sites, and impart corrosion, fogging, and abrasion resistance, as well as contribute to low odour, colour, and volatility.




2-Hydroxy-Propyl Methacrylate (2-HPMA)
CAS: 27813-02-1

2-Hydroxypropyl Methacrylate is a clear, colorless liquid with a light unpleasant odor with molecular formula C7H12O3. It may float or sink in water.

2-HPMA contains small amounts of methacrylic acid and propylene oxide. It copolymerizes readily with a wide range of monomers. The hydroxyl groups improve adhesion to surfaces, incorporate cross-link sites, impart corrosion, fogging, and abrasion resistance, color, and volatility.


Production
2-Hydroxypropyl methacrylate monomer is manufactured by reacting methacrylic acid with propylene oxide.

Uses
2-HPMA is a monofunctional methacrylic monomer used in UV-curable inks/coatings, in the manufacture of thermosetting acrylic polyols, butadiene styrene rubber latex modifier, acrylic acid modified polyester coating, adhesives, printing inks, caprolactone monomers, coatings for automotive, water-soluble electroplate coating binder, textile treatment agent, fiber finishing agent, paper coating, appliances, sealants, Napp printing plates, photoprepolymer printing plates, detergent lubricating-oil additives, binders and metals applications.

Application such as artificial fingernail (acrylic nail) applications, dental composites adhesives, dental prosthetics, or for any application that would result in implantation or prolonged contact within the human body need a specific grade.
PRODUCT DETAILS
Product group Hydroxy (meth)acrylates
Synonym product Propylene Glycol Monomethacrylate
Package Bulk and Packed Materials
Statistics number: 2916-14-00(-90)
Cas number:27813-02-1
Cus number:38367
EC number:248-666-3

PHYSICAL PROPERTIES
Molecular weight:144.17
Specific gravity (20°C\4°C):1.024 - 1.030
Refractive index Nd (20°C):1.4489
Boiling point (°C/mmHg): 96/10, 87/5, 66/1
Specific heat (cal/g/°C):0.46
Freezing point (°C):-57
Heat of Polymerization kcal/mol: 12.1
Solubility (% 20°C) in water:21.7
Solubility (% 20°C) in water:13.4
Flash point (°C) open cup: 106

2-Hydroxypropyl methacrylate
27813-02-1
2-Hydroxypropylmethacrylate
923-26-2
HPMA
beta-Hydroxypropyl methacrylate
Acryester HP
2-Hydroxypropyl 2-methylacrylate
Poly(2-hydroxypropyl methacrylate)
2-Hydroxypropyl 2-methyl-2-propenoate
2-Propenoic acid, 2-methyl-, 2-hydroxypropyl ester
Propylene glycol monomethacrylate
2-HPMA
CHEBI:53440
2HPMA
METHACRYLIC ACID, 2-HYDROXYPROPYL ESTER
EINECS 213-090-3
25703-79-1
methacrylic acid 2-hydroxypropyl ester
BRN 1752228
2-hydroxy-n-propyl methacrylate
2-hydroxy-3-propyl methacrylate
2-Propenoic acid, 2-methyl-, 2-hydroxypropyl ester, homopolymer
Methacrylic Acid Hydroxypropyl Ester
Hydroxypropyl methacrylate (7.4cp(30 degrees c))
2-hydroxypropyl 2-methylprop-2-enoate
2-Hydroxypropyl methacrylate homopolymer
Hydroxypropyl methacrylate, 97+%, mixture of isomers, stabilized
ACMC-20ah6g
2-hydroxyproyl methacrylate
Epitope ID:131322
2-Propenoic acid, 2-methyl-, monoester with 1,2-propanediol, homopolymer
Methacrylic acid 2-hydroxypropyl
.beta.-hydroxypropyl methacrylate
CTK1A5558
1,2-Propanediol, 1-methacrylate
Poly(propylene glycol) methacrylate
2-Hydroxypropyl 2-methylacrylate #
Hydroxypropyl methacrylate,mixture of isomers
M0512
128399-EP2277565A2
2-Propenoic acid,2-methyl-,2-hydroxypropyl ester
2-Hydroxypropyl methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate) (stabilized with MEHQ)
Hydroxypropyl Methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate) (stabilized with MEHQ)
Hydroxypropyl Methacrylate, (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate) (stabilized with MEHQ)



1,2-Propanediol, monomethacrylate (8CI)
213-090-3 [EINECS]
25703-79-1 [RN]
2-hydroxypropyl 2-methylprop-2-enoate
2-Hydroxypropyl methacrylate [ACD/IUPAC Name]
2-Hydroxypropylmethacrylat [German] [ACD/IUPAC Name]
2-Propenoic acid, 2-methyl-, 2-hydroxypropyl ester [ACD/Index Name]
2-Propenoic acid, 2-methyl-, monoester with 1,2-propanediol
Méthacrylate de 2-hydroxypropyle [French] [ACD/IUPAC Name]
?-HYDROXYPROPYL METHACRYLATE
[27813-02-1]
[923-26-2]
1,2-Propanediol, 1-methacrylate
1752228
248-666-3 [EINECS]
248-666-3MFCD00004536
'27813-02-1
2HPMA
2-HPMA
2-HYDROXY PROPYL METHACRYLATE
2-hydroxy-3-propyl methacrylate
2-hydroxy-n-propyl methacrylate
2-Hydroxypropyl 2-methyl-2-propenoate
2-Hydroxypropyl 2-methylacrylate
2-hydroxypropyl methacrylate 97%
2-Hydroxypropyl2-methyl-2-propenoate
2-Hydroxypropylmethacrylate
2-methyl-2-propenoic acid 1-hydroxypropan-2-yl ester
2-Methyl-2-propenoic acid 2-hydroxypropyl ester
2-Methyl-2-propenoicaci2-hydroxypropylester
2-Propenoic acid,2-methyl-, 2-hydroxypropyl ester
Acryester HP
HPMA
HYDROXYPROPYL METHACRYLATE
Hydroxypropyl Methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate)
Hydroxypropyl methacrylate (stabilised)
Hydroxypropyl methacrylate(7.4cp(30°c))
METHACRYLIC ACID 2-HYDROXYPROPYL ESTER
Methacrylic acid hydroxypropyl ester
Methacrylic acid, 2-hydroxypropyl ester
Methacrylic acid, monoester with propane-1,2-diol
MFCD00004536 [MDL number]
MFCD00051317
Propylene glycol monomethacrylate
β-Hydroxypropyl methacrylate
β-Hydroxypropyl methacrylate



2-Hydroxypropyl Methacrylate (HPMA)
2-Hydroxypropyl Methacrylate (HPMA) is an ester of Methacrylic acid and is used as a raw material component in the synthesis of polymers. 2-Hydroxypropyl Methacrylate (HPMA) is a functional hydrophobic hydroxy monomer consisting of a methacrylate group with a characteristic high reactivity and a cyclic hydrophobic group. 2-Hydroxypropyl Methacrylate (HPMA) forms a homopolymer and copolymers. Copolymers of 2-Hydroxypropyl Methacrylate (HPMA) can be prepared with (meth)acrylic acid and its salts, amides, and esters, as well as with (meth)acrylates, acrylonitrile, maleic acid esters, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, and other monomers.

2-Hydroxypropyl Methacrylate (HPMA) easily entering into the reaction of accession with a wide range of organic and inorganic substances, is used for the synthesis of organic low molecular weight substances.

Product Type: Methacrylate Monomer

Features & Benefits:
Chemical resistance
Hydraulic stability
Hydrophobicity
Flexibility
Adhesion
Shock resistance
Weather resistance

Applications areas:
2-Hydroxypropyl Methacrylate (HPMA) used in the preparation of solid and emulsion polymers, acrylic dispersions in combination with other (meth) acrylates, which are used in various industries, especially for textile coatings and dressings. 2-Hydroxypropyl Methacrylate (HPMA) is widely used in the production of acrylic polyols for automotive components, refurbishment coatings, and industrial coatings. 2-Hydroxypropyl methacrylate (HPMA) is also used as a comonomer in styrene-based unsaturated polyesters, PMMA-based acrylic resins, and vinyl ester formulations in anchor bolts and chemical anchors. 2-Hydroxypropyl methacrylate (HPMA) is particularly useful as a hydrophobic hydroxy monomer in the manufacture of sealants for vacuum impregnation of cast aluminum components. 2-Hydroxypropyl Methacrylate (HPMA) is also widely used in the production of flexible UV-curable photopolymer printing plates.

It is applied in the production of:
Automotive coatings
Architectural coatings
Industrial coatings
Plastics
Hygiene products
Adhesives & Sealants
Textile finishes
Modifications
Photosensitive materials
Additives for oil production and transportation
 

Chemical Properties:
Purity: min. 96.0%
Acid Value:max. 0.4%
Water content:max. 0.3%
Color APHA:max. 30
Physical Properties:
Appearance: clear
Physical form: liquid
Molecular weight:144 g/mol
Density: 1,029 g/cm3 at 20 °C
Boiling Point:80 °C(5mmHg)
Freezing Point:-57 °C
Flash point:109 °C
Melting Point: -58°
Viscosity: 6.2 mPa · s at 30 °C
Vapor Point: 0.05 mm Hg at 20 °C)
Storage & Handling:
To prevent polymerization, 2-Hydroxypropyl Methacrylate (HPMA) should always be stored in air, and never under inert gases. For the stabilizer to work effectively, oxygen is required. It must contain a stabilizer. Storage temperature should not exceed 35 °C. Under these conditions, the storage stability of one year can be expected. To minimize the likelihood of congestion, the storage procedure should strictly follow the principle of “first come, first come”. For a long shelf life of more than 4 weeks, it is advisable to replenish the oxygen content. Over time, the content of ethylene glycol diacrylate slowly increases. If this component is relevant to your process, 2-Hydroxypropyl Methacrylate (HPMA) should be used within 6 months of receipt. The preferred material for tanks and pipes is stainless steel. Carbon steel is also used, although rust formation may occur, which will lead to a problem with product quality (color). Iron (III) -ion has been shown to be a weak initiator of polymerization. If carbon steel is to be used, special treatment should be used to prepare the tank for use. Storage tanks, pumps, and pipes must be earthed.

Safety
2-Hydroxypropyl Methacrylate (HPMA) is a combustible substance. With intense healing, it forms explosive vapors with air. Vapors are heavier than air and may spread along with floors. In case of fire formation of harmful gaseous products is possible. Contact with skin may cause an allergic reaction. Flash-point is 101 °C. The ignition temperature is 355 °C. When working with 2-Hydroxypropyl Methacrylate (HPMA), sanitary rules for organizing technological processes and hygienic requirements for production equipment must be strictly observed. All types of work with GPMA should be carried out in rooms equipped with general supply and exhaust ventilation. It is not allowed to carry out work in these rooms using an open fire. Those working with 2-Hydroxypropyl Methacrylate (2-HPMA) should be provided with special clothing and personal protective equipment. In case of fire, it is necessary to use fire extinguishers OP-5, OVP-100 koshma, sand, asbestos cloth. 2-Hydroxypropyl Methacrylate (HPMA) spilled on solid soil should be covered with sand.

Note
The data presented here are based on current knowledge and experience. Given the many factors that can affect the processing and use of the product, these data do not free consumers from the need to conduct their own tests and samples. Also, these data do not imply a guarantee of any specific properties or suitability of the product for a particular application. Any descriptions, drawings, photographs, data, ratios, weights, etc. presented here. subject to change without prior notice and do not constitute the contractual quality of the product. The end-user of the product is required to comply with all property rights and existing laws, as well as legal standards.

rocryl410;Photomer 2317;2-Hydroxypropyl meth;HYDROXYPROPYL METHACRYLATE;Hydroxy propyl ethacrylate;2-HYDROXYPROYL METHACRYLATE;2-HYDROXYPROPYL METHACRYLATE;Methacrylsurehydroxypropylester;Hydroxypropyl Methacrylate HPMA;Hydroxypropyl Methacrylate 

(2-hydroxypropyl)-metakrylát (sk)
(2-hydroxypropyl)-methakrylát (cs)
2-hidroksipropil metakrilat (sl)
2-hidroksipropil-metakrilat (hr)
2-hidroksipropilmetakrilatas (lt)
2-hidroksipropilmetakrilāts (lv)
2-hidroxipropil metacrilat (ro)
2-hidroxipropil-metakrilát (hu)
2-hydroksipropyylimetakrylaatti (fi)
2-hydroksypropylmetakrylat (no)
2-hydroxipropylmetakrylat (sv)
2-hydroxypropylmethacrylaat (nl)
2-hydroxypropylmethacrylat (da)
2-Hydroxypropylmethacrylat (de)
2-hüdroksüpropüülmetakrülaat (et)
2-хидроксипропил метакрилат (bg)
ester 2-hydroksypropylowy kwasu metakrylowego (pl)
metacrilato de 2-hidroxipropilo (es)
metacrilato de 2-hidroxipropilo (pt)
metacrilato di 2-idrossipropile (it)
metakrylan 2-hydroksypropylu (pl)
méthacrylate de 2-hydroxypropyle; (fr)
μεθακρυλικό 2-υδροξυπροπύλιο (el)

CAS names
2-Propenoic acid, 2-methyl-, 2-hydroxypropyl ester
IUPAC names
2-hydroxypropyl 2-methylprop-2-enoate
2-HYDROXYPROPYL METHACRYLATE
2-Hydroxypropyl methacrylate
2-hydroxypropyl methacrylate
2-Propenoic acid, 2-methyl-, 2-hydroxypropyl ester
hydroxypropyl methacrylate
Polyethylene Glycol Dimethacrylate

2-Hydroxypropyl methacrylate Chemical Properties,Uses,Production
Chemical Properties
Clear colorless liquid
Uses
Monomer for acrylic resins, nonwoven fabric binders, detergent lubricating-oil additives.
General Description
White liquid with a light unpleasant odor. May float or sink in water.
Reactivity Profile
2-Hydroxypropyl methacrylate polymerization: May polymerize when hot or when exposed to ultraviolet light and free-radical catalysts [USCG, 1999].
Health Hazard
Inhalation causes coughing and irritation of nose and throat; lung injury may occur. Ingestion causes irritation and burning of mouth and stomach. Contact of vapor with eyes causes irritation. Liquid may cause severe eye burns and irritation of skin.
Fire Hazard
Behavior in Fire: Compound may polymerize when hot and burst container.
2-Hydroxypropyl methacrylate Preparation Products And Raw materials
Raw materials
Methacrylic acid Propylene oxide
Preparation Products
CC-2SH adhesive composite used in anterior teeth

27813-02-1(2-Hydroxypropyl methacrylate )Related Search:
2-Hydroxyethyl methacrylate Propylparaben ISO-PROPYL ACRYLATE PROPYLENE GLYCOL Ethylene glycol diacetate PROPYLENE N-PROPYL METHACRYLATE ALLYL ACRYLATE Triethylene glycol 2-Hydroxyethyl acrylate DIISOPROPYL METHYLPHOSPHONATE Butyl methacrylate Methacrylic acid N-PROPYL ACRYLATE C8E3 Hexylene Glycol 1,4-Butanediol Methyl acrylate
2-Propenoicacid,2-methyl-,monoesterwith1,2-propanediolMETHACRYLIC ACID 2-HYDROXYPROPYL ESTERMETHACRYLIC ACID HYDROXYPROPYL ESTERHYDROXYPROPYL METHACRYLATEmethacrylic acid, monoester with propane-1,2-diolHYDROXYPROPYL METHACRYLATE, MIXTURE OF I SOMERS, STAB.HYDROXYPROPYL METHACRYLATE, 97%, MIXTURE OF ISOMERSMETHACRYLIC ACID HYDROXYPROPYL ESTER (MIXTURE OF 2-HYDROXY-N-PROPYL AND 2-HYDROXY-1-METHYLETHYL METHACRYLATE)(STABILIZED WITH MEHQ) 95+%2-HYDROXYPROYL METHACRYLATEMETHACRYLICACID,1,2-PROPANEDIOLESTERMethacrylsurehydroxypropylesterHydroxypropyl methacrylate, mixture of isomers, 98%, stab. with ca 0.02% 4-methoxyphenolHydroxypropyl Methacrylate (mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl Methacrylate) (stabilized with MEHQ)2-Hydroxypropyl methHydroxypropyl methacrylate Mixture of hydroxypropyl and hydroxyisopropyl methacrylates.beta.-Hydroxypropylmethacrylate1,2-propanediol,2-methyl,monomethacrylate1,2-propanediol,monomethacrylate2-hydroxypropylmethacrylate,mixtureofisomers2-methyl-2-propenoicaci2-hydroxymethylethylester2-Hydroxy Propyl Methacrylate (HPMA)1,2-Propandiol 2-methylpropenoateMonoester of methacrylic adid with propyleneglycolmethacrylicacid,esterwith1,2-propanediolmethacrylicacid,monoesterwith1,2-propanediolrocryl4102-HYDROXYPROPYL METHACRYLATEHydroxypropyl methacrylate, mixture of isomers, stabilized, 97+%Hydroxypropyl Methacrylate HPMA(Mixture of 2-Hydroxypropyl and 2-Hydroxy-1-Methylethyl Methacrylate) (stabilized with MEHQ)Hydroxypropyl Methacrylate Hydroxypropyl Methacrylate, 97+%, Mixture of isoMers, stabilizedMethacrylic Acid Hydroxypropyl Ester Propylene Glycol MonomethacrylateHydroxypropyl Methacrylate (stabilized with MEHQ)Hydroxy propyl ethacrylate2-HYDROXYPROPYL METHACRYLATE (MIXTURE OF2-Hydroxypropyl Methacrylate, 98%, Mixture of isoMers, stabilizedHydroxypropyl Methacrylate, Mixture of isoMers, stabilizedHydroxypropyl methacrylate, 96.5%Hydroxypropyl methacrylate, mixture of isomers, stabilized with &ap:0.02% 4-methoxyphenolPROPYLENE GLYCOL MONOMETHACRYLATEHydroxypropyl Methacrylate Mixture of hydroxypropyl and hydroxyisopropyl Methacrylates, 97%, contains 180-220 ppM MonoMethyl ether hydroquinone as inhibitorHPMA,2-Hydroxypropyl methacrylatePhotomer 23172-Hydroxypropyl Methacrylate,mixture of 2-Hydroxypropyl and 2-Hydroxy-1-methylethyl methacrylate,stabilized with MEHQHydroxypropylMethacrylate(mixtureof2-Hydroxypropyland2-Hydroxy-1-methylethylMethacrylate)(stabilizedwithMEHQ)>Hydroxypropyl Methacrylate(mixture of Hydroxypropyl and Hydoxyisopropyl Methacrylates)27813-02-1CH2CCH3CO2CH2CHOHCH3CH2CCH3COOC3H6OHOrganic Building BlocksEstersBuilding BlocksCarbonyl CompoundsC6 to C7C6 to C7MonomersAcrylic MonomersCarbonyl Compounds

2-HYDROXY PROPYL METHACRYLATE
2-Hydroxypropyl methacrylate is a monofunctional methacrylic monomer used in UV-curable inks and coatings.

Substance name:hydroxypropyl methacrylate
Trade name:2-Hydroxypropyl Methacrylate
EC no:248-666-3
CAS no:27813-02-1
HS code:29161400
Formula:C7H12O3
Synonyms:1,2-propanediol, 2-methyl, monomethacrylate / 2-propenoic acid, 2-methyl-, 2-hydroxymethylethyl ester / 2-propenoic acid, 2-methyl-, monoester with 1,2-propanediol / methacrylic acid, ester with 1,2-propanediol / methacrylic acid, monoester with 1,2-propanediol / methacrylic acid, monoester with propane-1,2-diol / propylene glycol monomethacrylate / ROCRYL 410 / Substances with a flash-point above 60 °C and not more than 100 °C / Substances with a flash-point above 60 °C and not more than 100 °C, which do not belong to another class)

Use: HPMA is a clear, colorless liquid with a pungent, sweet odor. The product contains low levels of a polymerization inhibitor along with small amounts of methacrylic acid, and propylene oxide. HPMA is used in the manufacture of acrylic polymers for adhesives, inks, and coatings for automotive, appliance and metal applications. The added hydroxyl groups improve adhesion to surfaces, incorporate cross-link sites, and impart corrosion, fogging, and abrasion resistance.

2-HYDROXYPROYL METHACRYLATE
2-Hydroxypropyl meth
1,2-propanediol,monomethacrylate
HYDROXYPROPYL METHACRYLATE
Methacrylic Acid Hydroxypropyl Ester
2-Hydroxypropyl Methacrylate
Methacrylsurehydroxypropylester
Propylene Glycol Monomethacrylate
MFCD00004536
rocryl410
Hydroxypropyl Methacrylate HPMA
EINECS 248-666-3
Hydroxy propyl ethacrylate


2-Hydroxypropyl 2-methylacrylate
beta-Hydroxypropyl methacrylate
2-Hydroxypropylmethacrylate
2-Hydroxypropyl 2-methyl-2-propenoate
2-Hydroxypropyl methacrylate
HPMA2-HPMA
methacrylic acid 2-hydroxypropyl ester
2HPMA
propylene glycol monomethacrylate
2-hydroxy-n-propyl methacrylate
2-hydroxy-3-propyl methacrylate


2-Hydroxypropyl 2-methylacrylate
beta-Hydroxypropyl methacrylate
2-Hydroxypropylmethacrylate
2-Hydroxypropyl 2-methyl-2-propenoate
2-Hydroxypropyl methacrylate
HPMA
2-HPMA
methacrylic acid 2-hydroxypropyl ester
2HPMA
propylene glycol monomethacrylate
2-hydroxy-n-propyl methacrylate
2-hydroxy-3-propyl methacrylate
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