CAS No: 109-55-7
SYNONYMS: 3-Dimethylaminopropylamine; 109-55-7; 3-(Dimethylamino)propylamine; N,N-DIMETHYL-1,3-PROPANEDIAMINE; 3-(Dimethylamino)-1-propylamine; 1,3-Propanediamine, N,N-dimethyl-; N,N-Dimethyltrimethylenediamine; N,N-dimethylpropane-1,3-diamine; 3-Aminopropyldimethylamine; N,N-Dimethylpropylenediamine; (3-aminopropyl)dimethylamine; 3-(Dimethylamino)-1-propanamine; 1-(Dimethylamino)-3-aminopropane; 3-Amino-1-(dimethylamino)propane; N,N-Dimethyl-1,3-diaminopropane; N-Dimethyltrimethylenediamine; N,N-Dimethyl-1,3-propylenediamine; Dimethylaminopropylamine; N,N-Dimethyl-N-(3-aminopropyl)amine; NSC 1067; UNII-I98I2UEC03; Propylamine, 3-(N,N-dimethylamino)-; 1-Amino-3-dimethylaminopropane; CCRIS 4799; gamma-(Dimethylamino)propylamine; HSDB 5391; 1-Amino-3-(dimethylamino)propane; .gamma.-(Dimethylamino)propylamine; EINECS 203-680-9; 3-AMINO-(DIMETHYLPROPYLAMINE); 1,3-Propanediamine, N1,N1-dimethyl-; BRN 0605293; AI3-25441; I98I2UEC03; 1-Amino-3-dimethylamino propane; IUNMPGNGSSIWFP-UHFFFAOYSA-N; N,N-dimethyl-1,3-propane diamine; N1,N1-dimethylpropane-1,3-diamine; MFCD00008216; DSSTox_CID_5102; DSSTox_RID_77667; DSSTox_GSID_25102; 3-Dimethylaminopropylamine, 99%; CAS-109-55-7; N,N`-Dimethyl-1,3-diaminopropane; 3-dimethylamino propylamine; 3-(dimethylamino)-1-aminopropane; N`,N`-dimethylpropane-1,3-diamine; N`,N`-Dimethyl propane-1,3-diamine; N,3-propylenediamine; dimethylammo propylamme; dimethyl aminopropylamine; dimethylaminopropyl amine; Dimethylaminopropyl-amine; ACMC-1BRG7; NH2CH2CH2CH2NMe2; 3-dimethylamino-propylamine; 3-dimethylaminopropyl amine; EC 203-680-9; 3-(Dimethyamino)propylamine; Cyclohexyl amineN,N-Dimethyl-1,3-propanediamine; (3-dimethylaminopropyl)amine; 3-dimethylamino-1propylamine; 3-dimethylamino-propyl amine; N,N-dimethyltrimethylendiamin; SCHEMBL30161; 3-dimethylamino-n-propylamine; KSC174K7L; 3-(dimethyl-amino)propylamine; 3-(dimethylamino) propylamine; 3-(dimethylamino)-propylamine; 3-(dimethylamino)propyl amine; 3-dimethylamino-1-propylamine; Propylamine,N-dimethylamino)-; [3-(dimethylamino)propyl]amine; H2NC3H6N(CH3)2; SCHEMBL7633005; 1-amino-3-dimethylamino-propane; 3-(dimethylamino)-n-propylamine; CHEMBL1232234; DTXSID5025102; CTK0H4575; KS-00000WMI; N,N-Dimethy-1,3-propanediamine; WLN: Z3N1&1; N,N-dimethyl-1.3-propanediamine; NSC1067; 3-(N,N-dimethylamino)propylamine; H2N(CH2)3N(CH3)2; 3-(N,N-dimethyl amino)propylamine; 3-(N,N-dimethylamino)-propylamine; N, N-dimethyl-1,3-diaminopropane; N, N-dimethyl-1,3-propanediamine; N,N-dimethyl-1, 3-propanediamine; N,N-Dimethyl-1,3-propane-diamine; N,N-dimethyl-propane-1,3-diamine; 3-Dimethylaminopropylamine (DMAPA)i n`,n`-dimethyl-1,3-propanediamine; N,N-Dimethylpropylene-1,3-diamine; N1,N1-dimethylpropan-1,3-diamine; NSC-1067; STR00957; ZINC1587811; N1,N1-dimethyl-1,3-propanediamine; Tox21_202048; Tox21_303328; AC-363; ANW-16063; BBL027699; LS-481; N,N-Di-methyl-3-amino-propyl-amine; SBB028177; STL168867; N`,N`-dimethyl-propane-1,3-diamine; N1,N1-dimethyl-propane-1,3-diamine; 3-(Dimethyl-d6-amino)-1-propylamine; 3-(N,N-dimethylamino)-1-propylamine; AKOS000119881; MCULE-9301668058; RTC-020241; TRA0008731; PROPANE,1-AMINO,3-DIMETHYLAMINO; 3-(Dimethylamino)-1-propylamine, 99%; NCGC00249155-01; NCGC00257003-01; NCGC00259597-01; H305; SC-77485; N(1),N(1)-dimethyl-propane-1,3-diamine; TC-020241; D0790; FT-0629498; N(1), N(1)-dimethyl-propane-1,3-diamine; ST45255361; 98705-EP2289890A1; 98705-EP2301928A1; J-002305; J-520165; Q5277328; 3-(Dimethylamino)-1-propylamine, analytical standard; F2187-2249; 3-(Dimethylamino)-1-propylamine, purum, >=98.0% (GC); InChI=1/C5H14N2/c1-7(2)5-3-4-6/h3-6H2,1-2H; DIMETHYLAMINOPROPYLAMINE (DMAPA); dimetil; amino; amin; metil; methyl; dimethyl; propyl; propylamıne; propylamine; propilamin; propil amin; dimethyl amino propyl amine; dimethylamino; dimethylpropyl; dimethylamino; amino propil amin; aminopropilamin; aminopropylamine; amino propyl amine; dimethylpropylamine; methylpropylamine; dmapa; mapa; DİMETİL; AMİNO; AMİN; METİL; METHYL; DİMETHYL; PROPYL; PROPYLAMINE; PROPYLAMİNE; PROPİLAMİN; PROPİL AMİN; DİMETHYL AMİNO PROPYL AMİNE; DİMETHYLAMİNO; DİMETHYLPROPYL; DİMETHYLAMİNO; AMİNO PROPİL AMİN; AMİNOPROPİLAMİN; AMİNOPROPYLAMİNE; AMİNO PROPYL AMİNE; DİMETHYLPROPYLAMİNE; METHYLPROPYLAMİNE; DMAPA; MAPA; dimetilamin; dimetil amin; dimethylamine; dimethyl amine; DİMETİLAMİN; DİMETİL AMİN; DİMETHYLAMİNE; DİMETHYL AMİNE; dimetil amino propil; dimethyl amino propyl; dimethylaminopropyl; dimetilaminopropil; DİMETİL AMİNO PROPİL; DİMETHYL AMİNO PROPYL; DİMETHYLAMİNOPROPYL; DİMETİLAMİNOPROPİL; amin; aminoa, aminometil; aminodimetil; amino dimetil; amino metil; di metil amin; di metilamin; dimetilamin; propil amin; propilamin; di metılamıno proamin; proamine;dimetilaminpropil; dimetikaminpropan; propanol; dimethylaminpropan; di metil amino propanol amin; di metil amino propmanol amino; amino propanol dimetil; amino propanol di metil; metilaminopropanolamin; dimetil; minopropmanolamino; aminopropanoldimetil; aminopropanoldimetil; metil aminopropanol amin; di metil aminopropmanol amino; aminopropanol dimetil; aminopropanol di metil; di-metil; di-methylo amin; di-metiloamino propilamine; di-metilo amino propil amine; di-metiloaminopropilamine; propilodimetil amin; di propil metil amin; di propil metilamin; dipropilmetilamin; metilo diamin propil amin; metil di amin propil amin; diaminopropylamin; diamino propyl amin; amin metil; diamino propylamin; pro-amin; metılamınopropanolamın; dımetıl; mınopropmanolamıno; amınopropanoldımetıl; amınopropanoldımetıl; metıl amınopropanol amın; dı metıl amınopropmanol amıno; amınopropanol dımetıl; amınopropanol dı metıl; dı-metıl; dı-methylo amin; dı-metıloamino propılamıne; di-metılo amıno propıl amine; dı-metıloamınopropılamıne; propılodımetıl amın; dı propıl metıl amın; dı propıl metılamın; dıpropılmetılamın; metılo dıamın propıl amın; metıl dı amın propıl amın; dıamınopropylamın; dıamıno propyl amın; amın metıl; dıamino propylamın; pro-amın; dimetilamiynopropilamiyn; di metil amiynopropil amiyn; methiyl amin propily amin; methiylamin propilyamin; methiyl amino propilyo amin; methiylaminpropilyamin; Dİ METILAMINO PROAMİN; PROAMİNE;DİMETİLAMİNPROPİL; DİMETİKAMİNPROPAN; PROPANOL; DİMETHYLAMİNPROPAN; Dİ METİL AMİNO PROPANOL AMİN; Dİ METİL AMİNO PROPMANOL AMİNO; AMİNO PROPANOL DİMETİL; AMİNO PROPANOL Dİ METİL; METİLAMİNOPROPANOLAMİN; DİMETİL; MİNOPROPMANOLAMİNO; AMİNOPROPANOLDİMETİL; AMİNOPROPANOLDİMETİL; METİL AMİNOPROPANOL AMİN; Dİ METİL AMİNOPROPMANOL AMİNO; AMİNOPROPANOL DİMETİL; AMİNOPROPANOL Dİ METİL; Dİ-METİL; Dİ-METHYLO AMİN; Dİ-METİLOAMİNO PROPİLAMİNE; Dİ-METİLO AMİNO PROPİL AMİNE; Dİ-METİLOAMİNOPROPİLAMİNE; PROPİLODİMETİL AMİN; Dİ PROPİL METİL AMİN; Dİ PROPİL METİLAMİN; DİPROPİLMETİLAMİN; METİLO DİAMİN PROPİL AMİN; METİL Dİ AMİN PROPİL AMİN; DİAMİNOPROPYLAMİN; DİAMİNO PROPYL AMİN; AMİN METİL; DİAMİNO PROPYLAMİN; PRO-AMİN; METILAMINOPROPANOLAMIN; DIMETIL; MINOPROPMANOLAMINO; AMINOPROPANOLDIMETIL; AMINOPROPANOLDIMETIL; METIL AMINOPROPANOL AMIN; DI METIL AMINOPROPMANOL AMINO; AMINOPROPANOL DIMETIL; AMINOPROPANOL DI METIL; DI-METIL; DI-METHYLO AMİN; DI-METILOAMİNO PROPILAMINE; Dİ-METILO AMINO PROPIL AMİNE; DI-METILOAMINOPROPILAMINE; PROPILODIMETIL AMIN; DI PROPIL METIL AMIN; DI PROPIL METILAMIN; DIPROPILMETILAMIN; METILO DIAMIN PROPIL AMIN; METIL DI AMIN PROPIL AMIN; DIAMINOPROPYLAMIN; DIAMINO PROPYL AMIN; AMIN METIL; DIAMİNO PROPYLAMIN; PRO-AMIN; DİMETİLAMİYNOPROPİLAMİYN; Dİ METİL AMİYNOPROPİL AMİYN; METHİYL AMİN PROPİLY AMİN; METHİYLAMİN PROPİLYAMİN; METHİYL AMİNO PROPİLYO AMİN; METHİYLAMİNPROPİLYAMİN; metilaminopropilamin; metilo aminopropilamin; metil aminpropilamin; metil amin propiyl amin; METİLAMİNOPROPİLAMİN; METİLO AMİNOPROPİLAMİN; METİL AMİNPROPİLAMİN; METİL AMİN PROPİYL AMİN
Dimethylaminopropylamine has been used for preparing good corrosion inhibitors (amine phosphates) for aviation gasoline. Heating DMAPA and urea yields a product which is useful as an octane requirement reducer.
Dimethylaminopropylamine has been used effectively for curing epoxy resins.
Derivatives of dimethylaminopropylamine have been examined in pharmaceutical applications. Diquaternary salts of DMAPA derivatives have been suggested for regulating blood pressure.
Dimethylaminopropylamine as the undiluted product is severely irritating to the eyes, skin, and mucous membranes of exposed individuals. Adequate eye and skin protection must be provided; chemical goggles with full face shield, protective clothing, and impervious gloves must be worn during handling of dimethylaminopropylamine. In case of contact, flush eyes immediately with water for at least 15 minutes, then get medical attention.
Carbon steel is a satisfactory material for storing and handling dimethylaminopropylamine. Copper, zinc, lead, or alloys containing any of these materials should not be used, since they will be attacked by the product.Carbon steel is acceptable for transfer lines. Lines should be blown or drained clean after each use. NA75: Dimethylaminopropylamine (DMAPA)
Otherwise, the product will discolor when it is left in the lines for an extended period. In cases where it is impossible to drain lines, or where the dimethylaminopropylamine is handled warm, stainless steel will be required. Since the product will leach coventional pipe dopes from threaded connections, the lines should be welded or flanged.
Dimethylaminopropylamine is a flammable material; therefore, care should be taken in handling and storage. It should be stored away from heat and open flame. It is also a corrosive material; therefore, care should be taken to avoid contact with the product.
Dimethylaminopropylamine (DMAPA) came to the attention of the National Cancer Institute (NCI) Division of Cancer Biology as the result of a review of chemical industry information suggesting an increased production or use of this chemical.
DIMETHYLAMINOPROPYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Dimethylaminopropylamine (DMAPA) is a clear, essentially colorless liquid with a typical amine odor. It is completely soluble in water, benzene, heptane, and other organic solvents.
Dimethylaminopropylamine supply requirements and can ship bulk and various packaged products to meet such needs.
Dimethylaminopropylamine is widely used in the manufacture of cosmetic raw materials such as palmitamide dimethyl propylamine, cocamidopropyl betaine, oleose amide propylamine,
Dimethylaminopropylamine (DMAPA) is a colorless to yellow liquid and moderately basic compound having amine like odour. It is miscible in water and most common organic solvents like alcohol and esters among the others. It is significantly used in the formulation of personal care products like liquid soaps, shampoos, hair conditioners, hair colors, liquid hand wash, fabric softeners, foam boosters and sun protection agents among the others. It also finds applications such as surfactants, corrosion inhibitors, anti-static agents, emulsifiers, gasoline additives and flocculating agents inclusive of others. It is used as an intermediate in the production of pharmaceuticals, dyes, agrochemicals and paper adjuvants etc. Dimethylaminopropylamine (DMAPA) is also used in water treatment solutions. The derivatives of DMAPA are used as viscosity index improvers and dispersants in lubricants.
The major application of Dimethylaminopropylamine (DMAPA) include its use as a catalyst in the production of polyurethane foam. Thus extensive use of polyurethane foam is in bedding, interiors of cars, furniture and footwear among the others. The increasing demand for polyurethane foams is likely to result in an increase in demand for Dimethylaminopropylamine (DMAPA). Thus, in turn, driving the growth of the global Dimethylaminopropylamine (DMAPA) market during the forecast period. The rising demand for personal care products is expected to drive the growth of global Dimethylaminopropylamine (DMAPA) market, because of the use of Dimethylaminopropylamine (DMAPA) as a surfactant in personal care products. On the other hand, exposure to Dimethylaminopropylamine during manufacturing process in which it is used as raw material or as an intermediate, is found to result in allergies related to skin. Also, DMAPA as an impurity in personal care products results in allergies to skin. Thus, concerns as regards the ill-effects on health arising due to the use of DMAPA, are expected to be major challenge to growth of the global Dimethylaminopropylamine (DMAPA) market during the forecast period.
Dimethylaminopropylamine = DMAPA = 3-(Dimethylamino)propylamine= 3-Aminopropyldimethylamine
Chemical synonyms: N,N-3-dimethyl-1,3-propanediamine; 1-Amino-3-dimethylaminopropane; 3-Aminopropyldimethylamine; N,N-Dimethyl-1,3-diaminopropane; N-,N-Dimethylaminopropylamine; DMAPA ; 3-(Dimethylamino)propylamine
Dimethylaminopropylamine (DMAPA) is a diamine used in the preparation of some surfactants, such as cocamidopropyl betaine which is an ingredient in many personal care products including soaps, shampoos, and cosmetics.
3-Aminopropyldimethylamine is used as an intermediate in the production of binding agents, ion-exchange materials, flocculating agents (water treatment), cosmetic agents, washing and cleaning agents (betaines), additive for petrol and other fuels, polyurethane fibres and lubricants, dyes, agrochemicals, agents used in the photographic and textile industries, etc. 3-Aminopropyldimethylamine is also used directly as a hardener in epoxy resins in the plastics industry, as a cross-linking agent for cellulose fibres in the paper industry and as an anti-shriking agent for leather.
Dimethylaminopropylamine is an Epoxy hardener.
Dimethylaminopropylamine reacts with epoxide to form 3D cross-linked thermoset structures
DMAPA is also used for the synthesis of betaines, which are widely employed in personal care products, shampoos, washing and dishwashing detergents.
DMAPA (Dimethylaminopropylamine) is a multifunctional amine used as a building block for lube oil dispersants as well as lubricity improvers and corrosion inhibitors.
DMAPA amine acts as a catalyst.
Applications of DMAPA include ether based stabstock flexible foam, microcellulars, elastomers, RIM & RRIM and rigid packaging foam.
Product Type: Crosslinking Catalysts / Accelerators / Initiators > Amine or Nitrogen Content
Dimethylaminopropylamine can be used in personal care products such as fabric softeners, liquid soaps, shampoos, and dyes.
Leather, paper, and rubber industries also use DMAPA.
Because DMAPA contains one primary and one tertiary amine group, it has numerous uses in the production of other chemicals.
Final products include agricultural chemicals, antistatic agents, binding agents, carburetor detergents, fabric softeners, flocculants, fungicides, ion exchange resins, phthalocyanine dyes, and water-resistant textile fibers.
Derivatives based on DMAPA can be used in fuels as cloud point reducers, dispersants, and stabilizers for prevention of deposits or icing and reduction of octane number requirements.
Derivatives are also used as dispersants, anti-oxidants, and corrosion inhibitors for lubricants. Water soluble cationic polyelectrolytes based on DMAPA act as flocculants in removing floating solids and oil from waste water and are used as drilling fluid in the mining industry
DMAPA also has direct uses in consumer and industrial markets:
• As an unleaded gasoline additive that improves properties to the gasoline and provides bactericidal activity
• In synthetic dyes and paints for cotton, silk, synthetics, leather, paper, hair, and special printing inks
• As a crosslinking and bonding agent for epoxy and novolak resins (Huntsman, 1995).
• To treat polyester films and fibers, thereby reducing static electricity and improving receptivity to dyes
• To stabilize polystyrene to outdoor weathering
• As an anti-shrinking agent for leather
• As a crosslinking agent for cellulose fibers in the paper industry
(DMAPA)
3-(Dimethylamino)propylamine (DMAPA) belongs to the class of 1,3-diamines. DMAPA is a versatile intermediate with a variety of applications.
3-(Dimethylamino)propylamine (DMAPA) belongs to the portfolio of 1,3-diames.
DMAPA is a weakly basic, colorless liquid.
As an intermediate it is used for example for the sythesis of agro chemicals and surfactants.
DMAPA is used in water treatment chemicals and as catalyst for PU and Epoxy polymerisations.
On the basis of application, the DMAPA market is sub-divided into Personal Care, PU Catalyst, Water Treatment, Agriculture, Pharmaceuticals, and Others.
The growth of DMAPA market is largely due increasing demand for personal care products such as shampoos, hair gel, bath preparations; textile, PU foam, agrochemicals, and others.
DMAPA appears to have a significant and increasing demand for its use in personal care products.
Dimethylaminopropylamine also has applications in the leather processing, paper, and rubber industries and is an intermediate in the production of fabric softeners, polymers, agrochemicals, flocculating agents, liquid soaps, and dye intermediates
Application Markets of Dimethylaminopropylamine :
Personal Care
PU Catalyst
Water Treatment
Agriculture
Pharmaceuticals
Others
Fuel Additive
Corrosion Inhibitor
Dyes
Textile
Coating Compositions
Dimethylaminopropylamine (DMAPA)
Product description
DMAPA is a clear colorless liquid, free of suspended matter.
DMAPA is completely miscible with water, alcohols, esters and ketones.
DMAPA has limited miscibility with diethylether, benzene, and chlorinated hydrocarbons.
DMAPA is either used on itself or as an intermediate in the production of:
Surfactants
Water treatment chemicals
Ion exchange resins
Polyurethane catalysts
Epoxy resin hardeners
Corrosion inhibitors
Gasoline and motor additives / lubricating oil additives
Textile auxiliaries
Agrochemicals
Pharmaceuticals
Paper adjuvants
Photographic adjuvants
Applications/uses of DMAPA
Cosmetic and personal care intermediate
Fabric care
Hard surface care
Home & industrial care intermediates
Soap/detergents
Preparation oF DMAPA
DMAPA is commonly produced commercially via the reaction between dimethylamine and acrylonitrile (a Michael reaction) to produce dimethylaminopropionitrile
Manufacturing Process.
DMAPA is produced in a two-stage process from acrylonitrile and dimethyl amine.
In the first stage, the reaction of the starting materials leads to raw reaction products containing approximately 99 percent 3-dimethyl aminopropionitrile.
This addition product is then hydrogenated to DMAPA and a number of byproducts in the second stage.
The byproducts are then removed from the DMAPA through multiple-stage distillation.
The remaining pure product has a DMAPA content of >99.5% (OECD, 2004).
Health effects
Dimethylaminopropylamine is a known skin irritant and its presence as an impurity in cocamidopropyl betaine is thought to be the cause of irritation experienced by some individuals.
Names
Preferred IUPAC name
N1,N1-Dimethylpropane-1,3-diamine
Other names
3-(Dimethylamino)-1-propylamine
3-Dimethylaminopropylamine
N,N-Dimethyl-1,3-propanediamine
Identifiers
CAS Number: 109-55-7
EC Number: 203-680-9
MeSH 3-dimethylaminopropylamine
PubChem CID
7993
Properties
Chemical formula: C5H14N2
Molar mass: 102.181 g·mol−1
Appearance: Colourless liquid
Odor: fishy, ammoniacal
Density: 812 mg mL−1
Boiling point: 132.1 °C; 269.7 °F; 405.2 K
log P: −0.211
Vapor pressure: 0.7–2.4 kPa
Refractive index (nD): 1.435–1.436
Chemical and Physical Properties:
Description: Colorless liquid; strong base (pK1 = 9.9; pK2 = 7.7)
Solubility: Miscible in water; soluble in organic solvents
Reactivity: Incompatible with strong oxidizing agents, acid chlorides, carbon dioxide, alipha
Thermochemistry
Heat capacity (C): 255.7 J K−1 mol−1
Std molar entropy (So298): 323.0 J K−1 mol−1
Std enthalpy of formation (ΔfH⦵298): −76.9–−76.9 kJ mol−1
Std enthalpy of combustion (ΔcH⦵298): −3.8955–−3.8875 MJ mol−1
Hazards
GHS pictograms GHS02: Flammable GHS05: Corrosive GHS07: Harmful
GHS hazard statements H226, H302, H314, H317
GHS precautionary statements P280, P305+351+338, P310
Flash point: 32 °C (90 °F; 305 K)
Explosive limits: 2.3–12.36%
Lethal dose or concentration (LD, LC):
LD50 (median dose)
487 mg kg−1 (dermal, rabbit)
1.87 g kg−1 (oral, rat)
Chemical category: Amines
Chemical family :Specialty Amine
Chemical product: Dimethylaminopropylamine
• 1,3-Propanediamine, N,N-dimethyl-
• 1-(Dimethylamino)-3-aminopropane
• 1-Amino-3-dimethylaminopropane
• 3-(Dimethylamino)-1-propanamine
• 3-(Dimethylamino)-1-propylamine
• 3-(Dimethylamino)propylamine
• 3-Amino-1-(dimethylamino)propane
• 4-04-00-01259 (Beilstein Handbook Reference)
• AI3-25441
• BRN 0605293
• CCRIS 4799
• EINECS 203-680-9
• HSDB 5391
• N,N-Dimethyl-1,3-diaminopropane
• N,N-Dimethyl-1,3-propanediamine
• N,N-Dimethyl-1,3-propylenediamine
• N,N-Dimethyl-N-(3-aminopropyl)amine
• N,N-Dimethylpropylenediamine
• N,N-Dimethyltrimethylenediamine
• N-Dimethyltrimethylenediamine
• NSC 1067
• Propylamine, 3-(N,N-dimethylamino)-
• gamma-(Dimethylamino)propylamin
DMAPA: The global DMAPA market was valued at USD 237.8 Million in 2014 and is expected to reach USD 326 Million by 2020, at a CAGR of 5.4% from 2015 to 2020.
Increasing demand from end-use industries such as personal care and automotive and increasing demand from emerging economies such as China, India, Brazil and the favorable properties of DMAPA-based products are some of the drivers for the growth of this market.
The end products of DMAPA include agricultural chemicals, antistatic agents, binding agents, carburetor detergents, water resistant textile fibers, dyes, ion exchange resins, fabric softeners, anti-shrinking agent for leathers, and others.
Among the applications of DMAPA, the personal care segment is the biggest application segment.
Betaine is manufactured from DMAPA, which is used in soaps, liquid soaps, hair care products, shampoos, bath care products, cosmetics, and so on.
Because of its mild nature and effectiveness, DMAPA is widely substituting other additives which were earlier used as ingredient in personal and household care products.
DMAPA is also used to produce an amphoteric surfactant which possesses great detergent and surfactant properties.
The personal care application segment is, so far, the biggest consumer of DMAPA.
The major products in personal care include soap, liquid soap, hair care, bath preparations, shampoos, soft soaps, and so on.
DMAPA is mild and skin friendly, and hence, it is used to produce soft soap and shampoos as it does not causes irritation to the skin and eye.
The growing preference of consumers to use more skin friendly products is the major reason for the growth of this market.
Asia-Pacific held the largest share in the global DMAPA market in 2014 and is expected to continue doing so during the forecast period.
Asia-Pacific is also the fastest-growing market during the forecast period. Wide-scale industrialization, growing economy, and growing population are the main reasons for this high growth rate.
Many global players are entering into the region due to cheap labor, easily availability of raw material, and favorable governmental rules and regulations.
3-(dimethylamino)-1-propylamine
3-dimethylaminopropylamine
3-dimethylaminopropylamine, conjugate diacid
dimethylpropanediamine
DMAPA propylamine
N,N-dimethyl-1,3-propanediamine
N1,N1-dimethyl-1,3-propylenediamine
3-Dimethylaminopropylamine
109-55-7
3-(Dimethylamino)propylamine
N,N-DIMETHYL-1,3-PROPANEDIAMINE
3-(Dimethylamino)-1-propylamine
1,3-Propanediamine, N,N-dimethyl-
3-Aminopropyldimethylamine
N,N-Dimethyltrimethylenediamine
N,N-dimethylpropane-1,3-diamine
N,N-Dimethylpropylenediamine
Dimethylaminopropylamine
3-(Dimethylamino)-1-propanamine
1-(Dimethylamino)-3-aminopropane
3-Amino-1-(dimethylamino)propane
N,N-Dimethyl-1,3-diaminopropane
N-Dimethyltrimethylenediamine
(3-aminopropyl)dimethylamine
N,N-Dimethyl-1,3-propylenediamine
N,N-Dimethyl-N-(3-aminopropyl)amine
NSC 1067
N`,N`-dimethylpropane-1,3-diamine
UNII-I98I2UEC03
Propylamine, 3-(N,N-dimethylamino)-
1-Amino-3-(dimethylamino)propane
.gamma.-(Dimethylamino)propylamine
MFCD00008216
3-AMINO-(DIMETHYLPROPYLAMINE)
1,3-Propanediamine, N1,N1-dimethyl-
I98I2UEC03
N,N-dimethyl-1,3-propane diamine
N1,N1-dimethylpropane-1,3-diamine
DSSTox_CID_5102
DSSTox_RID_77667
DSSTox_GSID_25102
3-Dimethylaminopropylamine, 99%
CAS-109-55-7
1-Amino-3-dimethylaminopropane
CCRIS 4799
gamma-(Dimethylamino)propylamine
HSDB 5391
N,N`-Dimethyl-1,3-diaminopropane
EINECS 203-680-9
3-dimethylamino propylamine
BRN 0605293
AI3-25441
1-Amino-3-dimethylamino propane
3-(dimethylamino)-1-aminopropane
3-Dimethylaminopropylamine (DMAPA)
N`,N`-Dimethyl propane-1,3-diamine
N,3-propylenediamine
dimethylammo propylamme
dimethyl aminopropylamine
dimethylaminopropyl amine
Dimethylaminopropyl-amine
ACMC-1BRG7
NH2CH2CH2CH2NMe2
3-dimethylamino-propylamine
3-dimethylaminopropyl amine
EC 203-680-9
3-(Dimethyamino)propylamine
CN(C)CCC[N]
Cyclohexyl amineN,N-Dimethyl-1,3-propanediamine
(3-dimethylaminopropyl)amine
3-dimethylamino-1propylamine
3-dimethylamino-propyl amine
N,N-dimethyltrimethylendiamin
SCHEMBL30161
3-dimethylamino-n-propylamine
3-(dimethyl-amino)propylamine
3-(dimethylamino) propylamine
3-(dimethylamino)-propylamine
3-(dimethylamino)propyl amine
3-dimethylamino-1-propylamine
Propylamine,N-dimethylamino)-
[3-(dimethylamino)propyl]amine
H2NC3H6N(CH3)2
SCHEMBL7633005
1-amino-3-dimethylamino-propane
3-(dimethylamino)-n-propylamine
CHEMBL1232234
DTXSID5025102
N,N-Dimethy-1,3-propanediamine
WLN: Z3N1&1
N,N-dimethyl-1.3-propanediamine
NSC1067
3-(N,N-dimethylamino)propylamine
H2N(CH2)3N(CH3)2
3-(N,N-dimethyl amino)propylamine
3-(N,N-dimethylamino)-propylamine
N, N-dimethyl-1,3-diaminopropane
N, N-dimethyl-1,3-propanediamine
N,N-dimethyl-1, 3-propanediamine
N,N-Dimethyl-1,3-propane-diamine
N,N-dimethyl-propane-1,3-diamine
n`,n`-dimethyl-1,3-propanediamine
N,N-Dimethylpropylene-1,3-diamine
N1,N1-dimethylpropan-1,3-diamine
NSC-1067
STR00957
ZINC1587811
N1,N1-dimethyl-1,3-propanediamine
Tox21_202048
Tox21_303328
AC-363
ANW-16063
BBL027699
N,N-Di-methyl-3-amino-propyl-amine
SBB028177
STL168867
N`,N`-dimethyl-propane-1,3-diamine
3-(Dimethyl-d6-amino)-1-propylamine
3-(N,N-dimethylamino)-1-propylamine
AKOS000119881
MCULE-9301668058
PROPANE,1-AMINO,3-DIMETHYLAMINO
3-(Dimethylamino)-1-propylamine, 99%
68497-58-5
H305
N(1),N(1)-dimethyl-propane-1,3-diamine
D0790
FT-0629498
FT-0667531
N(1), N(1)-dimethyl-propane-1,3-diamine
3-(Dimethylamino)-1-propylamine, analytical standard
F2187-2249
3-(Dimethylamino)-1-propylamine, purum, >=98.0% (GC)
Chemical Abstract Service Name: 1,3-Propanediamine, N, N-dimethyl (9CI)
Synonyms: 1-Amino-3-dimethylaminopropane; 3-amino-1-dimethylaminopropane; 3-aminopropyldimethylamine; 1-dimethylamino-3-aminopropane; 3-(dimethylamino)-1-propanamine; dimethylaminopropylamine; (-dimethylaminopropylamine; N,N-dimethyl-1,3-diaminopropane; N,N-dimethylpropylenediamine; N,Ndimethyltrimethylenediamine; DMAPA; EINECS 203-680-9
Dimethylaminopropylamine (DMAPA) is a diamine that is widely used during the manufacturing of some surfactants, such as Cocamidopropyl betaine which is an ingredient in many personal care products including soaps, shampoos, and cosmetics and other personal care products.
DMAPA is completely miscible with water, alcohols, esters, and ketones.
It has limited miscibility with diethyl ether, benzene, and chlorinated hydrocarbons.
DMAPA is mild, skin-friendly, and hence its use has increased in the production of soft soap and shampoos as it does not cause irritation to the skin and eyes.
Dimethylaminopropylamine (DMAPA) is a clear, essentially colorless liquid with a typical amine odor. It is completely soluble in water, benzene, heptane, and other organic solvents.
DMAPA has applications in leather processing, paper, rubber, and personal care products.
Dimethylaminopropylamine is also used as an intermediate in the production of fabric softeners, polymers, agrochemicals, flocculating agents, liquid soaps, and dye intermediates.
Technical Data Sheet
Dimethylaminopropylamine (DMAPA)
Chemical Synonym
N,N-3-dimethyl-1,3-propanediamine; 1-Amino-3-dimethylaminopropane; 3-Aminopropyldimethylamine;
N,N-Dimethyl-1,3-diaminopropane; N-,N-Dimethylaminopropylamine; DMAPA
Applications
Cosmetic and personal care intermediate
Home & industrial care imtermediates
Product Description
DMAPA is a clear colorless liquid, free of suspended matter.
DMAPA is completely miscible with water, alcohols, esters and ketones. It has limited miscibility with diethylether,
benzene, and chlorinated hydrocarbons.
DMAPA is either used on itself or as an intermediate in the production of:
Surfactants
Water treatment chemicals
Ion exchange resins
Polyurethane catalysts
Epoxy resin hardeners
Corrosion inhibitors
Gasoline and motor additives / lubricating oil additives
Textile auxiliaries
Agrochemicals
Pharmaceuticals
Paper adjuvants
Photographic adjuvants
DMAPA is used as a surfactant in preparing shampoos, antiseptics, wetting agents, textile dyeing, finishing aids and emulsifiers.
Dimethylaminopropylamine is used for preparing corrosion inhibitors (amine phosphates) for aviation gasoline.
Dimethylaminopropylamine is also used in manufacture of water treatment chemicals, ion-exchange resins, polyurethane catalysts and epoxy resin hardeners.
DMAPA is produced from acrylonitrile and dimethyl amine in a 2-stage process.
In the first stage the reaction of the starting materials, acrylonitrile and dimethyl amine lead to raw reaction products containing approximately 99 % 3-dimethyl aminoproprionitrile.
This addition product is hydrogenated to DMAPA in the second stage of the manufacturing process.
As a result of competing and follow-on reactions occuring during the course of synthesis, a number of byproducts are produced.
These are removed from the DMAPA through multiple-stage distillation [1].
The pure product has a DMAPA content of > 99.5 %.
DMAPA is used as an intermediate in the production of binding agents, ion-exchange materials, flocculating agents (water treatment), cosmetic agents, washing and cleaning agents (betaines), additive for petrol and other fuels, polyurethane fibres and lubricants, dyes, agrochemicals, agents used in the photographic and textile industries, etc. OECD SIDS
3-AMINOPROPYLDIMETHYLAMINE
DMAPA is also used directly as a hardener in epoxy resins in the plastics industry, as a crosslinking agent for cellulose fibres in the paper industry and as an anti-shriking agent for leather [1]
CAS No.109-55-7
Chemical Name:3-Dimethylaminopropylamine
SynonymsDMAPA;DMPDA;NSC 1067;U-CAT 2000;-Dimethylamino;FENTAMINE DMAPA;amino)-1-propyL;H2N(CH2)3N(CH3)2;3-DIAMINOPROPANE;RARECHEM AL BW 0072
3-Dimethylaminopropylamine Chemical Properties,Uses,Production
Description
Dimethylaminopropylamine is an aliphatic amine present in amphoteric surfactants such as liquid soaps and shampoos. It is present as an impurity responsible for allergy from cocamidopropylbetaine. It is structurally similar to diethylaminopropylamine. It is also used as a curing agent for epoxy res ins and as an organic intermediate in chemical syntheses (ion exchangers, additives for flocculants, cosmetics and fuel additives, dyes and pesticides).
Chemical Properties
clear liquid
Uses
N,N-Dimethyl-1,3-propylenediamine is a useful catalyst for Knoevenagel condensation. It is also a useful hardening agent for expoxy resin.
Uses
3-(Dimethylamino)propylamine is an intermediate substance in the synthesis of alkylamidopropyldimethylamines/alkylamidobetaines; found as an impurity in cosmetic surfactants present in e.g. shampoos; hardener of epoxy resins; additive in fue!, dyes, pesticides and binding agents; in the production of ion-exchangers.
General Description
Colorless liquid.
Air & Water Reactions
Highly flammable. Temperature sensitive and possibly sensitive to air. Water soluble.
Reactivity Profile
3-Dimethylaminopropylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Fire Hazard
3-Dimethylaminopropylamine is flammable.
Contact allergens
Dimethylaminopropylamine is an aliphatic amine present in amphoteric surfactants such as liquid soaps and shampoos. It is present as a residual impurity thought to be responsible for allergy from cocamidopropylbetaine. It is structurally similar to diethylaminopropylamine. It is also used as a curing agent for epoxy resins and an organic intermediate in chemical synthesises (ion exchangers, additives for flocculants, cosmetics and fuel additives, dyes and pesticides). Patch test has to be carefully interpreted, since the 1% aqueous solution has pH > 11 (personal observation).
Safety Profile
Moderately toxic by ingestion and skin contact. A skin and eye irritant. Very flammable when exposed to heat, flame, or oxidmers. Reaction with 1,2dichloroethane produces explosive acetylene gas. This and other amines igmte on contact with cellulose nitrate of hgh surface area. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of NO
• RARECHEM AL BW 0072
• N,N-DIMETHYL PROPANE-1,3-DIAMINE
• N,N-DIMETHYLTRIMETHYLENEDIAMINE
• N,N-DIMETHYL-1,3-DIAMINOPROPANE
• gamma-dimethylaminopropylamine
• H2N(CH2)3N(CH3)2
• N-(3-aminopropyl)dimethylamine
• N,N-Dimethyl-1,3-propylenediamine
• n,n-dimethyl-3-propanediamine
• N,N-Dimethylaminopropylamine
• N,N-Dimethyl-N-(3-aminopropyl)amine
• N,N-Dimethylpropylene-1,3-diamine
• N,N-Dimethylpropylenediamine
• N,N-Dimethyltrimehtylenediamine
• Propylamine, 3-(N,N-dimethylamino)-
• N1,N1-Dimethyl-propane-1,3-diamine
• N,N-Dimethyl-1,3-propanediamine ,99%
• 3-(Dimethylamino)-1-propylamine,N,N-Dimethyl-1,3-diaminopropane, N,N-Dimethyl-1,3-propanediamine
• FENTAMINE DMAPA
• 3-DiMethylaMinopropylaMine, 99% 1LT
• 3-DiMethylaMinopropylaMine, 99% 250ML
• 1,1-DiMethyl-1,3-propylenediaMine
• N-(3-DiMethylaMinopropyl)aMine
• N,N-DiMethyl-3-aMinopropylaMine
• N-AMinopropyl-N,N-diMethylaMine
• NSC 1067
• U-CAT 2000
• 3-(Dimethylamino)propylamine N,N-Dimethyltrimethylenediamine
• N,N-DIMETHYLTRIMETHYLENEDIAMINE FOR SYNT
• 3-Dimethylamino Propylamine (DMAPA)
• 3-(Dimethylamino)propane-1-amine
• 3-(Diethylamino) Proylamine
• N,N-DiMethyl propyl diaMine
• 3-(DiMethylaMino)-1-propylaMine 99%
• 3-(DiMethylaMino)-1-propylaMine puruM, >=98.0% (GC)
• N, N - diMethyl - 1, 3 - propylene aMide
• DMAPA/N,N-Dimethyl-1,3-propanediamine
• N,N-Dimethyl-1,3-propanediamine
• DiMethylaMino)-1-propyla
• 1,3-Propanediamine, N1,N1-dimethyl-
• amino)-1-propyL
• N, N-Dimethyl-1, 3-Propanediamine（JD DMAPA）
• DIMETHYLAMINOPROPYLAMINE
• DMAPA
• -Dimethylamino
• gamma-(Dimethylamino)propylamine
• 1-(Dimethylamino)-3-aminopropane
• 1,3-propanediamine,N,N-dimethyl-
• 1-dimethylamino-3-aminopropane
• 3-(Dimethylamino)-1-propanamine
• 3-(n,n-dimethylamino)-propylamin
• 3-Amino-1-(dimethylamino)propane
• 3-Propanediamine,N,N-dimethyl-1
• 3-DIMETHYLAMINOPROPYLAMINE
• 3-DIMETHYLAMINO-N-PROPYLAMINE
• 3-DIMETHYLAMINO-1-PROPYLAMINE
• 1-Amino-3-dimethylaminopropane
• 3-Dimethylaminopopylamine
1,3-Propanediamine, N,N-dimethyl-
1,3-Propanediamine, N1,N1-dimethyl-
1-(Dimethylamino)-3-aminopropane
1-Amino-3-dimethylaminopropane
3-(Dimethylamino)-1-propanamine
3-(Dimethylamino)-1-propylamine
3-Amino-1-(dimethylamino)propane
3-aminopropyldimethylamine
3-Aminopropyldimethylamine
3-aminopropyldimethylamine
3-aminopropyldimethylamine; N,N-dimethyl-1,3-diaminopropane
3-Dimethylaminopropylamine
gamma-(Dimethylamino)propylamine
N,N-Dimethyl-1,3-diaminopropane
N,N-dimethyl-1,3-diaminopropane
N,N-Dimethyl-1,3-propanediamine
N,N-Dimethyl-1,3-propylenediamine
N,N-Dimethyl-N-(3-aminopropyl)amine
N,N-Dimethylpropylenediamine
N,N-Dimethyltrimethylenediamine
N-Dimethyltrimethylenediamine
Propylamine, 3-(N,N-dimethylamino)-
Translated names
3-(dietylamino)propylamin (no)
3-(dimethylamino)propylamin (da)
3-(dimethylamino)propylamine (nl)
3-(dimetilamino) propilamina (it)
3-(dimetilamino) propilamina (pt)
3-(dimetilamino)propilamin (sl)
3-(dimetilamino)propilamina (es)
3-(diméthylamino)propylamine (fr)
3-(N,N-dimetyloamino)propyloamina (pl)
3-aminopropildimetil-amin (hu)
3-aminopropildimetilamin (hr)
3-aminopropildimetilamina (ro)
3-aminopropildimetilamīns (lv)
3-aminopropyldimetylamín (sk)
3-aminopropyldiméthylamine; N,N-diméthyl-1,3-diaminopropane (fr)
3-Aminopropyylidimetyyliamiini (fi)
3-aminopropüüldimetüülamiin (et)
3-Dimethylaminopropylamin (de)
3-dimetilaminopropilaminas (lt)
3-dimetylaminopropylamin (sv)
3-dimetyloaminopropyloamina (pl)
3-аминопропилдиметиламин (bg)
N,N-dimetil-1,3-diaminopropan (hr)
N,N-dimethyl-1,3-diaminopropaan (nl)
N,N-dimethyl-1,3-diaminopropan (cs)
N,N-dimethyl-1,3-diaminopropan (da)
N,N-Dimethyl-1,3-diaminopropan (de)
N,N-dimethylpropan-1,3-diamin (cs)
N,N-dimetil-1,3-diaminopropan (ro)
N,N-dimetil-1,3-diaminopropan (sl)
N,N-dimetil-1,3-diaminopropanas (lt)
N,N-dimetil-1,3-diaminopropano (es)
N,N-dimetil-1,3-diaminopropano (pt)
N,N-dimetil-1,3-diaminopropán (hu)
N,N-dimetil-1,3-diaminopropāns (lv)
N,N-dimetile-1,3-diaminopropano (it)
N,N-dimetyl-1,3-diaminopropan (no)
N,N-dimetyl-1,3-diaminopropan (sv)
N,N-dimetylopropano-1,3-diamina (pl)
N,N-dimetylpropán-1,3-diamín (sk)
N,N-dimetüül-1,3-diaminopropaan (et)
N,N-διμεθυλο-1,3-διαμινοπροπάνιον (el)
N,N-диметил-1,3-диаминопропан (bg)
CAS names
1,3-Propanediamine, N1,N1-dimethyl-
IUPAC names
(3-aminopropyl)dimethylamine
1,3-Propanediamine, N,N-dimethyl-
3-(dimethylamino)-propylamine
3-(dimethylamino)-propylamine (DMAPA)
3-Aminopropyldimethylamin
3-AMINOPROPYLDIMETHYLAMINE
3-Aminopropyldimethylamine
3-aminopropyldimethylamine
3-aminopropyldimethylamine
3-dimethylaminopropylamine
Dimethyl Amineopropylamine
DIMETHYL AMINO PROPYL AMINE
dimethyl-1,3-diaminopropane
Dimethylaminopropylamine
Dimethylaminopropylamine
DMAPA
N`,N`-dimethylpropane-1,3-diamine
,
N,N, Dimethyl-1,3-propanediamine
N,N-Dimethyl-1,3-diamino-propan
N,N-dimethyl-1,3-diaminopropane
N,N-Dimethyl-1,3-propanediamine
N,N-Dimethylpropane-1,3-diamine
,
N,N-dimethylpropane-1,3-diamine
,
N,N-dimethylpropane-1,3-diamine
N,N-Dimethyltrimethylene diamine
Trade names
(3-Aminopropyl)dimethylamine
.gamma.-Dimethylaminopropylamine
1,3-Propanediamine, N,N-dimethyl- (6CI, 8CI, 9CI)
1-(Dimethylamino)-3-aminopropane
1-Amino-3-(dimethylamino)propane
3-(Dimethylamino)-1-aminopropane
3-(Dimethylamino)-1-propanamine
3-(Dimethylamino)-1-propylamine
3-(Dimethylamino)propanamine
3-(Dimethylamino)propylamine
3-Amino-1-(dimethylamino)propane
3-N,N-Dimethylaminopropylamine
Dimethylaminopropylamin
DMAPA
N,N-Dimethyl-1,3-diaminopropane
N,N-Dimethyl-1,3-propanediamine
N,N-Dimethyl-1,3-propylenediamine
N,N-Dimethyl-N-(3-aminopropyl)amine
N,N-Dimethylpropylendiamin
N,N-Dimethylpropylenediamine
N,N-Dimethyltrimethylenediamine
