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EPICHLOROHYDRIN (Glycidyl chloride)

EPICHLOROHYDRIN

CAS NUMBER: 106-89-8
EC NUMBER: 603-026-00-6

 Epichlorohydrin is a volatile and flammable, clear, colorless, liquid, chlorinated cyclic ether with an irritating, chloroform-like odor that emits toxic fumes of hydrochloric acid and

 other chlorinated compounds when heated to decomposition. Epichlorohydrin is used in the manufacture of epoxy resins, synthetic glycerin and elastomers. Exposure to epichlorohydrin

 irritates the eyes, skin and respiratory tract, and can cause chemical pneumonitis, pulmonary edema, and renal lesions

 

Epichlorohydrin (chloromethyloxirane) is an organic substance , a chloro derivative of propylene oxide, with the formula CH 2 (O) CH-CH 2 Cl. It is widely used in organic synthesis,

 used in the production of epoxy resins and glycerin. Highly toxic, irritant.

 

Epichlorohydrin is an epoxide that is 1,2-epoxypropene in which one of the methyl hydrogens is substituted by chlorine. It is an organochlorine compound and an epoxide. It derives from

 a 1,2-epoxypropane.

 

(Chloromethyl)oxirane, also known as alpha-epichlorohydrin or 1-chloro-2, 3-epoxypropane, belongs to the class of organic compounds known as epoxides. Epoxides are compounds containing a cyclic ether with three ring atoms(one oxygen and two carbon atoms) (Chloromethyl)oxirane exists as a liquid, soluble (in water), and an extremely weak basic (essentially neutral) compound (based on its pKa). Within the cell, (chloromethyl)oxirane is primarily located in the cytoplasm (Chloromethyl)oxirane can be biosynthesized from 1, 2-epoxypropane.

 

Preferred IUPAC name

2-(Chloromethyl)oxirane

Other names

(Chloromethyl)oxirane

Epichlorohydrin

1-Chloro-2,3-epoxypropane

γ-Chloropropylene oxide

Glycidyl chloride

 

Physical properties 

It is a colorless mobile transparent liquid with an irritating odor of chloroform , poorly soluble in water , well in most organic solvents. Forms an azeotropic mixture with water with a boiling point of +88 ° C and contains 75% epichlorohydrin. Forms azeotropic mixtures with a large number of organic liquids. Epichlorohydrin is optically active due to the presence of an asymmetric carbon atom [4] .

 

Chemical properties 

Epichlorohydrin is a chemically highly reactive compound with an active epoxy group and a mobile chlorine atom [5] .

 

Halogenation reaction

 

When chlorine interacts with epichlorohydrin under normal conditions, 3,3-dichloropropylene oxide (3,3-dichloroepoxypropylene) is formed [5] :

 

Hydrochlorination reaction

 

Easily adds hydrogen chloride at ordinary temperature both in solution and in anhydrous medium, with the formation of 1,3-dichlorohydrin [5] :

 

Dehydrochlorination reaction

 

In the presence of small amounts of alkali, epichlorohydrin easily attaches compounds containing one or more mobile hydrogen atoms to form chlorohydrins :

 

 

With an increase in the alkali concentration, the reaction proceeds with the elimination of hydrogen chloride and the reduction of the epoxy group, but in a different position :

 

 

Hydrolysis reaction

 

With an excess of alkali ( sodium carbonate is most often used ) and at a temperature of 100 ° C, epichlorohydrin is slowly converted into glycerin 

 

 

Hydration reaction

 

in the presence of dilute inorganic acids ( sulfuric or orthophosphoric ), epichlorohydrin forms glycerol α-monochlorohydrin 

 

As the temperature rises, the hydration of epichlorohydrin increases.

 

Esterification reaction

 

When epichlorohydrin interacts with alcohols , the epoxy ring opens with the formation of a hydroxyl group in position 2 and with the formation of an ether 

 

Amination reaction

 

Epichlorohydrin already at ordinary temperature adds ammonia or amines with ring opening 

 

Epichlorohydrin reacts with diphenylolpropane to form a polymeric diglycidal ether 

 

Diglycidether

This reaction is an example of the production of epoxy resins , which have recently become very widespread due to their exceptional properties

 

Polymerization reaction

 

Epichlorohydrin is capable of polymerizing. Depending on the catalyst used, mobile liquids, high-viscosity oils or resin-like products are obtained 

 

Application 

It is used as an intermediate for the synthesis of glycerin derivatives , dyes and surfactants ; for the production of synthetic materials (mainly epoxy resins ).

 

Toxicology and safety 

The general nature of the action 

It has an irritating and allergic effect. In experiments on animals, it selectively affects the kidneys. Penetrates the skin .

 

Epichlorohydrin is a highly toxic and flammable compound  . Epichlorohydrin vapors, when inhaled, even in small concentrations, cause nausea , dizziness and lacrimation , and with 

prolonged exposure lead to more serious consequences (often severe pulmonary edema occurs ). Epichlorohydrin on contact with the skin and prolonged contact causes dermatitis, 

up to superficial necrosis. All work with epichlorohydrin must be carried out in rubber gloves, a rubber apron, and in case of strong gas contamination in vapors - in a gas mask of 

grade A 

 

General

Systematic

name 2-chloromethyloxirane

Traditional names Epichlorohydrin,

3-chloro-1,2-epoxypropane,

chloromethyloxirane

 

(±)-Epichlorohydrin

(±)-1-Chloro-2,3-epoxypropane

(±)-1-Chloro-2,3-epoxypropane

(±)-2-(Chloromethyl)oxirane

(Chloromethyl)ethylene oxide

(DL)-α-epichlorohydrin

106-89-8 [RN]

13403-37-7 [RN]

2-(Chlormethyl)oxiran [German] [ACD/IUPAC Name]

2-(Chloromethyl)oxirane [ACD/IUPAC Name]

2-(Chlorométhyl)oxirane [French] [ACD/IUPAC Name]

203-439-8 [EINECS]

3-Chloro-1,2-propylene oxide

79785 [Beilstein]

Epichlorohydrin [Wiki]

EPICHLOROHYDRIN, (-)-

EPICHLOROHYDRIN, (+)-

Glycidyl chloride

MFCD00005132 [MDL number]

oxirane, (chloromethyl)-

Oxirane, 2-(chloromethyl)- [ACD/Index Name]

T3OTJ B1G [WLN]

TX4900000

(?)-epichlorohydrin

(±)-Epichlorohydrin

(Chloromethyl) Ethylene Oxide

(chloromethyl)-Oxirane

(DL)-α-Epichlorohydrin

(RS)-3-Chloro-1,2-epoxypropane

[106-89-8]

1,2-Epoxy-3-chloropropane

106-89-8; 13403-37-7

1-Chloor-2,3-epoxy-propaan

1-Chlor-2,3-epoxy-propan

1-Chloro-2,3-epoxy propone

1-Chloro-2,3-epoxy-Propane

1-Cloro-2,3-epossipropano

2-(Chloromethyl)-Oxirane

2-(Chloromethyl)oxirane; 1-Chloro-2,3-epoxypropane

2,3-Epoxypropyl chloride

3-Chloro-1,2-epoxypropene

3-Chloropropene-1,2-oxide

3-Chloropropyl epoxide

3-Chloro-propylene oxide

3-Chloropropylene Oxide

69533-54-6 [RN]

70735-27-2 [RN]

83385-55-1 [RN]

a-Epichlorohydrin

Allyl chloride oxide

Chloro-1,2-epoxypropane

Chloro-1,2-propylene oxide

Chloro-2,3-epoxypropane

chloromethylethylene oxide

chloromethyloxirane

Chloropropene-1,2-oxide

Chloropropyl epoxide

Chloropropylene

Chloropropylene oxide

D004811

DL-a-epichlorohydrin

Ech

EPI

Epichloorhydrine

epichlorhydrin [Wiki]

Epichlorhydrin 100 ?g/mL in Cyclohexane.

Epichlorhydrin 100 µg/mL in Cyclohexane

Epichlorhydrin 100 �g/mL in Cyclohexane

Epichlorhydrin 1000 µg/mL in Methanol

Epichlorhydrin 1000 �g/mL in Methanol

Epichlorhydrine

EPICHLORO HYDRIN

epi-Chlorohydrin

Epichlorohydrin;3-Chloro-1,2-epoxypropene;ECH

EPICHLOROHYDRIN|2-(CHLOROMETHYL)OXIRANE

Epichlorohydrine

Epichlorohydryna

Epichlorophydrin

Epicloridrina

Epoxy-3-chloropropane

Epoxypropyl chloride

Glycerol epichlorhydrin

https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:37144

InChI=1S/C3H5ClO/c4-1-3-2-5-3/h3H,1-2H2

Oxirane, 2-(chloromethyl)

Propane, 1-chloro-2,3-epoxy-

SCR89B4R6O

trans-Chloropropylene

UN 2023

VEC01H609I

WLN: T3OTJ B1G

α-epichlorohydrin

α-Epichlorohydrin

γ-chloropropylene oxide

γ-Chloropropylene oxide

环氧氯丙烷 [Chinese]

EPICHLOROHYDRIN

2-(Chloromethyl)oxirane

Epichlorhydrin

106-89-8

1-Chloro-2,3-epoxypropane

Glycidyl chloride

Oxirane, (chloromethyl)-

Epichlorhydrine

Chloromethyloxirane

1,2-Epoxy-3-chloropropane

2,3-Epoxypropyl chloride

Chloropropylene oxide

3-Chloro-1,2-epoxypropane

Glycerol epichlorhydrin

Epichloorhydrine

Glycerol epichlorohydrin

3-Chloropropylene oxide

(CHLOROMETHYL)OXIRANE

Epicloridrina

3-Chloro-1,2-propylene oxide

Epichlorohydryna

Epichlorophydrin

(Chloromethyl)ethylene oxide

alpha-Epichlorohydrin

epi-Chlorohydrin

3-Chloropropene-1,2-oxide

SKEKhG

Oxirane, 2-(chloromethyl)

(+/-)-Epichlorohydrin

Epoxypropyl chloride

gamma-Chloropropylene oxide

Propane, 1-chloro-2,3-epoxy-

1-Chlor-2,3-epoxy-propan

1-Cloro-2,3-epossipropano

2-Chloromethyl-oxirane

1-Chloor-2,3-epoxy-propaan

Rcra waste number U041

(+/-)-2-(Chloromethyl)oxirane

Allyl chloride oxide

DL-a-Epichlorohydrin

Epoxy-3-chloropropane

Caswell No. 424

(chloromethyl)-Oxirane

Chloropropylene

.alpha.-Epichlorohydrin

epichlorohydrine

Epicloridrina [Italian]

Epichloorhydrine [Dutch]

Epichlorhydrine [French]

Epichlorohydryna [Polish]

(RS)-3-chloro-1,2-epoxypropane

Alyl chloride oxide

Chloropropyl epoxide

.gamma.-Chloropropylene oxide

(DL)-.alpha.-Epichlorohydrin

3-Chloropropyl epoxide

Epichlorohydrin, 99%

Oxirane,(chloromethyl)-

Chloro-1,2-epoxypropane

Chloro-2,3-epoxypropane

Chloropropene-1,2-oxide

3-Chloro-propylene oxide

2-(chloromethyl)-oxirane

EINECS 203-439-8

UN2023

1-Chlor-2,3-epoxy-propan [German]

1-Chloor-2,3-epoxy-propaan [Dutch]

1-Cloro-2,3-epossipropano [Italian]

Chloro-1,2-propylene oxide

oxirane, 2-(chloromethyl)-

(chloromethyl) Ethylene oxide

1-chloro-2,3-epoxy-propane

1-Chloro-2,3-epoxy propone

Epichlorohydrin, >=99%

Polidexide

Oxirane, (chloromethyl)-, (R)-

Epichlorohydrin, 99%, AcroSeal(R)

Polidexidi sulfas

9009-12-5

CAS-106-89-8

C3H5ClO

Sulfate de polidexide

Sulfato de polidexido

5-17-01-00020 (Beilstein Handbook Reference)

CCRIS 6387

epichiorohydrin

Polidexidi sulfas [INN-Latin]

epi-chlorohydrine

a-Epichlorohydrin

Epichloro hydrine

Sulfate de polidexide [INN-French]

Sulfato de polidexido [INN-Spanish]

(rs)-epichlorohydrin

(+) epichlorohydrin

(-) epichlorohydrin

2-chloromethyloxirane

chloromethyl) Oxirane

(rac)-epichlorohydrin

Cardolite NC-513

racemic epichlorohydrin

beta-epoxypropylchloride

racemic epichlorohydrine

Epoxy-3-chlor opropane

3-Chloropro pylene Oxide

2-(chloromethyl) Oxirane

EC 203-439-8

(DL)-alpha-Epichlorohydrin

(RS)-(chloromethyl)oxirane

3-chloro-1,2-epoxypropene


SYNONYMS: 2-(Chloromethyl)oxirane; Epichlorhydrin; 106-89-8; 1-Chloro-2,3-epoxypropane; Glycidyl chloride; Oxirane, (chloromethyl)-; Epichlorhydrine; 1,2-Epoxy-3-Chloropropane; 2,3-Epoxypropyl chloride; Chloropropylene oxide; Chloromethyloxirane; 3-Chloro-1,2-epoxypropane; Glycerol epichlorhydrin; Epichloorhydrine; Glycerol epichlorohydrin; 3-Chloropropylene oxide; (CHLOROMETHYL)OXIRANE; Epicloridrina; 3-Chloro-1,2-propylene oxide; Epichlorohydryna; Epichlorophydrin; (Chloromethyl)ethylene oxide; alpha-Epichlorohydrin; epi-Chlorohydrin; 3-Chloropropene-1,2-oxide; SKEKhG; Oxirane, 2-(chloromethyl); Epoxypropyl chloride; gamma-Chloropropylene oxide; Propane, 1-chloro-2,3-epoxy-; 1-Chlor-2,3-epoxy-propan; 1-Cloro-2,3-epossipropano; 1-Chloor-2,3-epoxy-propaan; (+/-)-Epichlorohydrin; Rcra waste number U041; llyl chloride oxide; DL-a-Epichlorohydrin; Epoxy-3-chloropropane; Caswell No. 424; (chloromethyl)-Oxirane; Chloropropylene; .alpha.-Epichlorohydrin; Epicloridrina [Italian]; Epichloorhydrine [Dutch]; Epichlorhydrine [French]; (+/-)-2-(Chloromethyl)oxirane; Epichlorohydryna [Polish]; (RS)-3-chloro-1,2-epoxypropane; NSC 6747; lyl chloride oxide; Chloropropyl epoxide; .gamma.-Chloropropylene oxide; CCRIS 277; HSDB 39; (DL)-.alpha.-Epichlorohydrin; 2-Chloromethyl-oxirane; 3-Chloropropyl epoxide; NCI-C07001; Oxirane,(chloromethyl)-; Chloro-1,2-epoxypropane; Chloro-2,3-epoxypropane; Chloropropene-1,2-oxide; 3-Chloro-propylene oxide; 2-(chloromethyl)-oxirane; EINECS 203-439-8; UN2023; 1-Chlor-2,3-epoxy-propan [German]; RCRA waste no. U041; 1-Chloor-2,3-epoxy-propaan [Dutch]; 1-Cloro-2,3-epossipropano [Italian]; PA Pesticide Chemical Code 097201; BRN 0079785; Chloro-1,2-propylene oxide; oxirane, 2-(chloromethyl)-; (chloromethyl) Ethylene oxide; 1-chloro-2,3-epoxy-propane; -Chloro-2,3-epoxy propone; AI3-03545; CHEBI:37144; BRLQWZUYTZBJKN-UHFFFAOYSA-N; NCGC00091792-01; DSSTox_CID_566; Epichlorohydrin, >=99%; DSSTox_RID_75662; DSSTox_GSID_20566; 13403-37-7; 56227-39-5; ECH; Polidexide; Oxirane, (chloromethyl)-, (R)-; Polidexidi sulfas; 9009-12-5; CAS-106-89-8; Sulfate de polidexide; Sulfato de polidexido; 5-17-01-00020 (Beilstein Handbook Reference); CCRIS 6387; epichiorohydrin; epichlorohydrine; Polidexidi sulfas [INN-Latin]; epi-chlorohydrine; a-Epichlorohydrin; Epichloro hydrine; BRN 1420785; ()-Epichlorohydrin; Sulfate de polidexide [INN-French]; Sulfato de polidexido [INN-Spanish]; (rs)-epichlorohydrin; +) epichlorohydrin; (+)-epichlorohydrin; (-) epichlorohydrin; 2-chloromethyloxirane; chloromethyl) Oxirane; (rac)-epichlorohydrin; Cardolite NC-513; racemic epichlorohydrin; beta-epoxypropylchloride; racemic epichlorohydrine; Epichlorohydrin, 99%; Epoxy-3-chlor opropane; AC1L1PNR; AC1Q3UAD; 3-Chloropro pylene Oxide; 2-(chloromethyl) Oxirane; bmse000722; UNII-61TTR6T3SE; WLN: T3OTJ B1G; (DL)-alpha-Epichlorohydrin; (RS)-(chloromethyl)oxirane; 3-chloro-1,2-epoxypropene; 61TTR6T3SE; Epichlorohydrin Reagent Grade; ( )-2-(Chloromethyl)oxirane; CHEMBL1421613; DTXSID1020566; CTK5A4812; NSC6747; MolPort-001-779-799; BB_SC-6806; KS-00000V0U; NSC-6747; Tox21_111167; Tox21_200276; 6660AH; BBL012223; LS-409; MFCD00005132; STL163564; Epichlorohydrin [UN2023] [Poison]; AKOS000118974; KOS016039400; pichlorohydrin [UN2023] [Poison]; MCULE-9759519789; RP18559; TRA0067700; UN 2023; (+/-)-Epichlorohydrin, 99% 100g; NCGC00091792-02; NCGC00091792-03; NCGC00257830-01; BP-31004; HE027244; HE293532; HE315376; HE379166; KB-50544; SC-47193; (+/-)-Epichlorohydrin, analytical standard; KB-309491; LS-101030; TL8003414; E0012; Epichlorhydrin 100 ng/microL in Cyclohexane; FT-0625672; (+/-)-Epichlorohydrin, purum, >=99% (GC); 5717-EP2269977A2; 5717-EP2270011A1; 5717-EP2272817A1; 5717-; P2272839A1; 5717-EP2272840A1; 5717-EP2272841A1; 5717-EP2275418A1; 5717-EP2277874A1; 5717-EP2277878A1; 5717-EP2280001A1; 5717-EP2280009A1; 5717-EP2280010A2; 5717-; P2284159A1; 5717-EP2284169A1; 5717-EP2287161A1; 5717-EP2287162A1; 5717-EP2292227A2; 5717-EP2292592A1; 5717-EP2292596A2; 5717-EP2292628A2; 5717-EP2295407A1; 5717-; 2295426A1; 5717-EP2295427A1; 5717-EP2295434A2; 5717-EP2295437A1; 5717-EP2298312A1; 5717-EP2298734A2; 5717-EP2298736A1; 5717-EP2298750A1; 5717-EP2298774A1; 5717-; P2298775A1; 5717-EP2301921A1; 5717-EP2301924A1; 5717-EP2301926A1; 5717-EP2301929A1; 5717-EP2301934A1; 5717-EP2301935A1; 5717-EP2301936A1; 5717-EP2301937A1; 5717-; P2301939A1; 5717-EP2305219A1; 5717-EP2305649A1; 5717-EP2305658A1; 5717-EP2305674A1; 5717-EP2305682A1; 5717-EP2308828A2; 5717-EP2308857A1; 5717-EP2308858A1; 5717-; P2308861A1; 5717-EP2308873A1; 5717-EP2308875A1; 5717-EP2308877A1; 5717-EP2308879A1; 5717-EP2311808A1; 5717-EP2311816A1; 5717-EP2311817A1; 5717-EP2311822A1; 5717-; P2311829A1; 5717-EP2311831A1;5717-EP2311846A1; 5717-EP2314558A1; 5717-EP2314583A1; 5717-EP2314584A1; 5717-EP2314585A1; 5717-EP2316824A1; 5717-EP2316836A1; 5717-; P2371810A1; 5717-EP2371831A1; 5717-EP2372804A1; 5717-EP2374454A1; 5717-EP2378585A1; C14449; 23287-EP2270113A1; 23287-EP2270114A1; 23287-EP2272935A1; 23287-EP2275417A2;
23287-EP2277867A2; 23287-EP2280003A2; 23287-EP2280008A2; 23287-EP2280012A2; 23287-EP2284146A2; 23287-EP2284147A2; 23287-EP2284162A2; 23287-EP2284163A2; 23287-; P2285791A1; 23287-EP2286811A1; 23287-EP2292597A1; 23287-EP2295438A1; 23287-EP2298776A1; 23287-EP2301941A1; 23287-EP2305666A1; 23287-EP2308862A1; 23287-EP2308865A1; 23287-EP2314584A1; 204282-EP2277867A2; 204282-EP2280003A2; (+/-)-Epichlorohydrin, puriss., >=99.5% (GC); I14-0790; I14-1670; I14-2684; Q-201062; I14-22999; F0001-0128; Z955123632; 109351-74-8; 24969-06-0; 36250-81-4; Dextran 2-(diethyl-amino)ethyl 2-((2-(diethylamino)ethyl)diethylammonio)ethyl ether sulfate, epichlorohydrin; crosslinked; Starch, 2-(diethylamino)ethyl 2-((2-(diethylamino)ethyl)diethylammonio)ethyl ether, chloride, hydrochloride, polymer with (chloromethyl)oxirane; 1-Chloro-2,3-epoxypropane; gamma-Chloropropylene oxide; 2-(Chloromethyl)oxirane; C3H5ClO; Molecular mass: 92.5; ICSC #043; Epichlorhydrin;Epichlorohydrin;EPİKLORHİDRİN; EPIKLORHIDRIN;EPİKLOROHİDRİN;EPIKLOROHIDRIN; (+-)-Isomer;Epichlorohydrin, (S)-Isomer ;EPICHLOROHYDRIN; 2-(Chloromethyl)oxirane;Epichlorhydrin;106-89-8;1-Chloro-2,3-epoxypropane;Glycidyl chloride;Oxirane, (chloromethyl)-1,2-Epoxy-3-chloropropane;2,3-Epoxypropyl chloride 3-Chloropropylene oxide;Chloropropylene oxide;3-Chloro-1,2-epoxypropane;Chloromethyloxirane;Epichlorhydrine;Epicloridrina;Glycerol epichlorohydrin;Epichloorhydrine; Epichlorohydryna(CHLOROMETHYL)OXIRANE;Glycerol epichlorhydrin;3-Chloro-1,2-propylene oxide;(Chloromethyl)ethylene oxide;SKEKhG;alpha-Epichlorohydrin Epichlorophydrin;Oxirane, 2-(chloromethyl);3-Chloropropene-1,2-oxide;Propane, 1-chloro-2,3-epoxy-1-Chlor-2,3-epoxy-propan;1-Cloro-2,3-epossipropano epi-Chlorohydrin;1-Chloor-2,3-epoxy-propaan;Rcra waste number U041;Epoxypropyl chloride;gamma-Chloropropylene oxide;Caswell No. 424.alpha.-Epichlorohydrin; Epicloridrina [Italian];Epichloorhydrine [Dutch];Epichlorhydrine [French];Epichlorohydryna [Polish];NSC 6747;Alyl chloride oxide.gamma.-Chloropropylene oxide;CCRIS 277 ;HSDB 39;Allyl chloride oxide;(DL)-.alpha.-Epichlorohydrin;DL-a-Epichlorohydrin;Epoxy-3-chloropropane;(chloromethyl)-Oxirane;2-Chloromethyl-oxirane;(+/-)-2-(Chloromethyl)oxirane; ;NCI-C07001(RS)-3-chloro-1,2-epoxypropane;Oxirane,(chloromethyl)-;(+/-)-Epichlorohydrin;EINECS 203-439-8;UN2023;1-Chlor-2,3-epoxy-propan [German];RCRA waste no. U041; ;1-Chloor-2,3-epoxy-propaan [Dutch];1-Cloro-2,3-epossipropano [Italian];EPA Pesticide Chemical Code 097201;BRN 0079785;oxirane, 2-(chloromethyl)-;(chloromethyl) Ethylene oxide; ;AI3-03545;CHEBI:37144;BRLQWZUYTZBJKN-UHFFFAOYSA-N;NCGC00091792-01;DSSTox_CID_566;Epichlorohydrin, >=99%;Epichlorohydrin-2-13C;DSSTox_RID_75662;DSSTox_GSID_20566;;13403-37-7; ;56227-39-5;ECH;Polidexide;Oxirane, (chloromethyl)-, (R)-;Polidexidi sulfas;9009-12-5CAS-106-89-8;C3H5ClO;Sulfate de polidexide;Sulfato de polidexido;5-17-01-00020 (Beilstein Handbook Reference); ;CCRIS 6387;Chloropropylene;Polidexidi sulfas [INN-Latin];BRN 1420785;Chloropropyl epoxide;Sulfate de polidexide [INN-French];Sulfato de polidexido [INN-Spanish];2-chloromethyloxirane; ;(?)-Epichlorohydrin;chloromethyl) Oxirane;Cardolite NC-513;3-Chloropropyl epoxide;beta-epoxypropylchloride;Epichlorohydrin, 99%;Epoxy-3-chlor opropane;AC1L1PNR;AC1Q3UAD; ;3-Chloro-propylene oxide;Chloro-1,2-epoxypropan;eChloro-2,3-epoxypropane;Chloropropene-1,2-oxide;2-(chloromethyl)-oxirane;3-Chloropro pylene Oxide;2-(chloromethyl) Oxirane; bmse000722;UNII-61TTR6T3SE;WLN: T3OTJ B1G;(RS)-(chloromethyl)oxirane;3-chloro-1,2-epoxypropene;61TTR6T3SE;Chloro-1,2-propylene oxide;Epichlorohydrin Reagent Grade;1-chloro-2,3-epoxy-propane; ;1-Chloro-2,3-epoxy propone;( )-2-(Chloromethyl) xirane;CHEMBL1421613;DTXSID1020566;CTK5A4812;NSC6747;MolPort-001-779-799;BB_SC-6806;NSC-6747;Tox21_111167;Tox21_200276; ;6660AH;AR-1I7145;BBL012223;LS-409;MFCD00005132;STL163564;Epichlorohydrin [UN2023]; Poison];AKOS000118974;AKOS016039400;Epichlorohydrin [UN2023] [Poison];MCULE-9759519789;RP18559; ;TRA0067700;UN 2023;(+/-)-Epichlorohydrin, 99% 100g;NCGC00091792-02;NCGC00091792-03;NCGC00257830-01;BP-31004;HE027244;HE293532;HE315376;HE379166;KB-50544;SC-47193;(+/-)-Epichlorohydrin, analytical standard; KB-309491;LS-101030;TL8003414;E0012;FT-0625672;(+/-)-Epichlorohydrin, purum, >=99% (GC);5717-EP2269977A2; EPİKULOROHİDRİN; epikulorohidrin; epichlorohidirne; epichlorohydirne; epıkulorhıdrıne; epıkolorhıdrıne; epiklorohydirne; ebichlorohydrine; epiklorohydrine; epikolohydrin; epiklorohydrine; epiklorohıdrın; epıklorohıdrıne

 

 

 

1-CHLORO-2,3-EPOXYPROPANE is a clear colorless liquid with an irritating chloroform-like odor. Density 9.8 lb / gal. Flash point 87°F. Polymerizable. If polymerization takes place inside a closed container, the container is subject to violent rupture. Irritates the skin and respiratory system. Toxic by ingestion. A confirmed carcinogen. Vapors heavier than air. Used to make plastics and as a solvent.


Boiling point: 116°C
Melting point: (see Notes) -48°C
Relative density (water = 1): 1.2
Solubility in water, g/100 ml: 6
Vapour pressure, kPa at 20°C: 1.6
Relative vapour density (air = 1): 3.2
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.05
Flash point: 31°C c.c.
Auto-ignition temperature: 385°C
Explosive limits, vol% in air: 3.8-21
Octanol/water partition coefficient as log Pow: 0.26


Epichlorohydrin is a kind of organochlorine compound as well as epoxide. Epichlorohydrin can be used as an industrial solvent. Epichlorohydrin is a highly reactive compound, and can be used for the production of glycerol, plastics, epoxy glues and resins, and elastomers. Epichlorohydrin can also be used for the production of glycidyl nitrate and alkali chloride, used as the solvent of cellulose, resins, and paint as well as being used as an insect fumigant. In biochemistry, Epichlorohydrin can be used as a crosslinking agent for the production of Sephdex size-exclusion chromatography resins. However, Epichlorohydrin is a potential carcinogen, and can cause various kinds of side effects on respiratory tract and kidneys. Epichlorohydrin can be manufactured through the reaction between allyl chloride with hypochlorous acid as well as alcohols.


Chemical Properties
colourless liquid
Definition
ChEBI: An epoxide that is 1,2-epoxypropene in which one of the methyl hydrogens is substituted by chlorine.
Uses
Solvent for natural and synthetic resins, gums, cellulose esters and ethers, paints, varnishes, nail enamels and lacquers, cement for Celluloid. As stabilizer.
General Description
A clear colorless liquid with an irritating chloroform-like odor. Density 9.8 lb / gal. Flash point 87°F. Polymerizable. If polymerization takes place inside a closed container, the container is subject to violent rupture. Irritates the skin and respiratory system. Toxic by ingestion. A confirmed carcinogen. Vapors heavier than air. Used to make plastics and as a solvent.
Air & Water Reactions
Highly flammable. Water soluble.
Reactivity Profile
Epichlorohydrin may polymerize exothermically if heated or contaminated. Reacts explosively with aniline. Ignites on contact with potassium tert-butoxide. Reacts with trichloroethylene to give the explosive dichloroacetylene. Violent reaction with sulfuric acid or isopropylamine. Exothermic polymerization on contact with strong acids or bases, zinc, aluminum, aluminum chloride, iron, ferric chloride [Sax, 9th ed., 1996, p. 1469].
Health Hazard
Epichlorohydrin is caustic as both a liquid and gas. Irritation of the eyes and skin, and skin sensitization has been observed. Exposure to epichlorohydrin has caused inflammation of the lungs, asthmatic bronchitis, and liver and kidney damage. In acute poisonings, death may be caused by respiratory paralysis.
Fire Hazard
When heated to decomposition, Epichlorohydrin evolves highly toxic fumes of phosgene and carbon monoxide. Reactive and incompatible with strong oxidizers, strong acids, caustics, zinc, aluminum, chlorides of iron and aluminumand compounds with an active hydrogen atom, including water. Unstable, avoid heat, contaminants, strong acids and bases, certain curing agents such as ethylenediamine. Hazardous polymerization may occur.


CHEMICAL DANGERS
EPICHLOROHYDRIN will polymerize due to heating or under the influence of strong acid(s) , base(s) . On combustion, forms toxic and corrosive fumes,hydrogen chloride (see ICSC0163)andchlorine fumes (see ICSC0126). EPICHLOROHYDRIN reacts violently with strong oxidants. Reacts violently with aluminium , zinc , alcohols , phenols, amines (especially aniline), and organic acids causing fire and explosion hazard. EPICHLOROHYDRIN attacks steel in the presence of water.

Epichlorohydrin is a chlorinated epoxy compound used as an industrial solvent.EPICHLOROHYDRIN is a strong skin irritant and carcinogen.
(Chloromethyl)oxirane is used for cross-linking dextrose units in food starch (Chloromethyl)oxirane belongs to the family of Epoxides.
These are compounds containing a cyclic ether with three ring atoms(one oxygen and two carbon atoms).Molecular Formula of EPICHLOROHYDRIN is C3H5ClO.
Epichlorohydrin is mainly used in the production of epoxy resins. Acute (short-term) inhalation exposure to epichlorohydrin in the workplace has caused irritation to the eyes, respiratory tract, and skin of workers. At high levels of exposure, nausea, vomiting, cough, labored breathing, inflammation of the lung, pulmonary edema, and renal lesions may be observed in humans.
Chronic (long-term) occupational exposure of humans to epichlorohydrin in air is associated with high levels of respiratory tract illness and hematological effects.
Damage to the nasal passages, respiratory tract and kidneys have been observed in rodents exposed to epichlorohydrin by inhalation for acute or chronic duration. An increased incidence of tumors of the nasal cavity has been observed in rats exposed by inhalation.
EPA has classified epichlorohydrin as a Group B2, probable human carcinogen.EPICHLOROHYDRIN is a clear colorless liquid with an irritating chloroform-like odor. Density 9.8 lb / gal. Flash point 87°F. Polymerizable. If polymerization takes place inside a closed container,
the container is subject to violent rupture. Irritates the skin and respiratory system. Toxic by ingestion. A confirmed carcinogen. Vapors heavier than air. Used to make plastics and as a solvent.
Colorless liquid with a slightly irritating, chloroform-like odor.Epichlorohydrin is colorless liquid.Odor of Epichlorohydrin is sweet, pungent or chloroform-like ... generally perceived as a slightly irritating chloroform like odor.

The primary use of epichlorohydrin is in the production of epoxy resins used in coatings, adhesives, and plastics.
Epichlorohydrin is also used in the manufacture of synthetic glycerine, textiles, paper, inks and dyes, solvents, surfactants, and pharmaceuticals.
Epichlorohydrin is also listed as an inert ingredient in commercial pesticides.Industry Uses of Epichlorohydrin are adhesives and sealant chemicals,intermediates,solvents (which become part of product formulation or mixture).
Consumer Uses of Epichlorohydrin are Adhesives and Sealants,Paints and Coatings.

 

 

 

 

 

 

1-KLORO-2,3-EPOKSİPROPAN, berrak bir kloroform benzeri kokuya sahip berrak renksiz bir sıvıdır. Yoğunluk 9.8 lb / gal. Parlama noktası 87 ° F. Polimerleştirilebilir. Polimerizasyon kapalı bir kutunun içinde gerçekleşirse, kutu şiddetli bir kopmaya maruz kalır. Cildi ve solunum sistemini tahriş eder. Yutulduğunda zehirlidir. Karsinojen teyit edildi. Buhar havadan daha ağır. Plastik yapmak için ve solvent olarak kullanılır.


Kaynama noktası: 116 ° C
Erime noktası: (Notlara bakınız) -48 ° C
Bağıl yoğunluk (su = 1): 1.2
Suda çözünürlük, g / 100 ml: 6
Buhar basıncı, 20 ° C'de kPa: 1.6
Bağıl buhar yoğunluğu (hava = 1): 3.2
Buhar / hava karışımının 20 ° C'de (hava = 1) bağıl yoğunluğu: 1.05
Parlama noktası: 31 ° C c.c.
Kendiliğinden tutuşma sıcaklığı: 385 ° C
Patlayıcı sınırlar, hacimce havada: 3.8-21
Log Pow olarak oktanol / su ayrışma katsayısı: 0.26


Epiklorohidrin, bir tür organoklorin bileşiğinin yanı sıra epoksittir. Epichlorohydrin, endüstriyel bir çözücü olarak kullanılabilir. Epichlorohydrin oldukça reaktif bir bileşiktir ve gliserol, plastikler, epoksi yapıştırıcılar ve reçineler ve elastomerler üretiminde kullanılabilir. Epiklorohidrin glisidil nitrat ve alkali kloridin üretimi için kullanılabilir, bunlar selüloz, reçineler ve boya çözücüsü olarak kullanılırlar ve böcek fumigantı olarak kullanılırlar. Biyokimyada, Epichlorohydrin Sephdex ebat dışlama kromatografi reçinelerinin üretimi için çapraz bağlayıcı bir madde olarak kullanılabilir. Bununla birlikte, Epichlorohydrin potansiyel bir kanserojen olup solunum sistemi ve böbreklerde çeşitli yan etkilere neden olabilir. Epiklorohidrin, alil klorür ile hipokloröz asit ve alkoller arasındaki reaksiyon yoluyla üretilebilir.


Kimyasal özellikler
renksiz sıvı
Tanım
ChEBI: Metil hidrojenlerden birinin klor ile ikame edildiği 1,2-epoksipropen olan bir epoksit.

Kullanımları
Doğal ve sentetik reçineler, zamklar, selüloz esterleri ve eterler, boyalar, cilalar, çivi emayları ve vernikler, selüloit için çimento için çözücü. Stabilize edici olarak kullanılır.

Genel açıklama
Epiklorohidrin, Berrak kloroform benzeri bir kokuya sahip berrak renksiz bir sıvı. Yoğunluk 9.8 lb / gal. Parlama noktası 87 ° F. Polimerleştirilebilir. Polimerizasyon kapalı bir kutunun içinde gerçekleşirse, kutu şiddetli bir kopmaya maruz kalır. Cildi ve solunum sistemini tahriş eder. Yutulduğunda zehirlidir. Karsinojen teyit edildi. Buhar havadan daha ağır. Plastik yapmak için ve solvent olarak kullanılır.Hava ve Su Reaksiyonları, son derece yanıcı Suda çözünür.

Reaktivite Profili
Epichlorohydrin ısıtılırsa veya kirletilirse ekzotermik olarak polimerize olabilir. Anilinle patlayıcı olarak reaksiyona girer. Potasyum tert-butoksit ile temasında yanar. Patlayıcı dikloroetilen vermek üzere trikloroetilen ile reaksiyona girer. Sülfürik asit veya izopropilamin ile şiddetli reaksiyon. Güçlü asitler veya bazlarla temas halinde ekzotermik polimerizasyon, çinko, alüminyum, alüminyum klorür, demir, ferrik klorür.

Sağlık tehlikesi
Epiklorohidrin hem sıvı hem de gaz olarak kostiktir. Gözlerin ve cildin tahrişi ve cilt hassaslaşması gözlenmiştir. Epichlorohydrin'e maruz kalma akciğer iltihaplanmasına, astımlı bronşit ve karaciğer ve böbrek hasarına neden olmuştur. Akut zehirlenmelerde, ölüm solunum felcinden kaynaklanabilir.

Yangın tehlikesi
Parçalanmaya kadar ısıtıldığında, Epichlorohydrin, toksik fosgen ve karbon monoksit dumanı üretir. Güçlü oksitleyiciler, güçlü asitler, kostikler, çinko, alüminyum, demir ve alüminyum klorürleri ve aktif hidrojen atomu olan su dahil reaktif ve uyumsuz. Kararsız, ısı, kirleticiler, kuvvetli asitler ve bazlar, etilendiamin gibi bazı sertleştirici ajanlardan kaçının. Tehlikeli polimerizasyon meydana gelebilir.


KİMYASAL TEHLİKELER
EPICHLOROHYDRIN, ısıtma nedeniyle veya güçlü asit (ler), baz (lar) ın etkisi altında polimerize olacaktır. Yanma durumunda, toksik ve aşındırıcı dumanlar oluşturur, hidrojen klorür (bkz. ICSC0163) ve klor dumanları (ICSC0126'ya bakın). EPİCİLOROHİDRIN kuvvetli oksidanlarla şiddetle tepki gösterir. Alüminyum, çinko, alkoller, fenoller, aminler (özellikle anilin) ​​ve yangın ve patlama tehlikesine neden olan organik asitlerle şiddetle reaksiyona girer. EPICHLOROHYDRIN, su varlığında çeliğe saldırır.

Epichlorohydrin, endüstriyel solvent olarak kullanılan klorlu bir epoksi bileşendir. EPICHLOROHYDRIN, cildi tahriş edici ve kanserojen cildi tahriş eder.
(Klorometil) oksiran, gıda nişastasında (Klorometil) oksiranın Epoksitler ailesine ait olduğu dekstroz birimlerini çapraz bağlamak için kullanılır.
Bunlar üç halka atomlu (bir oksijen ve iki karbon atomlu) siklik bir eter içeren bileşiklerdir. EPICHLOROHYDRIN'in Moleküler Formülü C3H5ClO'dur.
Epiklorohidrin esas olarak epoksi reçinelerinin üretiminde kullanılır. İşyerinde epichlorohydrin'e akut (kısa süreli) solunum yoluyla maruz kalınması, gözler, solunum yolu ve işçiler derisinde iritasyona neden olmuştur. Yüksek seviyede maruz kalınması durumunda bulantı, kusma, öksürük, emzikli nefes alma, akciğer iltihabı, pulmoner ödem ve böbrek lezyonları insanlarda görülebilir.
Havadaki insanlardaki epichlorohydrin'e mesleki maruziyetin kronik (uzun süreli) maruziyeti, yüksek düzeyde solunum yolu hastalıkları ve hematolojik etkiler ile ilişkilidir.

Akut veya kronik süreyle inhalasyon ile epiklorohidrene maruz kalmış kemirgenlerde burun pasajları, solunum yolu ve böbrekler hasar görmüştür. İnhalasyon uygulanan sıçanlarda burun boşluğunun tümör insidansında artış görülmüştür.
EPA, epichlorohydrin'i Grup B2, olası insan kanserojeni olarak sınıflandırmıştır. EPİLHOROHİDRIN, kloroform benzeri kokusu olan açık renksiz bir sıvıdır. Yoğunluk 9.8 lb / gal. Parlama noktası 87 ° F. Polimerleştirilebilir. Polimerizasyon kapalı bir kap içinde gerçekleşirse,
konteynır şiddetli yırtılmaya maruz kalır. Cildi ve solunum sistemini tahriş eder. Yutulduğunda zehirlidir. Karsinojen teyit edildi. Buhar havadan daha ağır. Plastik yapmak için ve solvent olarak kullanılır.
Hafifçe tahriş edici, kloroform benzeri kokusu olan renksiz sıvıdır.Epiklorohidrin renksiz sıvıdır. Epiklorohidrin ürünü, tatlı, keskin kokulu veya kloroform benzeri genelde kokusu gibi hafif rahatsız edici bir kloroform olarak algılanır.

Epichlorohydrin'in birincil kullanımı, kaplamalarda, yapışkanlarda ve plastiklerde kullanılan epoksi reçinelerinin üretiminde kullanılır.
Epiklorohidrin ayrıca sentetik gliserin, tekstil, kağıt, mürekkep ve boyalar, çözücüler, sürfaktanlar ve farmasötik ürünlerin üretiminde de kullanılır.
Epichlorohydrin ayrıca ticari böcek ilacında inert bir bileşen olarak listelenmiştir. Endüstride Epichlorohydrin'in kullanımı, yapıştırıcılar ve dolgu macunu kimyasalları, ara maddeleri, çözücülerdir (ürün formülasyonunun veya karışımın parçası haline gelir).
Epichlorohydrin'in Tüketici Kullanımları Yapıştırıcılar ve Sızdırmazlık Maddeleri, Boyalar ve Kaplamalardır.

 

Epichlorohydrin is a volatile and flammable, clear, colorless, liquid, chlorinated cyclic ether with an irritating, chloroform-like odor that emits toxic fumes of hydrochloric acid and

 other chlorinated compounds when heated to decomposition. Epichlorohydrin is used in the manufacture of epoxy resins, synthetic glycerin and elastomers. Exposure to epichlorohydrin

 irritates the eyes, skin and respiratory tract, and can cause chemical pneumonitis, pulmonary edema, and renal lesions

 

Epichlorohydrin (chloromethyloxirane) is an organic substance , a chloro derivative of propylene oxide, with the formula CH 2 (O) CH-CH 2 Cl. It is widely used in organic synthesis,

 used in the production of epoxy resins and glycerin. Highly toxic, irritant.

 

Epichlorohydrin is an epoxide that is 1,2-epoxypropene in which one of the methyl hydrogens is substituted by chlorine. It is an organochlorine compound and an epoxide. It derives from

 a 1,2-epoxypropane.

 

(Chloromethyl)oxirane, also known as alpha-epichlorohydrin or 1-chloro-2, 3-epoxypropane, belongs to the class of organic compounds known as epoxides. Epoxides are compounds containing a cyclic ether with three ring atoms(one oxygen and two carbon atoms) (Chloromethyl)oxirane exists as a liquid, soluble (in water), and an extremely weak basic (essentially neutral) compound (based on its pKa). Within the cell, (chloromethyl)oxirane is primarily located in the cytoplasm (Chloromethyl)oxirane can be biosynthesized from 1, 2-epoxypropane.

 

Preferred IUPAC name

2-(Chloromethyl)oxirane

Other names

(Chloromethyl)oxirane

Epichlorohydrin

1-Chloro-2,3-epoxypropane

γ-Chloropropylene oxide

Glycidyl chloride

 

Physical properties 

It is a colorless mobile transparent liquid with an irritating odor of chloroform , poorly soluble in water , well in most organic solvents. Forms an azeotropic mixture with water with a boiling point of +88 ° C and contains 75% epichlorohydrin. Forms azeotropic mixtures with a large number of organic liquids. Epichlorohydrin is optically active due to the presence of an asymmetric carbon atom [4] .

 

Chemical properties 

Epichlorohydrin is a chemically highly reactive compound with an active epoxy group and a mobile chlorine atom [5] .

 

Halogenation reaction

 

When chlorine interacts with epichlorohydrin under normal conditions, 3,3-dichloropropylene oxide (3,3-dichloroepoxypropylene) is formed [5] :

 

Hydrochlorination reaction

 

Easily adds hydrogen chloride at ordinary temperature both in solution and in anhydrous medium, with the formation of 1,3-dichlorohydrin [5] :

 

Dehydrochlorination reaction

 

In the presence of small amounts of alkali, epichlorohydrin easily attaches compounds containing one or more mobile hydrogen atoms to form chlorohydrins :

 

 

With an increase in the alkali concentration, the reaction proceeds with the elimination of hydrogen chloride and the reduction of the epoxy group, but in a different position :

 

 

Hydrolysis reaction

 

With an excess of alkali ( sodium carbonate is most often used ) and at a temperature of 100 ° C, epichlorohydrin is slowly converted into glycerin 

 

 

Hydration reaction

 

in the presence of dilute inorganic acids ( sulfuric or orthophosphoric ), epichlorohydrin forms glycerol α-monochlorohydrin 

 

As the temperature rises, the hydration of epichlorohydrin increases.

 

Esterification reaction

 

When epichlorohydrin interacts with alcohols , the epoxy ring opens with the formation of a hydroxyl group in position 2 and with the formation of an ether 

 

Amination reaction

 

Epichlorohydrin already at ordinary temperature adds ammonia or amines with ring opening 

 

Epichlorohydrin reacts with diphenylolpropane to form a polymeric diglycidal ether 

 

Diglycidether

This reaction is an example of the production of epoxy resins , which have recently become very widespread due to their exceptional properties

 

Polymerization reaction

 

Epichlorohydrin is capable of polymerizing. Depending on the catalyst used, mobile liquids, high-viscosity oils or resin-like products are obtained 

 

Application 

It is used as an intermediate for the synthesis of glycerin derivatives , dyes and surfactants ; for the production of synthetic materials (mainly epoxy resins ).

 

Toxicology and safety 

The general nature of the action 

It has an irritating and allergic effect. In experiments on animals, it selectively affects the kidneys. Penetrates the skin .

 

Epichlorohydrin is a highly toxic and flammable compound  . Epichlorohydrin vapors, when inhaled, even in small concentrations, cause nausea , dizziness and lacrimation , and with 

prolonged exposure lead to more serious consequences (often severe pulmonary edema occurs ). Epichlorohydrin on contact with the skin and prolonged contact causes dermatitis, 

up to superficial necrosis. All work with epichlorohydrin must be carried out in rubber gloves, a rubber apron, and in case of strong gas contamination in vapors - in a gas mask of 

grade A 

 

General

Systematic

name 2-chloromethyloxirane

Traditional names Epichlorohydrin,

3-chloro-1,2-epoxypropane,

chloromethyloxirane

 

(±)-Epichlorohydrin

(±)-1-Chloro-2,3-epoxypropane

(±)-1-Chloro-2,3-epoxypropane

(±)-2-(Chloromethyl)oxirane

(Chloromethyl)ethylene oxide

(DL)-α-epichlorohydrin

106-89-8 [RN]

13403-37-7 [RN]

2-(Chlormethyl)oxiran [German] [ACD/IUPAC Name]

2-(Chloromethyl)oxirane [ACD/IUPAC Name]

2-(Chlorométhyl)oxirane [French] [ACD/IUPAC Name]

203-439-8 [EINECS]

3-Chloro-1,2-propylene oxide

79785 [Beilstein]

Epichlorohydrin [Wiki]

EPICHLOROHYDRIN, (-)-

EPICHLOROHYDRIN, (+)-

Glycidyl chloride

MFCD00005132 [MDL number]

oxirane, (chloromethyl)-

Oxirane, 2-(chloromethyl)- [ACD/Index Name]

T3OTJ B1G [WLN]

TX4900000

(?)-epichlorohydrin

(±)-Epichlorohydrin

(Chloromethyl) Ethylene Oxide

(chloromethyl)-Oxirane

(DL)-α-Epichlorohydrin

(RS)-3-Chloro-1,2-epoxypropane

[106-89-8]

1,2-Epoxy-3-chloropropane

106-89-8; 13403-37-7

1-Chloor-2,3-epoxy-propaan

1-Chlor-2,3-epoxy-propan

1-Chloro-2,3-epoxy propone

1-Chloro-2,3-epoxy-Propane

1-Cloro-2,3-epossipropano

2-(Chloromethyl)-Oxirane

2-(Chloromethyl)oxirane; 1-Chloro-2,3-epoxypropane

2,3-Epoxypropyl chloride

3-Chloro-1,2-epoxypropene

3-Chloropropene-1,2-oxide

3-Chloropropyl epoxide

3-Chloro-propylene oxide

3-Chloropropylene Oxide

69533-54-6 [RN]

70735-27-2 [RN]

83385-55-1 [RN]

a-Epichlorohydrin

Allyl chloride oxide

Chloro-1,2-epoxypropane

Chloro-1,2-propylene oxide

Chloro-2,3-epoxypropane

chloromethylethylene oxide

chloromethyloxirane

Chloropropene-1,2-oxide

Chloropropyl epoxide

Chloropropylene

Chloropropylene oxide

D004811

DL-a-epichlorohydrin

Ech

EPI

Epichloorhydrine

epichlorhydrin [Wiki]

Epichlorhydrin 100 ?g/mL in Cyclohexane.

Epichlorhydrin 100 µg/mL in Cyclohexane

Epichlorhydrin 100 �g/mL in Cyclohexane

Epichlorhydrin 1000 µg/mL in Methanol

Epichlorhydrin 1000 �g/mL in Methanol

Epichlorhydrine

EPICHLORO HYDRIN

epi-Chlorohydrin

Epichlorohydrin;3-Chloro-1,2-epoxypropene;ECH

EPICHLOROHYDRIN|2-(CHLOROMETHYL)OXIRANE

Epichlorohydrine

Epichlorohydryna

Epichlorophydrin

Epicloridrina

Epoxy-3-chloropropane

Epoxypropyl chloride

Glycerol epichlorhydrin

https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:37144

InChI=1S/C3H5ClO/c4-1-3-2-5-3/h3H,1-2H2

Oxirane, 2-(chloromethyl)

Propane, 1-chloro-2,3-epoxy-

SCR89B4R6O

trans-Chloropropylene

UN 2023

VEC01H609I

WLN: T3OTJ B1G

α-epichlorohydrin

α-Epichlorohydrin

γ-chloropropylene oxide

γ-Chloropropylene oxide

环氧氯丙烷 [Chinese]

EPICHLOROHYDRIN

2-(Chloromethyl)oxirane

Epichlorhydrin

106-89-8

1-Chloro-2,3-epoxypropane

Glycidyl chloride

Oxirane, (chloromethyl)-

Epichlorhydrine

Chloromethyloxirane

1,2-Epoxy-3-chloropropane

2,3-Epoxypropyl chloride

Chloropropylene oxide

3-Chloro-1,2-epoxypropane

Glycerol epichlorhydrin

Epichloorhydrine

Glycerol epichlorohydrin

3-Chloropropylene oxide

(CHLOROMETHYL)OXIRANE

Epicloridrina

3-Chloro-1,2-propylene oxide

Epichlorohydryna

Epichlorophydrin

(Chloromethyl)ethylene oxide

alpha-Epichlorohydrin

epi-Chlorohydrin

3-Chloropropene-1,2-oxide

SKEKhG

Oxirane, 2-(chloromethyl)

(+/-)-Epichlorohydrin

Epoxypropyl chloride

gamma-Chloropropylene oxide

Propane, 1-chloro-2,3-epoxy-

1-Chlor-2,3-epoxy-propan

1-Cloro-2,3-epossipropano

2-Chloromethyl-oxirane

1-Chloor-2,3-epoxy-propaan

Rcra waste number U041

(+/-)-2-(Chloromethyl)oxirane

Allyl chloride oxide

DL-a-Epichlorohydrin

Epoxy-3-chloropropane

Caswell No. 424

(chloromethyl)-Oxirane

Chloropropylene

.alpha.-Epichlorohydrin

epichlorohydrine

Epicloridrina [Italian]

Epichloorhydrine [Dutch]

Epichlorhydrine [French]

Epichlorohydryna [Polish]

(RS)-3-chloro-1,2-epoxypropane

Alyl chloride oxide

Chloropropyl epoxide

.gamma.-Chloropropylene oxide

(DL)-.alpha.-Epichlorohydrin

3-Chloropropyl epoxide

Epichlorohydrin, 99%

Oxirane,(chloromethyl)-

Chloro-1,2-epoxypropane

Chloro-2,3-epoxypropane

Chloropropene-1,2-oxide

3-Chloro-propylene oxide

2-(chloromethyl)-oxirane

EINECS 203-439-8

UN2023

1-Chlor-2,3-epoxy-propan [German]

1-Chloor-2,3-epoxy-propaan [Dutch]

1-Cloro-2,3-epossipropano [Italian]

Chloro-1,2-propylene oxide

oxirane, 2-(chloromethyl)-

(chloromethyl) Ethylene oxide

1-chloro-2,3-epoxy-propane

1-Chloro-2,3-epoxy propone

Epichlorohydrin, >=99%

Polidexide

Oxirane, (chloromethyl)-, (R)-

Epichlorohydrin, 99%, AcroSeal(R)

Polidexidi sulfas

9009-12-5

CAS-106-89-8

C3H5ClO

Sulfate de polidexide

Sulfato de polidexido

5-17-01-00020 (Beilstein Handbook Reference)

CCRIS 6387

epichiorohydrin

Polidexidi sulfas [INN-Latin]

epi-chlorohydrine

a-Epichlorohydrin

Epichloro hydrine

Sulfate de polidexide [INN-French]

Sulfato de polidexido [INN-Spanish]

(rs)-epichlorohydrin

(+) epichlorohydrin

(-) epichlorohydrin

2-chloromethyloxirane

chloromethyl) Oxirane

(rac)-epichlorohydrin

Cardolite NC-513

racemic epichlorohydrin

beta-epoxypropylchloride

racemic epichlorohydrine

Epoxy-3-chlor opropane

3-Chloropro pylene Oxide

2-(chloromethyl) Oxirane

EC 203-439-8

(DL)-alpha-Epichlorohydrin

(RS)-(chloromethyl)oxirane

3-chloro-1,2-epoxypropene 

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