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METHYLAL

Methylal is a colorless, highly flammable liquid with a low boiling point, excellent dissolving power, and a chloroform-like odor, used primarily as a solvent in various industrial applications including the manufacture of perfumes, resins, adhesives, and paint strippers.
Methylal has a very strong dissolving capacity and is used in personal care products such as hand cleansers, antibacterial gels, hair sprays, and nail polish removers due to its rapid evaporation and effective solvent properties.
Methylal is also utilized as a fuel additive for increasing the octane number of gasoline, and its low toxicity profile and rapid evaporation make it suitable for various applications in both industrial and personal care products.

CAS Number: 109-87-5
EC Number: 203-714-2
Molecular Formula: C3H8O2
Molecular Eeight: 76.08 g/mol

Synonyms: dimethoxy-, Dimethyl formal, Anesthenyl, Dimethoxymethane, Formal, Formaldehyde dimethyl acetal, Methoxymethyl methyl ether, Methylene dimethyl ether, Methylene glycol dimethylether, (CH3O)2CH2, Methylenedioxydimethane, Metylal, UN 1234, Formaldehyde methyl ketal, 2,4-Dioxapentane, Dimethylacetal formaldehyde, Bis(methoxy)methane, dimethoxymethane, formaldehyde dimethylacetal, methoxymethyl methyl ether, methylene dimethyl ether, 2,4-Dioxapentane, Anesthenyl, Bis(methoxy)methane, Dimethoxymethane, Dimethyl formal, Formal, Formaldehyde dimethyl acetal, Formaldehyde, methyl ketal, Methoxymethyl methylether, Methylal, Methylene dimethyl ether, 2,4-Dioxapentane, Anesthenyl, Bis(methoxy)methane, Dimethoxymethane, Dimethyl formal, Formal, Formaldehyde dimethyl acetal, Formaldehyde dimethylacetal, Formaldehyde methyl ketal, Methane, dimethoxy-, Methoxymethyl methyl ether, Methylene dimethyl ether, Metylal [Polish], [ChemIDplus] UN1234, Dimethoxymethane, Formal, Formaldehyde Dimethylacetal, Methoxymethyl Methyl Ether, Methylene Dimethyl Ether, Methane, dimethoxy-, Dimethyl formal, Anesthenyl, Dimethoxymethane, Formal, Formaldehyde dimethyl acetal, Methoxymethyl methyl ether, Methylene dimethyl ether, Methylene glycol dimethylether, (CH3O)2CH2, Methylenedioxydimethane, Metylal, UN 1234, Formaldehyde methyl ketal, 2,4-Dioxapentane, Dimethylacetal formaldehyde, Bis(methoxy)methane, Dimethoxymethane, METHYLAL, 109-87-5,Formal, Methane, dimethoxy-, Formaldehyde dimethyl acetal, Dimethyl formal, Anesthenyl, 2,4-Dioxapentane, Methylene dimethyl ether, Bis(methoxy)methane, Methoxymethyl methyl ether, Metylal, Formaldehyde methyl ketal, Formaldehyde dimethylacetal, bis(methyloxy)methane, Methylene glycol dimethylether, 7H1M4G2NUE, CHEBI:48341, Dimethoxy methane, MFCD00008495, HSDB 1820, EINECS 203-714-2, UN1234, UNII-7H1M4G2NUE, Dimethylformal, AI3-16096, CCRIS 9397, Methylene Glycol Dimethyl Ether, Dimethoxy-Methane, Methylenedioxydimethane, METHYLAL [HSDB], METHYLAL [INCI], METHYLAL [MI], Dimethoxymethane 99.5%, Dimethylacetal formaldehyde, METHYLAL [WHO-DD], EC 203-714-2, CHEMBL15537, (CH3O)2CH2, DTXSID1025564, AKOS000120977, UN 1234, Dimethoxymethane, ReagentPlus(R), 99%, Methylal [UN1234], D0637, FT-0625028, NS00003248, Formaldehyde dimethyl acetal, analytical standard, Q411496, J-520340, InChI=1/C3H8O2/c1-4-3-5-2/h3H2,1-2H, F0001-0207, Formaldehyde dimethyl acetal, absolute, over molecular sieve (H2O <=0.01%), >=99.0% (GC), Dimethoxymethane, Formal, Formaldehyde dimethylacetal, Methoxymethyl methyl ether, Methylene dimethyl ether, 2,4-Dioxapentane, Anesthenyl, Bis(methoxy)methane, Dimethoxymethane, Dimethyl formal, Formal, Formaldehyde dimethyl acetal, Formaldehyde dimethylacetal, Formaldehyde methyl ketal, Methane, dimethoxy-, Methoxymethyl methyl ether, Methylene dimethyl ether, UN1234, dimethoxymethane, formaldehyde dimethylacetal, methoxymethyl methyl ether, methylene dimethyl ether, (CH3O)2CH2, 2,4-Dioxapentane, Anesthenyl, Bis(methoxy)methane, Dimethoxymethane, Dimethyl formal, Dimethylacetal formaldehyde, Formal, Formaldehyde dimethyl acetal, Formaldehyde methyl ketal, Methane, dimethoxy-, Methoxymethyl methyl ether, Methylene dimethyl ether, Methylene glycol dimethylether, Methylenedioxydimethane, Metylal, UN 1234, formaldehyde, dimethyl acetal, methanal, dimethyl acetal, 2,4-Dioxapentane, Anesthenyl, Bis(methoxy)methane, Dimethoxymethane, Dimethyl formal, Formal, Formaldehyde dimethyl acetal, Formaldehyde, methyl ketal, Methoxymethyl methylether, Methylal, Methylene dimethyl ether, Formaldehyde Dimethyl Ether, Dimethoxymethane, Formaldehyde dimethyl aceta, Dimethoxymethane, Formal, Formaldehyde Dimethylacetal, Methoxymethyl Methyl Ether, Methylene Dimethyl Ether, Dimethoxymethane , Formal , Dimethyl Formal , Formaldehyde Dimethyl Acetal, 2,4-Dioxapentane, Anesthenyl, Bis(methoxy)methane, Dimethoxymethane, Dimethyl formal, Formal, Formaldehyde dimethyl acetal, Formaldehyde methyl ketal, Methoxymethyl methylether, Methylal, Methylene dimethyl ether, Dimethoxymethane, Formal, Formaldehyde dimethylacetal

Methylal is a colorless liquid with a low boiling point, low viscosity and excellent dissolving power.
Methylal is the dimethyl acetal of formaldehyde.

Methylal appears as a clear colorless liquid with a chloroform-like odor.
The flash point of Methylal is 0 °F.

The boiling point of Methylal is 42.3 °C.
The density of Methylal is 0.864 g / cm3 at 68 °F (20 °C).

Methylal is a colorless liquid with a low boiling point, low viscosity and excellent dissolving power.
Methylal has a chloroform-like odor and a pungent taste.

Methylal is the dimethyl acetal of formaldehyde.
Methylal is soluble in three parts water and miscible with most common organic solvents.

Methylal appears as a clear colorless liquid with a chloroform-like odor.
Flash point of Methylal is 0 °F.

Boiling point of Methylal is 42.3 °C.
Methylal's Vapors are heavier than air.

Methylal is an acetal that is the dimethyl acetal derivative of formaldehyde.
Methylal is an acetal and a diether.

Methylal is the dimethyl acetal of formaldehyde.
Methylal is soluble in three parts water and miscible with most common organic solvents

Methylal is a clear colorless liquid with a chloroform-like odor.
Methylal is soluble in water and miscible with common organic solvents like methanol and ethanol.

Methylal is a colorless liquid with the chemical formula C3H8O2.
Methylal is the dimethyl acetal of formaldehyde with unique properties, suitable for different applications.

Methylal is also known as formaldehyde dimethyl acetal, methylene dimethyl ether, and methoxymethyl methyl ether.
Methylal belongs to the following substance groups solvents.

Methylal is a colorless liquid with the chemical formula C3H8O2.
Methylal has a chloroform-like odor and a pungent taste.

Methylal is the dimethyl acetal of formaldehyde.
Methylal exhibits high solvent power, medium to low polarity/surface tension and low to high evaporation rate.

Methylal is functionally related to a methanediol.
Methylal is a colorless liquid.

Methylal is soluble in three parts water and miscible with most common organic solvents.
Methylal is primarily used as a solvent and in the manufacture of perfumes, resins, adhesives, paint strippers and protective coatings.

Another useful application of Methylal is to protect alcohols with a MOM ether in organic synthesis.
Methylal is a colorless liquid with a chloroform-like odor.

Methylal is an ether.
Methylal is a partial substitute for alcohols in gel.

In formulations of antibacterial gel and hand sanitizers, Methylal can replace 50% of the alcohol used.
Alcohol is scarce and this can be partly dissolved by using Methylal.

Methylal, also known as Dimethoxymethane or Formaldehyde dimethyl ether, is the dimethyl acetal of formaldehyde used as a solvent as well as in manufacturing resins, perfumes, adhesives, and protective coatings.
Methylal is the triester of ethanol and phosphoric acid and can be called "phosphoric acid, triethyl ester".

Methylal is a clear colorless flammable liquid with a low boiling point, low viscosity and excellent dissolving power.
Density of Methylal is 0.864 g / cm3 at 68 °F (20 °C).

Vapors of Methylal is heavier than air.
Methylal is an acetal that is the dimethyl acetal derivative of formaldehyde.

Methylal is an acetal and a diether.
Methylal is functionally related to a methanediol.

Methylal is a colorless liquid with a harsh, sharp odor.
Methylal is a colorless yet highly volatile acetal solvent that is manufactured from Methanol.

Methylal has a chloroform-like odor and a pungent taste.
Methylal is the dimethyl acetal of formaldehyde.

Methylal is soluble in three parts water and miscible with most common organic solvents.
Another useful application of Methylal is to protect alcohols with a MOM ether in organic synthesis.

Methylal, is a colorless flammable liquid with a low boiling point, low viscosity and excellent dissolving power.
Methylal is a colorless liquid.

Methylal is the triester of ethanol and phosphoric acid and can be called "phosphoric acid, triethyl ester".
Methylal is a clear colorless flammable liquid with a low boiling point, low viscosity and an excellent dissolving power.

Methylal has a chloroform-like odor and a pungent taste.
Methylal is the dimethyl acetal of formaldehyde.

Methylal is a colorless yet highly volatile acetal solvent that is manufactured from Methanol.
Methylal has an extremely low toxicity profile.

Methylal is incompatible with strong oxidizing agents and acids.
Methylal should be kept away from heat, hot surfaces, sparks, open flames and other ignition sources.
Methylal is a colourless liquid with excellent dissolving power.

Methylal is registered under the REACH Regulation and is manufactured in and / or imported to the European Economic Area, at ≥ 1 000 to < 10 000 tonnes per annum.
Methylal is a colorless flammable liquid with a low boiling point, low viscosity and excellent dissolving power.

Methylal has a chloroform-like odor and a pungent taste.
Methylal is a colorless liquid with a chloroform-like odor.

Methylal Market Overview:
Methylal Market is forecast to reach $445 million by 2026, after growing at a CAGR of 1.5% during the forecast period from 2021-2026.
Methylal is also known as dimethoxymethane and is often produced by oxidizing methanol or through the reaction of formaldehyde and methanol.

Globally, rising demand for methylal as blowing agents for PU foams, growing pharmaceuticals industries, flourishing cosmetic industry, and extensive properties of methylal such as good solubility, low boiling point, and anti-carcinogenic are the prime growth drivers of the methylal market.
In addition, the emergence of methylal as an automotive fuel and diesel modification additive, increase in the adoption of methylal for application in newer industrial verticals will create new opportunities for the methylal market, which will then substantially drive the methylal market during the forecast period.

Uses of Methylal:
Methylal is used as a solvent for adhesives and coatings, a fuel, and an intermediate for other organic compounds.
Methylal has been used as an anesthetic.
Methylal can also be used for blending with diesel.

Methylal is often used as a fuel, to manufacture other organic chemicals, and a compatibilizer of actives in solvent and water based recipes.
In personal care applications, methylal improves spray performance and reduces solvent amount in aerosol cans and pump sprays.

Methylal has an extremely low toxicity profile.
Methylal is used as a fuel and a solvent and to manufacture other organic chemicals.

Methylal is used aerosol cans & Pump sprays.
Methylal has a comparable, strong, dissolving capacity, which means that the quality of this substance can be found again.

In the case of Ethyl Alcohol, an improvement in quality is possible, when part of the alcohol is replaced by Methylal, smaller drop sizes are possible and the drying time is greatly shortened.
Further application of Methylal is possible in creams and lotions.

The rapid evaporation creates a nice cooling effect.
This property, together with the high dissolving power for UV filters, makes the solvent very useful for sun protection products.

Removing nail polish with Methylal, possibly in combination with Dioxolane, is very effective.
Also as a replacement for Acetone or Ethyl Acetate, Methylal has no intoxicating effect when used on the hands, close to the face.

Methylal is used hand Cleansers, Antibacterial Gels, Hair Sprays, Sun Protection, Nail Polish Remover.
Industrially, Methylal is primarily used as a solvent and in the manufacture of perfumes, resins, adhesives, paint strippers and protective coatings.

Another application of Methylal is as a gasoline-additive for increasing octane number.
Methylal is often used as a fuel, to manufacture other organic chemicals, and a compatibilizer of actives in solvent and water based recipes.

Methylal is used as a solvent for adhesives and coatings, a fuel, and an intermediate for other organic compounds.
Methylal has been used as an anesthetic.

Methylal is a colorless liquid that acts as a solvent.
Methylal has a very strong dissolving capacity and can be used in many different applications.
Because of the rapid evaporation, Methylal is often used in aerosol cans, especially as a replacement for, for example, Methylene chloride or Ethyl alcohol.

Methylal is suitable for use in cosmetics, here it can be used in a number of product groups.
The most commonly used application is hair styling sprays, the Methylal is then usually used as a replacement for Methylene chloride or Ethyl alcohol (CAS 64-17-5).

Methylene chloride contains, among other things, the H351 (suspected carcinogen) warning and has been replaced by other solvents in cosmetic aerosol cans.
In personal care applications, Methylal improves spray performance and reduces solvent amount in aerosol cans and pump sprays.

Methylal is used in removing nail polish.
Methylal acts as a solvent and can be used in many different applications.

Methylal is used as a solvent in different industries.
Methylal is used to produce anion exchange resins, manufacture perfumes, paint stripping, etc.

Methylal is used reaction solvent manufacturing pharmaceuticals,
Adhesives, Gasoline-additive for increasing octane number, and Protective coatings.

Methylal is used Paint Stripping, and Aerosol cans.
Methylal is used as a solvent and in the manufacture of perfumes, resins, adhesives, paint strippers and protective coatings.

Methylal has a very strong dissolving capacity and is used as an extraction solvent in manufacturing pharmaceuticals, aerosols, paints, and varnishes.
Methylal is used as a fuel additive for smoke reduction.

Methylal is widely used as a solvent and in the manufacture of perfumes, resins, adhesives.
Besides methylal is applied to increase the octane number of gasoline.

Methylal is primarily used as a solvent and in the manufacture of perfumes, resins, adhesives, paint strippers and protective coatings.
Methylal can be used in many different applications.

Due to the rapid evaporation, Methylal is often used in aerosol cans.
Methylal is suitable for use in cosmetics.

For example, Methylal is used in hair styling sprays, creams and lotions.
Methylal is mostly used as a solvent in different industries.

Methylal is used as a solvent in the manufacture of pharmaceuticals, aerosols, paints, varnishes and cleanings.
Methylal is used glue formulations fragrances and pesticides.

Methylal is used fuel additive for smoke reduction.
Methylal is used paint stripping.

Methylal is used in the production of creams and lotions. Methylal is a suitable solvent for sun protection products.
Methylal is widely used as a solvent and in the manufacture of perfumes, resins, adhesives.

Release to the environment of Methylal can occur from industrial use: in processing aids at industrial sites, of substances in closed systems with minimal release, as an intermediate step in further manufacturing of another substance (use of intermediates) and for thermoplastic manufacture.
Release to the environment of Methylal can occur from industrial use: manufacturing of the substance.

Methylal is used in inks and coatings.
Methylal is a clear colourless liquid with a chloroform-like odour.

Methylal is soluble in water and is miscible with common organic solvents.
Methylal is used in different industries.
Methylal is used as a solvent in the manufacture of resins, adhesives, paint strippers and protective coatings.

Methylal is the dimethyl acetal of formaldehyde.
Methylal is used by consumers, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing.

Methylal is used in the following products: coating products, air care products, lubricants and greases, fuels, washing & cleaning products, adhesives and sealants, biocides (e.g. disinfectants, pest control products), fillers, putties, plasters, modelling clay and polishes and waxes.
Other release to the environment of Methylal is likely to occur from: outdoor use and indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners).
Other release to the environment of Methylal is likely to occur from: outdoor use in long-life materials with high release rate (e.g. tyres, treated wooden products, treated textile and fabric, brake pads in trucks or cars, sanding of buildings (bridges, facades) or vehicles (ships)) and indoor use in long-life materials with high release rate (e.g. release from fabrics, textiles during washing, removal of indoor paints).

Besides Methylal is applied to increase the octane number of gasoline.
Methylal can be found in complex articles, with no release intended: machinery, mechanical appliances and electrical/electronic products (e.g. computers, cameras, lamps, refrigerators, washing machines).
Methylal is used in the following products: lubricants and greases, coating products, explosives, fuels, hydraulic fluids, laboratory chemicals, plant protection products, polymers and washing & cleaning products.

Other release to the environment of Methylal is likely to occur from: outdoor use and indoor use (e.g. machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners).
Release to the environment of Methylal can occur from industrial use: formulation of mixtures and formulation in materials.

Methylal is used in the following products: fuels, hydraulic fluids, lubricants and greases, polymers, coating products, heat transfer fluids, laboratory chemicals, washing & cleaning products and extraction agents.
Methylal has an industrial use resulting in manufacture of another substance (use of intermediates).

Methylal is a product which can be today biosourced up to 86,5% with incredible properties which can fit in various applications to optimize:
Wetting
Viscosity
Drying time (in spray and aerosols)
Solubilization of ingredients (resins, actives, grease,..)

That's really the key polyvalent product to improve performances of your formulations.
Moreover, Methylal is only flammable and not label for health or environment issue

Advantages of Methylal:
Excellent Stability
A versatile replacement solvent
Excellent water removal property from organic molecules
Excellent stability in acidic or alkaline medium
Good miscibility with water
Rapid evaporation
Low viscosity
Excellent dissolving power

Synthesis And Structure of Methylal:
Methylal can be manufactured by oxidation of methanol or by the reaction of formaldehyde with methanol.
In aqueous acid, Methylal is hydrolyzed back to formaldehyde and methanol.

Due to the anomeric effect, Methylal has a preference toward the gauche conformation with respect to each of the C–O bonds, instead of the anti conformation.

Since there are two C–O bonds, the most stable conformation is gauche-gauche, which is around 7 kcal/mol more stable than the anti-anti conformation, while the gauche-anti and anti-gauche are intermediate in energy.
Since Methylal is one of the smallest molecules exhibiting this effect, which has great interest in carbohydrate chemistry, Methylal is often used for theoretical studies of the anomeric effect.

Reagent In Organic Synthesis:
Another useful application of Methylal is to protect alcohols with a methoxymethyl (MOM) ether in organic synthesis.
Methylal can be activated with phosphorus pentoxide in dichloromethane or chloroform.

This method is preferred to the use of chloromethyl methyl ether (MOMCl).
Phenols can also be MOM-protected using Methylal, p-toluenesulfonic acid.

Alternatively, MOMCl can be generated as a solution by treating Methylal with an acyl chloride in the presence of a Lewis acid catalyst like zinc bromide:
MeOCH2OMe + RC(=O)Cl → MeOCH2Cl + RC(=O)(OMe)).

Unlike the classical procedure, which uses formaldehyde and hydrogen chloride as starting materials, the highly carcinogenic side product bis(chloromethyl) ether is not generated

Production of Methylal:
Methylal is produced through the reaction of methanol and formaldehyde in the presence of concentrated sulfuric acid.
The resultant methylal is distilled, and unreacted methanol is separated from the product for recycling to obtain methylal with a content of 85% or more.

Methylal is produced through the reaction of methanol and formaldehyde in the presence of an acidic catalyst.
Methylal is generally known that methylal can be produced in the presence of sulfuric acid.
Conventionally, the methylal production is of batch process in which reaction and product isolation are carried out separately.

Handling and Storage of Methylal:

Handling:

Safety Precautions:
Use Methylal in a well-ventilated area to avoid inhaling vapors.
Avoid contact with skin and eyes.
Wear appropriate personal protective equipment (PPE) such as gloves, safety goggles, and lab coats.

Spill Response:
In the event of a spill, eliminate all ignition sources, evacuate the area, and ventilate it well.
Contain and collect the spill with inert materials (e.g., sand or vermiculite) and dispose of Methylal according to local regulations.

Storage:
Methylal is an important raw material and an excellent solvent in industry.
Methylal should be kept separated from strong oxidants and strong bases.

Methylal should be stored in a cool, dry, and well-ventilated facility.
Methylal should be stored in a tightly closed container, away from direct sunlight.

Methylal should be stored in a cool, dry and well-ventilated facility away from incompatible substances.
Methylal should be kept away from heat, sparks, and flame.

Conditions:
Store Methylal in a cool, dry, well-ventilated area away from sources of ignition, heat, and incompatible materials.
Keep the container tightly closed to prevent evaporation.

Containers: Use containers made of compatible materials such as glass or certain plastics.
Ensure containers are properly labeled.

Stability and Reactivity of Methylal:

Stability:

General Stability:
Methylal is relatively stable under normal conditions but may decompose upon exposure to heat, light, or certain catalysts.

Decomposition Products:
Decomposition may release toxic fumes, including carbon monoxide and formaldehyde.

Reactivity:

Incompatibilities:
Methylal is reactive with strong oxidizing agents, acids, and bases.
Avoid contact with these substances to prevent dangerous reactions.

Polymerization:
Methylal is not known to polymerize under normal conditions but should be kept away from conditions that could initiate polymerization reactions.

First Aid Measures of Methylal:

Inhalation:
Move the person to fresh air immediately.
If symptoms persist, seek medical attention.
Administer oxygen if breathing is difficult.

Skin Contact:
Wash the affected area with plenty of water and soap.
Remove contaminated clothing.
If irritation persists, seek medical advice.

Eye Contact:
Rinse the eyes with plenty of water for at least 15 minutes.
Remove contact lenses if present and easy to do.
Seek medical attention if irritation persists.

Ingestion:
Do not induce vomiting.
Rinse the mouth with water and seek medical attention immediately.
Provide supportive care as needed.

Fire Fighting Measures of Methylal:

Suitable Extinguishing Media:
Use foam, dry chemical powder, or carbon dioxide (CO₂) for extinguishing fires involving Methylal.
These agents are effective in controlling flammable liquid fires.

Unsuitable Extinguishing Media:
Do not use water, as Methylal can spread the fire and may cause dangerous reactions with certain chemical components.

Fire Fighting Procedures:

Protective Equipment:
Wear self-contained breathing apparatus (SCBA) and full protective clothing when fighting a fire involving Methylal.
This protects against toxic fumes and high temperatures.

Cooling:
If possible, cool containers with water spray to prevent pressure build-up and explosion.
Ensure that the cooling process is conducted from a safe distance.

Fire Hazards:

Flammability:
Methylal is highly flammable and may form explosive mixtures with air.
Vapors can travel long distances to an ignition source and flash back.

Combustion Products:
Burning Methylal may produce toxic gases, including carbon monoxide and formaldehyde.
Ensure proper ventilation and respiratory protection.

Accidental Release Measures of Methylal:

Personal Precautions:

Evacuation:
Evacuate all non-essential personnel from the area immediately.

Protective Equipment:
Wear appropriate PPE, including gloves, safety goggles, and a respirator.
Avoid direct contact with the material and inhalation of vapors.

Environmental Precautions:

Prevent Spread:
Prevent the material from entering water sources, sewers, or soil.
Contain the spill using barriers or absorbent materials if feasible.

Containment and Cleanup:

Containment:
Use barriers (e.g., booms or dikes) to contain the spill and prevent it from spreading.

Cleanup:
Absorb the spill with inert materials (e.g., sand, vermiculite, or commercial absorbents).
Collect the contaminated materials in suitable containers for disposal.
Clean the affected area with appropriate cleaning agents.

Disposal:
Dispose of the collected waste and contaminated materials according to local, regional, and national regulations.
Follow specific guidelines for hazardous waste disposal.

Exposure Controls/Personal Protective Equipment of Methylal:

Engineering Controls: 
Use local exhaust ventilation or general ventilation to maintain air concentrations below permissible exposure limits.
Ensure that the working area is well-ventilated to avoid the accumulation of vapors.

Work Practices: Implement safe work practices to minimize exposure.
Avoid eating, drinking, or smoking in areas where Methylal is handled.

Personal Protective Equipment:

Respiratory Protection:
If ventilation is insufficient or if exposure limits are exceeded, wear a suitable respirator with an organic vapor cartridge.
Ensure that the respirator is properly fitted and maintained.

Hand Protection:
Wear chemical-resistant gloves made of materials such as nitrile or butyl rubber.
Regularly check gloves for signs of wear or contamination.

Eye Protection:
Use safety goggles or face shields to protect against splashes and vapor exposure.
Ensure that eye protection is compatible with other PPE used.

Skin Protection:
Wear protective clothing such as lab coats or aprons to prevent skin contact.
Ensure that clothing is resistant to chemical penetration.

Foot Protection:
Use safety shoes or boots that are resistant to chemical spills and provide adequate protection.

Hygiene Measures:

Personal Hygiene:
Wash hands thoroughly after handling Methylal and before eating or drinking.
Ensure that contaminated clothing is removed and cleaned promptly.

Identifiers of Methylal:
CAS Number: 109-87-5
Molecular Formula: C3H8O2
Molecular Weight: 76.09 g/mol
Appearance: Clear colorless liquid
Flash point: 180°C
Boiling Point: 42°C-44°C
Freezing Point/Melting Point: 105°C
Auto Ignition Temperature: 237°C
IUPAC name: Dimethoxymethane
CAS Number: 109-87-5
Density: 0.821 g/cm3
Boiling Point: 42 °C
Flashpoint: -31 °C
Melting Point: −105 °C

Molecular formula: C3H8O2
Molecular weight: 76,08
CAS number: 109-87-5
EC number: 203-714-2
IUPAC name: Dimethoxymethane
EC name: Dimethoxymethane
Boiling point (°C) at 1013 hPa: 42.3
Freezing point (°C) at 1013 hPa: -104.8
Flash-point (°C) at 1013 hPa :-30.5
Relative density at 20°C: 0.861

Molecular formula: C3H8O2
Molecular weight: 76.08 g/mol
CAS number: 109-87-5
EC number: 203-714-2
IUPAC name: Dimethoxymethane
EC name: Dimethoxymethane
EINECS: 203-714-2
Density: 0.8560 g/cm3
Freezing Point/Melting Point: -104.8°C
Boiling Point: 45.238 °C at 760 mmHg
Vapor Pressure: 43.99 kPa at 20 °C
Flash point: -17.8 °C
Explosion Limits, Lower: 1.60 vol%
Upper: 17.60 vol%
Appearance: Colorless transparent liquid

Properties of Methylal:
Melting Point: -105.00 °C @ 760.00 mm Hg
Boiling Point: 42.00 °C @ 760.00 mm Hg
Vapor Pressure: 398.000000 mmHg @ 25.00 °C
Flash Point: 1.00 °F TCC (-17.22 °C)
Soluble in alcohol, water (244000 mg/L @ 16°C, experimentally determined)
Physical description: Colorless liquid with a chloroform-like odor.
Boiling point: 111°F
Molecular weight: 76.1
Freezing point/melting point: -157°F
Vapor pressure: 330 mmHg
Flash point: -26°F (open cup)
Vapor density: 2.6
Specific gravity: 0.86

Ionization potential: 10.00 eV
Lower explosive limit (LEL): 1.6%
Upper explosive limit (UEL): 17.6%
NFPA health rating: 1
NFPA fire rating: 3
NFPA reactivity rating: 1
EINECS: 203-714-2
Density: 0.8560 g/cm3
Melting Point: -104.8°C
Boiling Point: 45.238 °C at 760 mmHg
Vapor Pressure: 43.99 kPa at 20 °C
Flash point: -17.8 °C
Explosion Limits, Lower: 1.60 vol%
Explosion Limits, Upper: 17.60 vol%

Molecular Weight: 76.09 g/mol
XLogP3: 0.2
Hydrogen Bond Donor Count: 0
Hydrogen Bond Acceptor Count: 2
Rotatable Bond Count: 2
Exact Mass: 76.052429494 g/mol
Monoisotopic Mass: 76.052429494 g/mol
Topological Polar Surface Area: 18.5Ų
Heavy Atom Count: 5
Complexity: 12.4
Isotope Atom Count: 0
Defined Atom Stereocenter Count: 0
Undefined Atom Stereocenter Count: 0
Defined Bond Stereocenter Count: 0
Undefined Bond Stereocenter Count: 0
Covalently-Bonded Unit Count: 1
Compound Is Canonicalized: Yes

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