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SORBITAN TRISTEARATE

Sorbitan Tristearate (E492) is used as an emulsifier and stabilizer in bakery products, toppings, and coatings, fat emulsions, milk and cream analogs, beverage whiteners, edible ices, desserts, sugar confectionery including chocolate, emulsified sauces, dietary food supplements, chewing gum, and dietetic foods.

Sorbitan Tristearate is used mainly in chocolates to maintain color and shine and prevent blooming and in margarine and cooking oils to maintain an appealing texture.


As a food additive, it has the E number E492. 


CAS no.: 26658-19-5

EC / List no.: 247-891-4




Sorbitan Tristearate is produced by esterifying sorbitol with commercial stearic acid derived from food fats and oils.

Sorbitan Tristearate is a mixture of the partial esters of sorbitol and its mono- and dianhydride with edible stearic acid. 


Sorbitan Tristearate is an effective emulsifier to retard fat bloom in chocolate. 

Sorbitan tristearate and lecithin are often used as surface-active substances to reduce viscosity in chocolate formulations. 

In chocolate, sorbitan tristearate adjusts sugar crystallization and appearance, and it can reduce stickiness.

Sorbitan Tristearate is used as a crystal inhibitor in margarine, low-fat spreads, palm olein, and coconut oil.



PERSONAL CARE Application of Sorbitan Tristearate:
Sorbitan Tristearate can also be used in various personal care products, including skin care products, skin cleansing products, moisturizers, eye makeup, and other makeup.

Sorbitan tristearate functions as a surfactant in cosmetics and personal care products. 
Its concentrations typically range between 0.1% and 5% (up to 10%).


Sorbitan tristearate may be present in the following products: 

Skincare products
Makeup products
Moisturizers 


Sorbitan tristearate is used as a water-in-oil (W/O) emulsifier, and when combined with polysorbates, it can stabilize oil-in-water (O/W) emulsions. 

The Span/Polysorbate ratio formulation can produce emulsifying systems with various HLB values. 




ECHA InfoCard: 100.043.523 

E number: E492 


Chemical formula: C60H114O8

Molar mass: 963.54 g/mol

Appearance: Waxy solid



The consistency of sorbitan tristearate is waxy; its color is light cream to tan.

IUPAC name: Octadecanoic acid [(2R,3S,4R)-2-[1,2-bis(1-oxooctadecoxy)ethyl]-4-hydroxy-3-tetrahydrofuranyl] ester

Other names: 
Sorbitan trioctadecanoate
E492
Anhydrosorbitan tristearate
Anhydrosorbitol tristearate
Span 65


CAS Number: 26658-19-5 


Solubility of Sorbitan tristearate: 

Slightly soluble in toluene, ether, carbon tetrachloride, and ethyl acetate;
dispersible in petroleum ether, mineral oil, vegetable oils, acetone, and dioxane; 
insoluble in water, methanol, and ethanol. 


Sorbitan Tristearate may be found in Bakery products, toppings and coatings, fat emulsions, milk and cream analogs, beverage whiteners, edible ices, desserts, sugar confectionery, chocolate, emulsified sauces, dietetic foods.



PHYSICAL/CHEMICAL SPECIFICATION
Appearance: Cream to Yellowish Flakes/Powder
Acid Value: Max. 15 mgKOH/g
Saponification Value: 170-190 mgKOH/g
Melting Point: 55-65 °C
Hydroxyl Value: 66-80 mgKOH/g
Moisture Content: 1% Max.
HLB Value: 2.2


APPLICATION
• Anticrystallization in Oils
• Antiblooming agent in chocolates
• Antisandinesss agent in margarines
• Cosmetic Applications


SYNONYMS:

sorbitan tristearate (STS) 

Anhydrosorbitol tristearate

Sorbitan tristearate

Sorbitan tristearate

sorbitan tristearate

Sorbitan, trioctadecanoate

Sorbitani tristearas

Triestearato de sorbitano

Tristearate de sorbitan



IUPAC names
(2R)-2-[(2R,3R,4S)-3,4-bis(octadecanoyloxy)oxolan-2-yl]-2-hydroxyethyl octadecanoate (2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl octadecanoate (2R)-2-hydroxy-2-[(2R,3R,4S)-3-hydroxy-4-(octadecanoyloxy)oxolan-2-yl]ethyl (9Z)-octadec-9-enoate

1,3,6-tri-O-stearoylhexitol

[2-[(2R,3S,4R)-4-hydroxy-3-octadecanoyloxyoxolan-2- yl]-2-octadecanoyloxyethyl] octadecanoate

KOSTERAN-S/3KOSTERAN-S/3, UG

SORBITAN TRISTEARATE

Sorbitan, trioctadecanoate




Trade names
Crill 36E

RADIAMULS SORB 2345K

RADIAMULS SORB 2346K

RADIASURF 7345

Span 65

Span 65V

Triestearato de sorbitan

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