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CALCIUM SULFONATE (CALCIUM SULPHONATE)

HIGH BASED SYNTHETIC CALCIUM SULFONATE


METATAGS: CERAN FG;CERAN GEP; CERAN HV; CERAN HVA; CERAN XM; CERAN WR; NEVASTANE SFG 1, 2; NEVASTANE HPX 320; C-300 CS; C-400 CLR; CALCINATE, C-300 R; CALCINATE, C-400 W; HYBASE, C-311; HYBASE, C-401; HYBASE, C-402; HYBASE, C-500; HYBASE, M-12; HYBASE, M-14; LOBASE, C-4502; LOBASE, C-4503; LOBASE, C-4506; PRESYN Ca (OB); PRESYN Ca (HOB); NLGI 1; HIGH BASED SYNTHETIC CALCIUM SULFONATE; calcium sulfonat; calcium sulphonate; kalsiyum sülfonat; aşırı bazlı kalsiyum sülfonat; aşırı bazlı sentetik kalsiyum sülfonat; aşırı bazlı kalsiyum sülfonate; kalsiyum sulfonat; kalsiyum sulphonate; calcium sülfonat; calcıum sulphonate; calcium sülponat; calcıum sülponat; calcium sulpunat; KALSİYUM SÜLFONAT; KALSIYUM SÜLFONAT; KALSİYUM SULFONAT.

 

 

 

 

 


Detergent/dispersant/antirust rust inhibitor marine engine motor oil/antirust oil additive/rust preventive. High base synthetic calcium sulfonate. Application. High based synthetic calcium sulfonate. Detergent/dispersant/antirust/rust inhibitor. Lubricating oil additive/lubricant additive. Marine engine oil additive/engine motor oil/antirust oil additive/rust preventive. This additive is a brownish-red liquid, mainly used for blending engine oil and marine oil, especially for blending the lubricant applied in conditions of high-sulfur fuel, to provide detergency, antirust and acid neutralization properties as well as expending oil drain interval. Features. Excellent high temperature detergency. Fine antirust performance. High-temperature stability. Excellent acid neutralizing ability. Synergy well with other additives. Antifoam. Recommended dosage. 1.5-3.0% in normal lubricant oil. 3.0-25.0% in marine oil. Packing and storage. Packing:. 200kgs/drum, 200 l steel drum.


Extreme-pressure water resistant calcium sulfonate complex grease. Adapted for the static protection of spare parts and designed for use on slide rails, metal cables, wire ropes, winches, small open gears and chains working under severe circumstances. It is used in marine applications, cement works, mines and quarries, ports (e.g. travelling cranes) off shore, and other "heavy" industry applications.

Applications
As a dispersant & corrosion inhibitor in engine oils.
Used in rust preventive formulations, coatings & greases
Disperses carbon formed in diesel engines

PRODUCT DESCRIPTION

Calcinate overbased calcium sulfonates are used for acid scavenging and EP/AW performance in industrial and metalworking lubricants. These products are composed of a natural/synthetic blend of calcium sulfonate detergent in oil and excel at cleaning metal surfaces and deposit control. Major differences between grades are the composition of material, the size of the dispersed calcium carbonate particles, the physical form, and the amount of calcium hydroxide. ​

Calcium sulfonate complex greases, not new to the industry, are known for over six decades and have been improved over times by various people to make suitable grease for different applications. This class of grease is known for having excellent high temperature, extreme pressure and rust protection characteristics. The down side of its performance is poor pumpability, poor low temperature properties and higher cost compared to lithium greases.

In general, the art in preparing this class of greases involves converting liquid overbased calcium sulfonate to grease containing calcite particles. The degree of conversion to calcite form can greatly influence the properties of the finished grease and therefore the art lies how best one controls the process parameters and incorporate the other performance enhancing ingredients during processing stage.

The worldwide volume for calcium sulfonate greases is increased from 1.2 % in 2005 to 1.4 % in 2010. In North America, its volume increased significantly from 3.8 % in 2005 to 5.4 % in 2010, where in India it's merely about 0.8 %. In North America by virtue of its characteristics these greases are gaining more popularity over others and are gradi !ally becoming true multi-purpose greases.

T106D Detergent-High Based Synthetic Calcium Sulfonate Description T106 detergent is widely use for blending internal combustion engine oils for each grade and industrial lubricants as the antirust agent. T106 also has some dispersity. The alkaline calcium sulfonate can neutralize the oxygenated acid of the lubricant and fuel oil oxidized, preventing them from condensation further so that coatings and sludge are reduced. It has the excellent detergency, and can remove the coatings and deposit,increasing solubility and making them disperse in the lubricant.

SEPECIFICATION
ITEM TYPICAL DATA
Density (20°C), kg/m3 1150-1250
Oil soluble bolt clean
Flash point (open) °C ≥180

 

 

 

 

 

 

 

Calcium Petroleum Sulfonates; Sulfonic Acids, Petroleum, Calcium Salts; 61789-86-4; Calcium Sulfonate

 

corrosion inhibitor supplier Ataman Chemicals:Sulfonates are used as additives for metal working fluids and engine oils. They provide special functions such as surfactant and rust-prevention functions.

 

Calcium petroleum sulfonate; Calcium petroleum sulfonates; EC 263-093-9; EINECS 263-093-9; Sulfonic acids, petroleum, calcium salts; Sulfonic acid, petroleum, calcium salt; Sulfonic acids, petroleum, calcium salts; Superlist Names Petroleum sulfonic acids, calcium salts; Sulfonic acids, petroleum, calcium salts;;Calcium petroleum sulfonate;Sulfonic acids, petroleum, calcium salts

 

Chemical Name:Sulfonic acids, petroleum, calcium salts

Synonyms: calcium petrolem sulfonate;calcium petrolem sulfonate;CALCIUM PETROLEUM SULPHONATE; Petroleum calcium sulfonate; sulfonic acid, petroleum, calcium salt; Petroleum sulfonic acids calcium salts; Sulfonic acids, petroleum, calcium salts; Overbased Synthetic Calcium Sulfonate TBN400, TBN300; Dispersant T102

 

Rust Preventing Oil; Lubricating oil; Refrigerator oil ; Antiwear hydraulic oil ;Gear oil ;Industrial gear oil; Antirust lubricating oil; DISPERSING AGENTS; Epoxy coating of terrace RESIN; Antirust emulsified oil; Dehydration antirust oil; Printing ink ;Plastic cement paint; Rust-proof cleaning agent NA; Antirust agent

 

Antirust oil;Rust preventing oil

 

Calcium petroleum sulfonate uses and applications include: Detergent, rust inhibitor; lubricating oil additive; emulsifier

 

CLASS: Specialty Chemicals 

 

FUNCTIONS: Emulsifier,  Rust Inhibitor,  Additive 

 

Sulfonic acids, petroleum, calcium salts

Agent Name: Sulfonic acids, petroleum, calcium salts

CAS Number: 61789-86-4

Synonyms: Calcium petroleum sulfonate; Calcium petroleum sulfonates; Sulfonic acid, petroleum, calcium salt; Petroleum sulfonic acids, calcium salts; (Neutral) Calcium Sulfonate; Additin RC 4220; Calcium long chain alkaryl sulphonate; OLOA 4246A; XDE25/A; [IUCLID]

Category: Petroleum Oils

Description: Dark viscous liquid with an odor of petroleum

Sources/Uses: Used in the lubricant and fuel industries; [IUCLID] Petroleum additive alkaryl sulfonates: Produced in highly refined lubricating base oil and are never isolated; Used as additives in petroleum base stocks (sold to oil blenders where they are further processed to finished oil blends); [EPA ChAMP] Permitted for use as an inert ingredient in non-food pesticide products; [EPA] Used in corrosion inhibiting fluids; [Redox Chemicals MSDS]

 

 

 

 

 

 

Manufactured solely in the presence of lubricating type oils, and has not been isolated for measurement of physical properties; Equivocal results in human skin sensitization patch test studies; No adverse health effects known to be caused by this type of material, which has been in use for over fifty years with high occupational exposure in laboratory and manufacturing personnel; [IUCLID] Petroleum additive alkaryl sulfonates: Members of the group and supporting compounds demonstrated low acute oral toxicity in animal studies; [EPA ChAMP] May cause mild skin and severe eye irritation; High vapor concentrations may cause respiratory tract irritation and headache; 

 

ATAMAN CHEMICALS is a Overbased Calcium Sulfonate supplier. ATAMAN  supplies Overbased Calcium Sulfonate to various industries for a variety of applications and uses. ATAMAN  is an importer of Overbased Calcium Sulfonate to numerous countries around the world. Manufacturers rely on ATAMAN  for a reliable, efficient, and cost-effective supply of Overbased Calcium Sulfonate. ATAMAN  works with competitive and reliable manufacturers of Overbased Calcium Sulfonate to provide supply chain solutions for our customers.

 

ATAMAN CHEMICALS supplies Overbased Calcium Sulfonate in Overbased Calcium Sulfonate 300 TBN, Overbased Calcium Sulfonate 400 TBN, Overbased Calcium Sulfonate Tech grade(s). ATAMAN  supplies Overbased Calcium Sulfonate to users/customers for Lubricant & Grease.

 

Ataman’s sodium sulfonates provide excellent emulsion quality and corrosion resistance in customer formulations. While the lower molecular weight sulfonates provide excellent emulsion performance,the higher molecular weight sulfonates provide unsurpassed rust prevention. Depending on the application, the balance of these two properties is critical for maximum performance

 

Key Applications

Petroleum additives; Detergents, Anti-wear; Dispersants; VI Improver; Corrosion Inhibitors; Emulsifiers; Extreme Pressure; Friction Modifier; Antifoam

 

Product Description

These neutralized, first-intent, water and oil soluble synthetic calcium sulfonates are used in dispersant, emulsification, metal working, corrosion prevention, lube oil additive, agriculture, ore floatation, enhanced oil recovery, and industrial cleaning applications.

 

Applications

As a dispersant & corrosion inhibitor in engine oils.

Used in rust preventive formulations, coatings & greases

Disperses carbon formed in diesel engines

 

 

APPLICATION

 

Imparts excellent rust prevention, detergency and Anti oxidant Properties.

Corrosion inhibitor in mill oils, short-term rust preventatives, coatings and greases

Dispersant and corrosion inhibitor in engine oil.

Provides excellent resistance to coated Cold Rolled Steel for antirust applications.

Works in extremely hostile conditions like highly acidic environment as well as highly humid atmosphere.

It is non-staining having detergent, dispersant properties.

Environmental Friendly, Biodegradable without side effect.

 

 

 

 

 

 

 

CALCIUM PETROLEUM SULPHONATE USES

Ataman Chemicals supplies normal as well as high TBN (high total base number -Calcium Petroleum sulphonate. 

Calcium Petroleum sulphonates are are used in following applications:

 

Grease

Calcium sulfonate greases are generally beneficial for rust performance, with oxidation stability considered good or excellent.

calcite particles, inherent in calcium sulfonate greases, make them a good choice for high-temperature applications. 

Ataman’s  Calcium Petroleum Sulfonate is good choice for grease manufacturers as our Sulfonates are available customized specifications and at attractive price.

Calcium Sulfonate Greases are used in automotive, agricultural, construction, food, industry, mining, paper manufacturing and steel mills.

 

Detergent

Ataman Kimya’s Calcium Petroleum Sulfonate find its use in manufacturing best quality detergent which can be used to prevent sludge deposits.

 

Rust Preventives & Corrosion Inhibitor

High Base number as well as normal Calcium Petroleum Sulphonate of ATAMAN CHEMICALS is well accepted performance chemicals to manufacture rust preventives, inhibitors and corrosion inhibitors oils and lubricants.

 

Emulsifier

Emulsifier formulation with corrosion inhibition are best blended with our range of petroleum sulfonates.

 

Oil Additives

Calcium Petroleum Sulfonates are used in Engine Oil, MetalWorking, Automatic Transmission Fluid, Industrial and Automotive Gear Oil additives and Lubricants. Ataman’s petroleum sulfonates are used for high temperature applications industrial oils and lubricants blending.

 

 

 

Regulatory process names: Sulfonic acids, petroleum, calcium salts

EC Inventory: Sulfonic acids, petroleum, calcium salts

Pre-Registration process

CAS names: Sulfonic acids, petroleum, calcium salts

Other IUPAC names

CALCIUM PETROLEUM SULFONATE

Calcium petroleum sulfonate

CALCIUM SALT OF SULFONIC ACIDS, PETROLEUM

Petroleum mixture of C10 to 40 saturated linear and branched alkylaryl derivatised benzenesulfonic acid calcium salts.

Petroleum mixture of C10 to 47 saturated linear alkaryl derivatised cyclopentan cyclohexanbenzene sulfonic acid and C10 to 47 saturated linear alkaryl derivatised cyclopentan phenobenzene sulfonic acid calcium salts

sulfonic acid, petroleum, calcium salts

sulfonic acids, petroleum calcium salt

SULFONIC ACIDS, PETROLEUM, CALCIUM SALTS

Sulfonic acids, petroleum, calcium salts

Sulfonic acids, petroleum, calcium salts

Sulfonic acids, petroleum, calcium salts, overbased

 

 

 

 

 

 

 

 

 

Sulfonates are derived from petroleum fractions, from lignin, and from fatty oils.

These materials are mixtures of indeterminate or variable composition, probably comprising one or more of the main chemical types of sulfonates together with sulfates and other sulfur compounds, and are made largely by empirical procedures.

Sulfonates are used as additive agents for metal working oil and engine oil. In this usage, sulfonates provide special functions such as surfactant functions and rust prevention.

Sulfonation may be defined as any chemical process by which the sulfonic acid group (SO2OH) or the corresponding salt or sulfonyl halide group (e.g. –SO2CI) is introduced into an organic compound

Natural petroleum sulfonates are defined as those manufactured by sulfonation of crude oil, crude distillates, or any portion of these distillates in which hydrocarbons present are not substantially different from their state in the original crude oil.

These natural materials, then, are quite different from synthetic sulfonates, which are derived most commonly from sulfonation of olefinic polymers or alkyl aromatic hydrocarbons.

Calcium Petroleum Sulphonate is Calcium salt of Sulphonic Acid made by processing Heavy Alkaline Benzene of suitable fraction with Sulphuric Acid or Sulphur Trioxide and refining by liquid extraction by using suitable alcoholic solvent and precipitating insoluble salts by control of PH and centrifuging.

Meta petroleum sulfonates are widely used in the manufacture of lubricating oil additives and greases. Recently a process has been developed for the manufacture of superior metal petroleum sulfonates, particularly calcium petroleum sulfonates, by the sulfonation of a highly viscous, highly refined parafiinic oil fraction having a viscosity of at least about 200 to 230 SUS at 210 F. and having a viscosity index of about 85 to 100 or higher.

Petroleum sulfonate is mainly obtained by treating high-boiling petroleum fractions in a stirred tank reactor (STR) or in a falling-film reactor (FFR).  Synthesis of Petroleum Sulfonate Surfactant with Ultra-Low Interfacial Tension in Rotating Packed Bed Reactor.

 

Metatags:

Calcium Petroleum Sulfonate

Production of Calcium Petroleum Sulfonate

Chloride free Calcium sulfonate

Process for Overbased Calcium sulfonate

Filtration of petroleum sulfonate product

Production of Petroleum Sulfonates

Process for preparation of Improved Lubricating Compositions

Metal Petroleum Sulfonates

Overbased Petoleum Sulfonate

Apparatus for producing Overbased petroleum sulfonate

 

 

 

KEY CONCEPTS

• Metalcorrosion o os o preventive reventives perform the important function unction of protecting metal parts by forming a protective rotective layer on the surface of the component.

• Selection Selection of the correct metalcorrosion preventive is a complex process based on application, pplication, the needs of the end-user and subsequent bsequent process processing steps.

• Future trends influencing the use of metalcorrosion preventives are the increased use of non-ferrou non-ferrous metals,environment environmental issues, worldwi worldwide regulations and the reduced storage timefor metal parts inventory

 

 

Petroleum Sulphonates 

ATAMAN offers clients an effective range of Petroleum Sulphonates – Barium Petroelum sulphonate,calcium petroleum sulphonates as well as Magnesium petroleum sulphonate.

These petroleum sulphonates are safe to use and processed as per the prevailing lubricant industry standards. 

Acknowledged for precise pH value, petroleum sulphonates are available in various grades to suit diverse requirements of lubricant manufacturing and oil industries.

 

Quality of Sodium Petroleum Sulphonate

Gravity, at 15.6 °C 1.02

Viscosity at 100°C, CST 190

Basicity Basic

Flash Point °C(COC) 205

Barium Petroleum Sulphonate

Components of barium petroleum sulphonate include:

Napthanic Oil 0.5-25%

Paraffinic oil 0.5-25%

Solvents (Kerosene, Toluene and MTO) 0.5-25%

Application Area of Sodium Petroleum Sulphonate and Barium Petroleum Sulphonate:

Corrosion inhibitor in mill oils

Rust preventatives, coatings and greases

Demulsibility

Non-staining

Used as wetting agent, dispersant and corrosion inhibitor in engine oil

Utilized for formulating greases, slushing oils, hydraulic fluids other industry products

Calcium Petroleum Sulphonate

ATAMAN also manufacture and export Calcium Petroleum Sulphonate that is accurate in composition and competitive in price. Our range is appreciated by clients for accurate composition and precise pH value. We process our range in hygienic conditions to ensure excellent quality, purity and stability under different climatic conditions.

 

Range of Calcium Petroleum Sulphonate

Customized calcium petroleum sulphonate available on request.

 

Magnesium Petroleum Sulphonate

ATAMAN also manufacture and export Calcium Petroleum Sulphonate that is accurate in composition and competitive in price. Our range is appreciated by clients for accurate composition and precise pH value. We process our range in hygienic conditions to ensure excellent quality, purity and stability under different climatic conditions.

 

Range of Magnesium Petroleum Sulphonate

Customized magnesium petroleum sulphonate (sulfonate) available on request.

 

Contact us for your requirement of petroleum sulphonate(sulfonate)

 

 

 

Commercial calcium petroleum sulfonates have found widespread use in lubricating'oil as additives designed to reduce or eliminate these combustion chamber deposits. These sulfonates are desirably prepared by sulfonating'a lubricating oil and neutralizing the resulting sulfonic acids with lime in order to form calcium petroleum sulfonates and stabilize the sulfonic acid mixture with respect to ferrous corrosion. The resulting neutralized mixture, which contains solids such as calcium sulfate dihydrate, is then separated to obtain the calcium petroleum sulfonates, the separation generally being carried out byfiltration of the neutralized mixture.

 

Sulphonates as rust inhibitors 

Anti-Corrosion Methods and Materials

 

ISSN: 0003-5599

 

Publication date: 1 July 1986 Reprints & Permissions

 

Abstract

The rust inhibiting characteristics of barium/calcium petroleum sulphonates, prepared from two indigenously available base stocks of different origin have been determined in concentration ranging from 0.5 to 3.0% W/W in mineral oil as per ASTM D‐1748 method. The products have been characterised as ‘outstanding’, ‘good’ and ‘satisfactory’ on the basis of their performance in the humidity cabinet. It has been observed that Ba/Ca petroleum sulphonates possessing outstanding rust inhibiting characteristics show low oil/water interfacial tension and high water solubilization characteristics as compared to other sulphonates. It has also been observed that the rust inhibiting characteristics are profoundly influenced by the structural parameter of the hydrocarbon portion of the petroleum sulphonates. The larger the alkyl side chain, the better is the rust inhibiting properties.


 


Deterjan / dispersan / paslanmaya karşı pas önleyici marine motor motor yağı / paslanmaz yağ katkısı / pas önleyici. Yüksek bazlı sentetik kalsiyum sülfonat. Uygulama. Yüksek bazlı sentetik kalsiyum sülfonat. Deterjan / dispersan / anti-pas / pas önleyici. Yağlayıcı yağ katkı maddesi / yağlayıcı katkı maddesi. Deniz motor yağı katkı maddesi / motor motor yağı / paslanmaz yağ katkısı / pas önleyici. Bu katkı kahverengimsi-kırmızı bir sıvıdır, özellikle motor yağını ve deniz yağını harmanlamak için, özellikle yüksek kükürtlü yakıt koşullarında uygulanan kayganlaştırıcıyı harmanlamak için, deterjan, paslanma ve asit nötralizasyon özellikleri ile yağ boşaltma aralığının arttırılması için kullanılır. Özellikler. Mükemmel yüksek sıcaklıkta deterjan. İyi anti-pas koruma performansı. Yüksek sıcaklık kararlılığı. Mükemmel asit nötrleştirme kabiliyeti. Sinerji diğer katkılarla iyi. Köpük önleyici. Önerilen dozaj. Normal yağlayıcı yağda% 1.5-3.0. Deniz yağında% 3.0-25.0. Paketleme ve saklama. Paketleme:. 200kgs / tambur, 200 l çelik tambur.


Aşırı basınçlı suya dayanıklı kalsiyum sülfonat kompleks gres. Yedek parçaların statik koruması için uyarlanmıştır ve slayt rayları, metal kablolar, tel halatlar, vinçler, küçük açık dişliler ve zor koşullar altında çalışan zincirlerde kullanılmak üzere tasarlanmıştır. Deniz uygulamalarında, çimento fabrikalarında, madenlerde ve taş ocaklarında, limanlarda (örneğin seyahat vinçleri) kıyılarda ve diğer "ağır" endüstri uygulamalarında kullanılır.

Uygulamalar
Motor yağlarında bir dispersan ve korozyon inhibitörü olarak.
Pas önleyici formülasyonlar, kaplamalar ve greslerde kullanılır
Dizel motorlarda oluşan karbon dağılımları

ÜRÜN AÇIKLAMASI

Kalsinat aşırı bazlı kalsiyum sülfonatlar, endüstriyel temizleme ve metal işleme yağlarında asit süpürme ve EP / AW performansı için kullanılır. Bu ürünler yağdaki kalsiyum sülfonat deterjanın doğal / sentetik bir karışımından oluşur ve metal yüzeylerin temizlenmesi ve depozit kontrolünde üstünlük sağlar. Maddeler arasındaki ana farklılıklar, maddenin bileşimi, dağınık kalsiyum karbonat parçacıklarının boyutu, fiziksel form ve kalsiyum hidroksit miktarıdır.

Sektörde yeni olmayan kalsiyum sülfonat kompleksi gresleri, altı yılı aşkın süredir bilinmektedir ve farklı insanlar için uygun yağ oluşturmak için çeşitli insanlar tarafından zaman içinde geliştirilmiştir. Bu gres sınıfı, mükemmel yüksek sıcaklık, aşırı basınç ve pas koruma özelliklerine sahip olduğu bilinmektedir. Performansının aşağı tarafı, lityum greslerine kıyasla, kötü pompalanabilirlik, zayıf düşük sıcaklık özellikleri ve daha yüksek maliyettir.

Genel olarak, bu gres sınıfının hazırlanmasına ilişkin sanat, sıvıya aşırı bazlı kalsiyum sülfonatın gres içeren kalsit parçacıklarına dönüştürülmesini içerir. Kalsit formuna dönüştürme derecesi tamamlanmış gresin özelliklerini büyük ölçüde etkileyebilir ve bu nedenle bu alanda en iyi yöntemin proses parametrelerini kontrol etmesi ve işleme aşamasında diğer performans artırıcı katkı maddelerini içermesi yatmaktadır.

Kalsiyum sülfonat gresleri için dünya çapındaki hacim 2005'de% 1.2'den 2010'da% 1.4'e yükselmiştir. Kuzey Amerika'da, hacmi 2005'de% 3.8 iken 2010'da% 5.4'e yükselmiştir; Hindistan'da sadece% 0.8'dir. Kuzey Amerika'da özelliklerinden dolayı bu gresler diğerlerinden daha fazla popülarite kazanmakta ve gerçek anlamda çok amaçlı gresler haline gelmektedirler.

T106D Deterjan Esaslı Sentetik Kalsiyum Sülfonat Tanımı T106 deterjan, içten yanmalı motor yağlarının her dereceli ve endüstriyel yağlayıcılar için antirust ajanı olarak harmanlanması için yaygın olarak kullanılır. T106 da bir miktar dağılma özelliğine sahiptir. Alkalin kalsiyum sülfonat yağlayıcı ve yakıt yağının oksijenlenmiş asidini oksitleyebilir, böylece kaplamaların ve çamurun azaltıldığı yoğunlaşmayı önler. Mükemmel bir deterjan özelliğine sahiptir ve kaplamaları ve depolamayı kaldırabilir, çözünürlüğü arttırır ve yağlayıcıda dağılmasını sağlar.

SEPECİFİKASYON
MADDE TİPİK VERİLERİ
Yoğunluk (20 ° C), kg / m3 1150-1250
Yağda çözünür civata temizliği
Parlama noktası (açık) ° C ≥180

 

 

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